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Diaqua(2,2′-bipyridine-κ2 N,N′)bis(perchlorato-κO)copper(II)
| Content Provider | Semantic Scholar |
|---|---|
| Author | Damous, Maamar Hamlaoui, Meriem Bouacida, Sofiane Merazig, Hocine Daran, Jean-Claude |
| Copyright Year | 2011 |
| Abstract | The central CuN(2)O(4) motif of the title compound, [Cu(ClO(4))(2)(C(10)H(8)N(2))(H(2)O)(2)], exhibits a Jahn-Teller-distorted octa-hedral geometry around the metal atom, showing a considerably long Cu-O bond distance of 2.5058 (12) Å towards the second perchlorate group, giving a (4 + 1+1)-type coordination mode. In the crystal, the components are linked via inter-molecular O-H⋯O hydrogen bonds, forming layers parallel to (001). Additional stabilization within these layers is provided by π-π [centroid-centroid distances of 3.7848 (9)-4.4231 (9) Å] stacking inter-actions. |
| Starting Page | m611 |
| Ending Page | m612 |
| Page Count | 2 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S1600536811013808 |
| PubMed reference number | 21754328 |
| Journal | Medline |
| Volume Number | 67 |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536811013808 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |