NDLI: Characterization of polychlorinated naphthalenes in stack gas emissions from waste incinerators.

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Characterization of polychlorinated naphthalenes in stack gas emissions from waste incinerators.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Hu, Jicheng Xiao, Ke Liu, Guorui Zhang, Bing Li, Changliang Gao, Lirong Zheng, Minghui Liu, Wenbin Nie, Zhiqiang
Description	Country affiliation: China Author Affiliation: Hu J ( State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, PO Box 2871, Beijing 100085, China.)
Abstract	Nine typical waste incinerating plants were investigated for polychlorinated naphthalene (PCN) contents in their stack gas. The incinerators investigated include those used to incinerate municipal solid, aviation, medical, and hazardous wastes including those encountered in cement kilns. PCNs were qualified and quantified by isotope dilution high resolution gas chromatography-high resolution mass spectrometry techniques. An unexpectedly high concentration of PCNs (13,000 ng Nm(-3)) was found in the stack gas emitted from one waste incinerator. The PCN concentrations ranged from 97.6 to 874 ng Nm(-3) in the other waste incinerators. The PCN profiles were dominated by lower chlorinated homologues, with mono- to tetra-CNs being the main homologues present. Furthermore, the relationships between PCNs and other unintentional persistent organic pollutants involving polychlorinated dibenzo-p-dioxins and dibenzofurans, polychlorinated biphenyls, hexachlorobenzene, and pentachlorobenzene were examined to ascertain the closeness or otherwise of their formation mechanisms. A good correlation was observed between ΣPCN (tetra- to octa-CN) and ΣPCDF (tetra- to octa-CDF) concentrations suggesting that a close relationship may exist between their formation mechanisms. The results would provide an improved understanding of PCN emissions from waste incinerators.
ISSN	09441344
Issue Number	5
Volume Number	20
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2013-05-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Air Pollutants Analysis Dioxins Hydrocarbons, Chlorinated Naphthalenes Chemistry Environmental Monitoring Gas Chromatography-mass Spectrometry Incineration Principal Component Analysis Journal Article Research Support, Non-u.s. Gov't Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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