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(2,2′-Bipyridine-κ2 N,N′)bis(4-chlorobenzoato-κO)zinc
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Bi-Song Zhu, Hong-Line Dai, Dongdong Peng, Yi-Bao |
| Copyright Year | 2012 |
| Abstract | In the title compound, [Zn(C(7)H(4)ClO(2))(2)(C(10)H(8)N(2))], the Zn(II) atom is coordinated by two O atoms from two 4-chloro-benzoate ligands and two N atoms from a chelating 2,2'-bipyridine (bpy) mol-ecule in a distorted N(2)O(2) tetra-hedral geometry. The Zn(II) atom is located on a twofold rotation axis, which also passes through the mid-point of the central C-C bond of the bpy ligand. In the crystal, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine rings of the bpy ligands [centroid-centroid distance = 3.642 (3) Å] link the complex mol-ecules into a two-dimensional supra-molecular structure parallel to (100). An intra-molecular C-H⋯O hydrogen bond is also observed. |
| Starting Page | m321 |
| Ending Page | m322 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S160053681200699X |
| PubMed reference number | 22412459 |
| Journal | Medline |
| Volume Number | 68 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/a1/9b/e-68-0m321.PMC3297269.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S160053681200699X |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
