NDLI: Antimony oxofluorides – a synthesis concept that yields phase pure samples and single crystals

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Ali, Sk Imran Johnsson, Mats
Description	Author Affiliation: Ali SI ( Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden. mats.johnsson@mmk.su.se.); Johnsson M ( Department of Materials and Environmental Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden. mats.johnsson@mmk.su.se.)
Abstract	The single crystals of the new isostructural compounds $Sb_{3}O_{4}F$ and $Y_{0.5}Sb_{2.5}O_{4}F$ and the two previously known compounds M-SbOF and $α-Sb_{3}O_{2}F_{5}$ were successfully grown by a hydrothermal technique at 230 °C. The new compound $Sb_{3}O_{4}F$ crystallizes in the monoclinic space group $P2_{1}/c;$ a = 5.6107(5) Å, b = 4.6847(5) Å, c = 20.2256(18) Å, β = 94.145(8)°, z = 4. The replacing part of Sb with Y means a slight increase in the unit cell dimensions. The compounds M-SbOF and $α-Sb_{3}O_{2}F_{5}$ have not been grown as single crystals before and it can be concluded that hydrothermal synthesis has proved to be a suitable technique for growing single crystals of antimony oxofluorides because of the relatively low solubility of such compounds compared to other antimony oxohalides that most often have been synthesised at high temperatures by solid state reactions or gas–solid reactions.
ISSN	14779226
Issue Number	30
Journal	Dalton Trans.
Volume Number	45
e-ISSN	13645447
Language	English
Publisher	Royal Society of Chemistry
Publisher Date	2016-07-26
Publisher Place	Great Britain (UK)
Access Restriction	Subscribed
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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