NDLI: Synthesis and characterization of organic nonlinear optical material: urea para-nitrophenol

Content Provider	Springer Nature Link
Author	Selvakumar, S. Leo Rajesh, A.
Copyright Year	2016
Abstract	The organic nonlinear single crystals of urea para-nitrophenol (UPN) have been grown using slow evaporation solution growth technique. The formation of the organic product has been confirmed by CHN analysis. The structure of grown crystal was examined by single-crystal X-ray diffraction technique. The presences of functional groups were identified from FT-IR spectrum. The large transmittance properties of the crystal and its linear band gap energy of 3.18 eV inform that the material is suitable for optoelectronic applications. The TG–DTA curve confirms that the grown crystal was thermally stable up to 120 °C. Dielectric constant and dielectric loss values were also measured as a function of frequency between 5 Hz and 5 MHz and temperature from 40 to 100 °C. The second-harmonic generation efficiency of the UPN crystal is found to be 3.5 times greater than that of KDP crystal. The NLO parameters intensity dependent refractive index (n$_{2}$), nonlinear absorption coefficient (β) and third-order susceptibility \|χ $^{3}$\| were calculated using Z-scan techniques. The morphology of its UPN crystal was studied using SEM analysis.
Starting Page	7509
Ending Page	7517
Page Count	9
File Format	PDF
ISSN	09574522
Journal	Journal of Materials Science: Materials in Electronics
Volume Number	27
Issue Number	7
e-ISSN	1573482X
Language	English
Publisher	Springer US
Publisher Date	2016-03-30
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Optical and Electronic Materials Characterization and Evaluation of Materials
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering

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