NDLI: Effect of adsorbed chlorine on the durability of a stainless steel reactor

Content Provider	Springer Nature Link
Author	Nagornykh, S. N. Khiteva, D. V.
Copyright Year	2015
Abstract	The stress-corrosion cracking of steel is described using a model of the scalar density of gliding and climbing dislocations near the surface on which chlorine is adsorbed. A barrier-free criterion of the durability of the climbing dislocation pairs is defined, which takes into account both mechanical stress and the concentration of chlorine. The calculated energy values and characteristic dimensions are consistent with experimental data for the dissolution of an anode in an electrolyte and the nucleation and growth of crack nuclei. The model also takes into account the adsorption of chlorine, which, by neutralizing the potential of zero charge, effectively reduces the durability proportionally to the exponent of the steady-state potential.
Starting Page	749
Ending Page	752
Page Count	4
File Format	PDF
ISSN	10274510
Journal	Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques
Volume Number	9
Issue Number	4
e-ISSN	18197094
Language	English
Publisher	Pleiades Publishing
Publisher Date	2015-08-06
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	stress-corrosion cracking defect density equations durability criterion pair climbing anode-cathode pairs steady-state potential chemisorbed chlorine resistive layer Surfaces and Interfaces, Thin Films
Content Type	Text
Resource Type	Article
Subject	Nanoscience and Nanotechnology Surfaces, Coatings and Films

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Effect of adsorbed chlorine on the durability of a stainless steel reactor