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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Yan, Kai Zhu, Yuhan Cheng, Ling Zhang, Jingdong |
| Description | Author Affiliation: Yan K ( Key Laboratory for Large-Format Battery Materials and System (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology.) |
| Abstract | A novel photoelectrochemical strategy for the sensitive determination of p-nitrophenol (PNP) was developed using a glassy carbon electrode (GCE) modified with CdSe quantum dots (QDs) and DNA composite film (CdSe-DNA/GCE). Various surface analytical techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM) and scanning electron microscopy (SEM), were employed to characterize the synthesized CdSe QDs and CdSe-DNA modified electrode. The interfacial behaviors of the modified electrodes were analyzed by electrochemical impedance spectroscopy (EIS), and the interaction between PNP and DNA was studied by UV-visible spectrometry. Due to the PNP-DNA interaction, CdSe-DNA/GCE exhibited a sensitive photocurrent response toward PNP under visible-light irradiation. The influencing factors, such as the concentration of DNA used for fabricating CdSe-DNA/GCE and the bias potential applied in the photoelectrochemical measurement, were investigated. Under the optimized conditions, the photocurrent on CdSe-DNA/GCE was linearly increased with the PNP concentration from 0.7 to 50 µmol L(-1), with a detection limit (3 S/N) of 0.27 µmol L(-1). The proposed photoelectrochemical strategy was successfully applied to monitoring the degradation of PNP. |
| File Format | HTM / HTML |
| ISSN | 09106340 |
| e-ISSN | 13482246 |
| Journal | Analytical Sciences |
| Issue Number | 7 |
| Volume Number | 31 |
| Language | English |
| Publisher | The Japan Society for Analytical Chemistry |
| Publisher Date | 2015-01-01 |
| Publisher Place | Japan |
| Access Restriction | Open |
| Subject Keyword | Discipline Analytical Discipline Chemistry Techniques Biosensing Techniques Cadmium Compounds Chemistry Nitrophenols Photochemical Processes Quantum Dots Selenium Compounds Animals Electrochemistry Electrodes Hydrogen Peroxide Limit Of Detection Research Support, Non-u.s. Gov't |
| Content Type | Text |
| Resource Type | Article |
| Subject | Analytical Chemistry |
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