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The oriented and patterned growth of fluorescent metal–organic frameworks onto functionalized surfaces
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhuang, Jinliang Friedel, Jasmin Terfort, Andreas |
| Copyright Year | 2012 |
| Abstract | A metal-organic framework (MOF) material, [Zn(2)(adc)(2)(dabco)] (adc = anthracene-9,10-dicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]-octane), the fluorescence of which depends on the loading of its nanopores, was synthesized in two forms: as free-flowing nanocrystals with different shapes and as surface-attached MOFs (SURMOFs). For the latter, we used self-assembled monolayers (SAMs) bearing functional groups, such as carboxylate and pyridyl groups, capable of coordinating to the constituents of the MOF. It could be demonstrated that this directed coordination also orients the nanocrystals deposited at the surface. Using two different patterning methods, i.e., microcontact printing and electron-beam lithography, the lateral distribution of the functional groups could be determined in such a way that the highly localized deposition of the SURMOF films became possible. |
| Starting Page | 570 |
| Ending Page | 578 |
| Page Count | 9 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://publikationen.ub.uni-frankfurt.de/opus4/frontdoor/deliver/index/docId/26345/file/2190-4286-3-66.pdf |
| PubMed reference number | 23019553 |
| Volume Number | 3 |
| Journal | Beilstein journal of nanotechnology |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Flow Fluorescence Nanocrystalline Materials Solute Carrier Organic Anion Transporter Family Member 1b1 carboxylate triethylenediamine |
| Content Type | Text |
| Resource Type | Article |
