NDLI: Charge transfer dye-based PHEMA hydrogel sensor: its fluorescence responses to pH, metal ion, and humidity

Content Provider	Springer Nature Link
Author	Baek, Chang Hoon Moon, Byoung Cheon Lee, Wang Eun Kwak, Giseop
Copyright Year	2012
Abstract	Poly(2-hydroxyethylmethacrylate) (PHEMA) is one of the most well known synthetic hydrogels. In this study, PHEMA gel containing a charge transfer dye was synthesized using a copolymerization method. This polymer gel swelled appropriately in water with a swelling ratio (Q) of approximately 1.0, and swelled significantly in aprotic polar solvents, such as DMF and DMSO, with Q values of >8.0, whereas it never swelled in nonpolar solvents. The fluorescence (FL) emission band of the hydrogel polymer showed a red shift exclusively in water, whereas it showed a blue shift in the other solvents tested. The emission band also shifted to shorter wavelengths with increasing proton activity (with decrease in pH) or iron cation concentration, and the FL intensity increased gradually. The FL intensity also decreased significantly with increasing absolute humidity.A charge transfer dye-based PHEMA gel was synthesized using a copolymerization method. The FL emission band of the hydrogel polymer showed a red shift exclusively in water. The emission band shifted to shorter wavelengths with increasing in proton activity or iron cation concentration and the FL intensity gradually increased. The FL intensity deceased significantly with increasing absolute humidity.
Starting Page	71
Ending Page	79
Page Count	9
File Format	PDF
ISSN	01700839
Journal	Polymer Bulletin
Volume Number	70
Issue Number	1
e-ISSN	14362449
Language	English
Publisher	Springer-Verlag
Publisher Date	2012-08-14
Publisher Place	Berlin, Heidelberg
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Charge transfer dye PHEMA Hydrogel sensor PH Metal ion Humidity Polymer Sciences Soft and Granular Matter, Complex Fluids and Microfluidics Characterization and Evaluation of Materials Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry Condensed Matter Physics Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Enhanced adsorption properties of interpenetrating polymer network hydrogels for heavy metal ion removal

Drug release characteristics of modified PHEMA hydrogel containing tethered PEG sulfonate

Preparation and properties of PEG-modified PHEMA hydrogel and the morphological effect

Drug release characteristics of modified PHEMA hydrogel containing thermo-responsive pluronic copolymer

Synthesis and fluorescence properties of a waterborne polyurethane–acrylic hybrid polymeric dye

Modified hydrogels based on poly(2-hydroxyethyl methacrylate) (pHEMA) with higher surface wettability and mechanical properties

Synthesis and characterization of biodegradable pHEMA-starch composites for immobilization of L-asparaginase

Synthesis and optical properties of pH-responsive conjugated polyampholytes

Conjugated polymer-hybridized silica nanoparticle as a fluorescent sensor for cysteine

Charge transfer dye-based PHEMA hydrogel sensor: its fluorescence responses to pH, metal ion, and humidity

Similar Documents

Enhanced adsorption properties of interpenetrating polymer network hydrogels for heavy metal ion removal

Drug release characteristics of modified PHEMA hydrogel containing tethered PEG sulfonate

Preparation and properties of PEG-modified PHEMA hydrogel and the morphological effect

Drug release characteristics of modified PHEMA hydrogel containing thermo-responsive pluronic copolymer

Synthesis and fluorescence properties of a waterborne polyurethane–acrylic hybrid polymeric dye

Modified hydrogels based on poly(2-hydroxyethyl methacrylate) (pHEMA) with higher surface wettability and mechanical properties

Synthesis and characterization of biodegradable pHEMA-starch composites for immobilization of L-asparaginase

Synthesis and optical properties of pH-responsive conjugated polyampholytes

Conjugated polymer-hybridized silica nanoparticle as a fluorescent sensor for cysteine

Charge transfer dye-based PHEMA hydrogel sensor: its fluorescence responses to pH, metal ion, and humidity