NDLI: Combustion behaviors of cotton fabrics treated by a novel nitrogen- and phosphorus-containing polysiloxane flame retardant

Content Provider	Springer Nature Link
Author	Dong, Chaohong Lu, Zhou Zhang, Fengjun Zhu, Ping Wang, Peng Che, Ying Sui, Shuying
Copyright Year	2015
Abstract	A novel flame-retardant agent, nitrogen- and phosphorus-containing polysiloxane [(IB-co-N-MDPA)PDMS] was synthesized, and it was employed on cotton fabrics. Cone calorimeter testing showed that the treated cotton fabric with (IB-co-N-MDPA)PDMS became less flammable with longer time to ignition and lower value of HRR, THR, EHC and mass loss. Thermogravimetric analysis demonstrated that (IB-co-N-MDPA)PDMS improved the thermal and thermo-oxidative stability of cotton fabric with fewer flammable volatiles, and more char is produced during combustion. Scanning electron microscopy showed that the surface of treated cotton fabric after combustion was covered by a compact char layer which indicated that (IB-co-N-MDPA)PDMS favored the formation of char as evidenced by the FTIR of residues. Furthermore, EDS analysis results demonstrated that the concurrent presence of Si and P in flame retardant effectively enhance the flame retardancy of cotton fabric with the remarkable amount of Si and P elements that were still present on the surface of fibers after combustion.
Starting Page	535
Ending Page	544
Page Count	10
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	123
Issue Number	1
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2015-07-24
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Flame retardancy Cotton fabric Cone calorimeter Thermal analysis Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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