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Calix‐Like Metal–Organic Complex for High‐Sensitivity X‐Ray‐Induced Photochromism
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Hao Wu, Xintao |
| Copyright Year | 2016 |
| Abstract | Metal-organic complexes (MOCs) as promising candidates for directly visual X-ray detection at room temperature are rare and discovered unexpectedly, even though every crystalline material needs X-ray diffraction studies. Here, we report a rational strategy of mimicking host-guest system for developing high-sensitive X-ray-induced photochromic materials. Two resulting calix-like metal-organic complexes (cMOC-1 and cMOC-2) were prepared by encapsulating the electron-capturing "guest" into the cavity of calix-like electron-donating "host." One of them (cMOC-1) achieves instantaneous X-ray-induced photochromism and easy recovery by synergizing the aprotic matrix of MOC and similar host-guest interaction. Their strikingly different response to X-ray irradiation resulting from the structural difference demonstrates the feasibility and acceptability of our design strategy. This strategy may open new perspectives for developing high-performance photo-responsive functional materials. |
| File Format | PDF HTM / HTML |
| PubMed reference number | 5063167 |
| Volume Number | 3 |
| Journal | Advanced science |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Dental caries Solute Carrier Organic Anion Transporter Family Member 1b1 |
| Content Type | Text |
| Resource Type | Article |
