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(2,2′-Bipyridine-κ2 N,N′)tetrakis(dimethyl sulfoxide-κO)copper(II) bis(perchlorate)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Iskenderov, Turganbay S. |
| Copyright Year | 2013 |
| Abstract | The title compound, [Cu(C2H6OS)4(C10H8N2)](ClO4)2, contains a Cu(II) ion with a distorted octa-hedral coordination environment, bonded by four O atoms of the monodentate dimethyl sulfoxide ligands and two N atoms of the bidentate chelating 2,2'-bi-pyridine ligand. The equatorial Cu-N and Cu-O bond lengths are in the range 1.979 (2)-1.998 (3) Å. The axial Cu-O bond distances are 2.365 (2) and 2.394 (2) Å. In the crystal, the complex cations and perchlorate anions are connected by numerous C-H⋯O hydrogen bonds, which leads to additional stabilization of the structure. The perchlorate anion is disordered over two sets of sites with a 0.716 (3):0.284 (3) occupancy ratio. |
| Starting Page | m448 |
| Ending Page | m449 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536813018485 |
| PubMed reference number | 24109274 |
| Journal | Medline |
| Volume Number | 69 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/6f/aa/e-69-0m448.PMC3793687.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536813018485 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
