NDLI: Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation† †Electronic supplementary information (ESI) available: Materials and methods, reaction procedures, characterization data. CCDC 1056687, 1062118. For ESI and crystallographic data in CIF or other electronic format

Content Provider	Semantic Scholar
Author	Park, Jung-Woo Kou, Kevin G. M. Kim, Daniel K. Dong, Vy M.
Copyright Year	2015
Abstract	We describe a Rh-catalyzed desymmetrization of all-carbon quaternary centers from α,α-bis(allyl)aldehydes by a cascade featuring isomerization and hydroacylation. This desymmetrization competes with two other novel olefin functionalizations that are triggered by C-H bond activation, including carboacylation and bisacylation. A BIPHEP ligand promotes enantioselective formation of α-vinylcyclopentanones. Mechanistic studies support irreversible and enantioselective olefin-isomerization followed by olefin-hydroacylation.
Starting Page	4479
Ending Page	4483
Page Count	5
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://cloudfront.escholarship.org/dist/prd/content/qt7rf2b303/qt7rf2b303.pdf?t=pcqonm
Alternate Webpage(s)	http://www.rsc.org/suppdata/c5/sc/c5sc01553g/c5sc01553g1.pdf
PubMed reference number	26508999v1
Volume Number	6
Journal	Chemical science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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