NDLI: Synthesis, structure, and magnetic properties of two novel lanthanide-organic frameworks

Content Provider	Springer Nature Link
Author	Li, XiuHua Fang, Ming Zhao, Bin
Copyright Year	2009
Abstract	Two novel metal-organic frameworks, {[Eu(phen)(NDA)$_{1.5}$(H$_{2}$O)]}$_{ n }$ ((1); NDA = 2,6-naphthalenedicarboxylate ions, phen = 1,10-phenanthroline) and {[Gd(phen)(NDA)$_{1.5}$]·0.5H$_{2}$NDA}$_{ n }$ (2), have been synthesized under hydrothermal conditions. The structure analyses of 1 and 2 reveal that the two compounds belong to the triclinic system with space group P-1. Compound 1 features a 2D lattice structure while compound 2 displays a novel 3D architecture. The two frameworks were further characterized by elemental analyses, luminescent spectrua, and variable-temperature magnetic susceptibilities. The investigation of luminescent property reveals that 1 exhibits characteristic red emission of Eu$^{3+}$. Magnetic investigation suggests that the ferromagnetic coupling exists between adjacent Gd$^{3+}$ in compound 2.
Starting Page	1456
Ending Page	1462
Page Count	7
File Format	PDF
ISSN	10069291
Journal	Science in China Series B: Chemistry
Volume Number	52
Issue Number	9
e-ISSN	18622771
Language	English
Publisher	SP Science in China Press
Publisher Date	2009-09-24
Publisher Place	Heidelberg
Access Restriction	Subscribed
Subject Keyword	2,6-naphthalenedicarboxylate lanthanide complexes ferromagnetic coupling luminescent property Chemistry/Food Science
Content Type	Text
Resource Type	Article
Subject	Chemistry

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