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| Content Provider | Springer Nature Link |
|---|---|
| Author | Żukowski, P. Kołtuwicz, T. N. Kierczyński, K. Rogalski, P. Subocz, J. Szrot, M. Gutten, M. Sebok, M. Korenciak, D. |
| Copyright Year | 2016 |
| Abstract | The paper presents an analysis of test results by Frequency Domain Spectroscopy (FDS) of the loss tangent (tgδ) in electrotechnical pressboard impregnated with insulating oil and containing nanoparticles of water depending on the frequency of alternating current, sample temperature and degree of moisture. We found tgδ reduction in areas of low and ultra-low frequency. It is associated with relaxation due to the hopping conductivity (tunnelling) of electrons between moisture nanoparticles occurring in the cellulose impregnated with insulating oil. In frequency areas close to the local minimum of tgδ and higher, relaxation does not depend on the moisture content and is associated with other polar molecules which are part of the cellulose. We developed a new method converting experimental frequency dependence of the loss angle tangent, measured by the FDS method to the reference temperature of 293 K (20 °C), using the exponential dependence of the relaxation time on the temperature, was developed. The activation energy of the relaxation time was determined based on the loss angle tangent of moist electrotechnical pressboard impregnated with insulating oil. It was found that the variation in moisture content in the composite cellulose–mineral oil–water nanoparticles do not cause changes in the activation energy of the relaxation time. The conversion of experimental frequency dependence of the loss angle tangent determined by the FDS method to the reference temperature of 293 K (20 °C) eliminates the temperature dependence in the areas of ultra-low and low frequencies occurring in the runs made directly on the basis of the measurement results. After calculating the frequency dependence of the loss angle tangent to the reference temperature, all that remains is its dependence on the moisture content. |
| Starting Page | 1609 |
| Ending Page | 1616 |
| Page Count | 8 |
| File Format | |
| ISSN | 09690239 |
| Journal | Cellulose |
| Volume Number | 23 |
| Issue Number | 3 |
| e-ISSN | 1572882X |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2016-04-07 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | FDS Electrotechnical pressboard Moisture content Loss angle tangent Relaxation time Activation energy Reference temperature Bioorganic Chemistry Physical Chemistry Organic Chemistry Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Polymers and Plastics |
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