NDLI: Application of AC-SECM in Corrosion Science: Local Visualisation of Inhibitor Films on Active Metals for Corrosion $Protection^{†}$

Please wait, while we are loading the content...

Interplay of Direct Stereocontrol and Dynamic Kinetic Resolution in a Bifunctional Amine Thiourea Catalyzed Highly Enantioselective Cascade Michael–Michael Reaction

Ionic-Liquid Synthesis Route of $TiO_{2}(B)$ Nanoparticles for Functionalized Materials

Charm-Bracelet-Type Poly(N-vinylcarbazole) Functionalized with Reduced Graphene Oxide for Broadband Optical Limiting

Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed CO Activation

Gearing of Molecular Swirls: Columnar Packing of Nematogenic Hexakis(4-alkoxyphenylethynyl)benzene Derivatives

Phenylazomethine Dendrimers with Soft Aliphatic Units as Metal-Storage Nanocapsules and Their Self-Assembled Structures

Enzyme-Inspired Controlled Release of Cucurbit[7]uril Nanovalves by Using Magnetic Mesoporous Silica

Anion Recognition and Cation-Induced Molecular Motion in a Heteroditopic [2]Rotaxane

Aromatic/Proaromatic Donors in 2-Dicyanomethylenethiazole Merocyanines: From Neutral to Strongly Zwitterionic Nonlinear Optical Chromophores

Prebiotic Routes to Nucleosides: A Quantum Chemical Insight into the Energetics of the Multistep Reaction Pathways

Supramolecular Organization of Light-Harvesting Porphyrin Macrorings

Selective Multiple Magnesiations of the Thieno[3,2-b]thiophene Scaffold

Structure and Reactivity of the Cysteine Methyl Ester Radical Cation

Exploiting the Divergent Reactivity of α-Isocyanoacetate: Multicomponent Synthesis of 5-Alkoxyoxazoles and Related Heterocycles

A New Entry into Aluminum Chemistry: $[L^{1}AlMe]⋅THF,$ a Versatile Building Block for Bimetallic and Polymetallic Complexes

Application of AC-SECM in Corrosion Science: Local Visualisation of Inhibitor Films on Active Metals for Corrosion $Protection^{†}$

Dynamic Disorder in the Crystal Structure of an Organic Semiconductor: An Unusual Phase Transition Involving the Heat Capacity

Synthesis of Ferrite Nanocrystals Stabilized by Ionic-Liquid Molecules through a Thermal Decomposition Route

Synthesis and Characterization of Tetramethylammonium Trifluorosulfate

Intramolecularly Coordinated Telluroxane Clusters and Polymers

Controlled Synthesis and Self-Assembly of Highly Monodisperse Ag and $Ag_{2}S$ Nanocrystals

Synthesis of [5]Rotaxanes Containing Bi- and Tridentate Coordination Sites in the Axis

A Flexible Asymmetric Approach to Methyl 5-Alkyltetramates and Its Application in the Synthesis of Cytotoxic Marine Natural Product Belamide A

Star-Shaped Tripodal Chemosensors for the Detection of Aliphatic Amines

Surface-Initiated Atom-Transfer Radical Polymerization of 4-Acetoxystyrene for Immunosensing

Synthesis of Chiral Cyclic Nitrones by Asymmetric Addition of β-Ketosulfones to Nitroalkenes followed by Reductive Cyclization

Synthesis of Enantiopure 1,4-Dioxanes, Morpholines, and Piperazines from the Reaction of Chiral 1,2-Diols, Amino Alcohols, and Diamines with Vinyl Selenones

Triosmium Clusters on a Support: Determination of Structure by X-ray Absorption Spectroscopy and High-Resolution Microscopy

Enantiomer Resolution of Intrinsically Chiral C21-Alkylated N-Confused Porphyrin Complexes

Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides, and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides

Supermolecular Liquid Crystals with a Six-Armed Cyclotriphosphazene Core: From Columnar to Cubic Phases

Diverse Structures and Magnetism of Cobalt(II) and Manganese(II) Compounds with Mixed Azido and Carboxylato Bridges Induced by Methylpyridinium Carboxylates

Triazine-Based Polymers as Nanostructured Supports for the Liquid-Phase Oxidation of Alcohols

Year: 2011 Volume: 17 Issue: 2

Year: 2011 Volume: 17 Issue: 1

Year: 2010 Volume: 16

Year: 2009 Volume: 15

Year: 2008 Volume: 14

Year: 2007 Volume: 13

Year: 2006 Volume: 12

Year: 2005 Volume: 11

Year: 1997 Volume: 3

Application of AC-SECM in Corrosion Science: Local Visualisation of Inhibitor Films on Active Metals for Corrosion $Protection^{†}$

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Santana, Juan José Pähler, Maike Souto, Ricardo M. Schuhmann, Wolfgang
Description	Author Affiliation: Pähler M ( Analytische Chemie - Elektroanalytik & Sensorik, Ruhr-Universität Bochum, Universitätsstr. 150, 44780 Bochum, Germany.)
Abstract	The suitability of frequency-dependent alternating-current scanning electrochemical microscopy (4D AC-SECM) for investigation of thin passivating layers covering the surface of corrosion-inhibited metals has been demonstrated. Inhibition of copper corrosion by benzotriazole (BTAH) and methylbenzotriazole (MBTAH), which are effective inhibitors for this metal under many environmental conditions, was investigated. Strong dependencies were found for the AC z-approach curves with both the duration of the inhibitor treatment and the frequency of the AC excitation signal applied in AC-SECM. Both negative and positive feedback behaviours were observed in the AC approach curves for untreated copper and for Cu/BTAH and Cu/MBTAH samples. Negative feedback behaviour occurred in the low-frequency range, whereas a positive feedback effect was observed at higher frequencies. A threshold frequency related to the passage from negative to positive regimes could be determined in each case. The threshold frequency for inhibitor-modified samples was found always to be significantly higher than for the untreated metal, because the inhibitor film provides electrical insulation for the surface. Moreover, the threshold frequency increased with increasing surface coverage by the inhibitor. 4D AC-SECM was successfully applied to visualizing spatially resolved differences in local electrochemical activity between inhibitor-free and inhibitor-covered areas of the sample.
ISSN	09476539
e-ISSN	15213765
Journal	Chemistry - A European Journal
Issue Number	3
Volume Number	17
Language	English
Publisher	Wiley-VCH;ChemPubSoc Europe
Publisher Date	2011-01-17
Publisher Place	Germany
Access Restriction	Open
Subject Keyword	Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Uses of Scanning Electrochemical Microscopy (SECM) for the Characterization with Spatial and Chemical Resolution of Thin Surface Layers and Coating Systems Applied on Metals: A Review

Physico-chemical aspects of protection of metals by organic corrosion inhibitors

Effect of residual stress on corrosion sensitivity of carbon steel studied by SECM

Corrosion of ferrous metals by organic Acid vapours emitted by packaging wood and its prevention by volatile corrosion inhibitor

In Situ Scanning Electrochemical Microscopy (SECM) Detection of Metal Dissolution during Zinc Corrosion by Means of Mercury Sphere-Cap Microelectrode Tips

Inorganic–organic sol gel hybrid coatings for corrosion protection of metals

Investigations of Local Corrosion Behavior of Plasma-Sprayed FeCr Nanocomposite Coating by SECM

Depositing nanolayers of volatile organic compounds on metals for higher resistance to atmospheric corrosion

Estimate of contributions of polysulfide film and inhibitor to the protection of steel from hydrogen-sulfide corrosion

Application of AC-SECM in Corrosion Science: Local Visualisation of Inhibitor Films on Active Metals for Corrosion $Protection^{†}$

Similar Documents

Uses of Scanning Electrochemical Microscopy (SECM) for the Characterization with Spatial and Chemical Resolution of Thin Surface Layers and Coating Systems Applied on Metals: A Review

Physico-chemical aspects of protection of metals by organic corrosion inhibitors

Effect of residual stress on corrosion sensitivity of carbon steel studied by SECM

Corrosion of ferrous metals by organic Acid vapours emitted by packaging wood and its prevention by volatile corrosion inhibitor

In Situ Scanning Electrochemical Microscopy (SECM) Detection of Metal Dissolution during Zinc Corrosion by Means of Mercury Sphere-Cap Microelectrode Tips

Inorganic–organic sol gel hybrid coatings for corrosion protection of metals

Investigations of Local Corrosion Behavior of Plasma-Sprayed FeCr Nanocomposite Coating by SECM

Depositing nanolayers of volatile organic compounds on metals for higher resistance to atmospheric corrosion

Estimate of contributions of polysulfide film and inhibitor to the protection of steel from hydrogen-sulfide corrosion

Application of AC-SECM in Corrosion Science: Local Visualisation of Inhibitor Films on Active Metals for Corrosion $Protection^{†}$