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On the role of hydrophobic Si-based protective coatings in limiting mortar deterioration

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On the role of hydrophobic Si-based protective coatings in limiting mortar deterioration

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Fratini, F. Fermo, P. Pino, F. Pargoletti, E. La Russa, M. F. Cappelletti, G. Pecchioni, E. Ruffolo, S. A.
Description	Country affiliation: Italy Author Affiliation: Cappelletti G ( Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133, Milano, Italy. giuseppe.cappelletti@unimi.it.); Fermo P ( Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133, Milano, Italy.); Pino F ( Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133, Milano, Italy.); Pargoletti E ( Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133, Milano, Italy.); Pecchioni E ( Dipartimento di Scienza della Terra, Università degli Studi di Firenze, Via G. La Pira 4, 50121, Firenze, Italy.); Fratini F ( CNR-Istituto per la Conservazione e la Valorizzazione dei Beni Culturali, Via Madonna del Piano 10, 50019, Sesto Fiorentino, Firenze, Italy.); Ruffolo SA ( Dipartimento di Biologia, Ecologia e Scienze della Terra (DiBEST), Università della Calabria, Via Pietro Bucci, Cubo 12 B, 87036, Arcavacata di Rende, Cosenza, Italy.); La Russa MF ( Dipartimento di Biologia, Ecologia e Scienze della Terra (DiBEST), Università della Calabria, Via Pietro Bucci, Cubo 12 B, 87036, Arcavacata di Rende, Cosenza, Italy.)
Abstract	In order to avoid both natural and artificial stone decay, mainly due to the interaction with atmospheric pollutants (both gases such as $NO_{x}$ and $SO_{2}$ and particulate matter), polymeric materials have been widely studied as protective coatings enable to limit the penetration of fluids into the bulk material. In the current work, an air hardening calcic lime mortar (ALM) and a natural hydraulic lime mortar (HLM) were used as substrates, and commercially available Si-based resins (Alpha®SI30 and Silres®BS16) were adopted as protective agents to give hydrophobicity features to the artificial stones. Surface properties of coatings and their performance as hydrophobic agents were studied using different techniques such as contact angle measurements, capillary absorption test, mercury intrusion porosimetry, surface free energy, colorimetric measurements and water vapour permeability tests. Finally, some exposure tests to UV radiation and to real polluted atmospheric environments (a city centre and an urban background site) were carried out during a wintertime period (when the concentrations of the main atmospheric pollutants are higher) in order to study the durability of the coating systems applied. The effectiveness of the two commercial resins in reducing salt formation (sulphate and nitrate), induced by the interaction of the mortars with the atmospheric pollutants, was demonstrated in the case of the HLM mortar.
ISSN	09441344
Issue Number	22
Volume Number	22
e-ISSN	16147499
Journal	Environmental Science and Pollution Research
Language	English
Publisher	Springer
Publisher Date	2015-11-01
Publisher Place	Germany
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Air Pollutants Chemistry Particulate Matter Calcium Compounds Construction Industry Construction Materials Hydrophobic And Hydrophilic Interactions Oxides Surface Properties Thermodynamics Journal Article Discipline Environmental Science Discipline Environmental Chemistry
Content Type	Text
Resource Type	Article
Subject	Environmental Chemistry Health, Toxicology and Mutagenesis Pollution Medicine

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