NDLI: Elaborated studies on nano-sized homo-binuclear Mn(II), Fe(III), Co(II), Ni(II), and Cu(II) complexes derived from N$_{2}$O$_{2}$ Schiff base, thermal, molecular modeling, drug-likeness, and spectral

Content Provider	Springer Nature Link
Author	Shah, Reem K. Abou Melha, Khlood S. Saad, Fawaz A. Yousef, Tarek Al Hazmi, Gamil A. A. Elghalban, Marwa G. Khedr, Abdalla M. El Metwaly, Nashwa
Copyright Year	2015
Abstract	A series of new homo-binuclear nano Mn(II), Fe(III), Co(II), Ni(II), and Cu(II) complexes were synthesized using a Schiff base ligand derived by condensation of p-phenylenediamine with 2-hydroxy-1-naphthaldehyde. The prepared complexes were characterized using elemental, thermal analyses, FTIR, $^{1}$HNMR, $^{13}$CNMR, UV–Vis, XRD, SEM, molar conductance, and magnetic moment measurements. FTIR spectral studies revealed the interaction of the ligand as bi-negative tetra-dentate towards Mn(II) and Fe(III) atoms, whereas the ligand molecule coordinates in neutral tetra-dentate mode towards Co(II), Ni(II), and Cu(II) ions. The geometries proposed are mainly octahedral configuration surrounds the central atoms referring to the electronic spectral data and magnetic measurements. The calculations abstracted from XRD patterns propose the nano-sized complexes. The SEM images show the nano-sized appearance of the particles except for the Ni(II)-complex. Thermo-gravimetric analysis was used to ensure the nature of the presence of solvent molecules attaching to the complexes. Molecular modeling was performed to assert the structural formula proposed for the ligand and some of its complexes. Also, drug-likeness was theoretically estimated to display the probable biological activity of the free ligand through a theoretical comparison with known drugs.
Starting Page	731
Ending Page	743
Page Count	13
File Format	PDF
ISSN	13886150
Journal	Journal of thermal analysis
Volume Number	123
Issue Number	1
e-ISSN	15882926
Language	English
Publisher	Springer Netherlands
Publisher Date	2015-07-14
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Schiff base complexes Spectral Thermal Molecular modeling studies Physical Chemistry Analytical Chemistry Polymer Sciences Inorganic Chemistry Measurement Science and Instrumentation
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Condensed Matter Physics

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