NDLI: Synthesis and characterization of cellulose-g-polyoxyethylene (2) hexadecyl ether solid

Content Provider	Springer Nature Link
Author	Han, Na Li, Zhinan Zhang, Xingxiang Yu, Wanyong Chen, Xiaoying Wang, Dong Li, Junbao
Copyright Year	2016
Abstract	A series of novel solid–solid phase change materials, namely, cellulose-g-polyoxyethylene (2) hexadecyl ether (Cellulose-g-E2C16) copolymers, were synthesized using toluene 2,4-diisocyanate (TDI) as a coupling reagent in the ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The optimum prepolymerization conditions were determined to be 25 °C and 75 min without catalyst, and the optimum reaction conditions of the grafting step were 90 °C, 6 h and 0.1 wt% dibutyltin dilaurate (DBTDL, weight percent of TDI). The successful grafting was confirmed by FTIR and 1H-NMR. The properties of the Cellulose-g-E2C16 copolymers were investigated by DSC, TG and XRD. It is shown that the heat storage ability and phase change temperature of Cellulose-g-E2C16 copolymers depended on the degree of substitution. The crystalline type of the grafted E2C16 was not affected by the cellulosic backbone. Compared with E2C16, Cellulose-g-E2C16 copolymers showed better thermal stability. They are expected to be widely applied in the area of thermal energy storage.
Starting Page	1663
Ending Page	1674
Page Count	12
File Format	PDF
ISSN	09690239
Journal	Cellulose
Volume Number	23
Issue Number	3
e-ISSN	1572882X
Language	English
Publisher	Springer Netherlands
Publisher Date	2016-04-11
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cellulose Polyoxyethylene (2) hexadecyl ether Grafting Phase change Bioorganic Chemistry Physical Chemistry Organic Chemistry Polymer Sciences
Content Type	Text
Resource Type	Article
Subject	Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Effects of Fatty Acid Anhydride on the Structure and Thermal Properties of Cellulose-g-Polyoxyethylene (2) Hexadecyl Ether

Polyethylene glycol grafted cotton as phase change polymer

Antifungal cellulose by capsaicin grafting

Controlled grafting of MMA onto cellulose and cellulose acetate

Grafting onto microfibrils of native cellulose

Characterization of cellulose by SEC-MALLS

UV light-induced grafting of fluorinated monomer onto cellulose sheets

Synthesis and characterization of alkyl cellulose ω-carboxyesters for amorphous solid dispersion

Extensional rheometry of cellulose ether solutions: flow instability

Synthesis and characterization of cellulose-g-polyoxyethylene (2) hexadecyl ether solid–solid phase change materials

Similar Documents

Effects of Fatty Acid Anhydride on the Structure and Thermal Properties of Cellulose-g-Polyoxyethylene (2) Hexadecyl Ether

Polyethylene glycol grafted cotton as phase change polymer

Antifungal cellulose by capsaicin grafting

Controlled grafting of MMA onto cellulose and cellulose acetate

Grafting onto microfibrils of native cellulose

Characterization of cellulose by SEC-MALLS

UV light-induced grafting of fluorinated monomer onto cellulose sheets

Synthesis and characterization of alkyl cellulose ω-carboxyesters for amorphous solid dispersion

Extensional rheometry of cellulose ether solutions: flow instability

Synthesis and characterization of cellulose-g-polyoxyethylene (2) hexadecyl ether solid–solid phase change materials