NDLI: A tandem dearomatization/rearomatization strategy: enantioselective N-heterocyclic carbene-catalyzed α-arylation† †Electronic supplementary information (ESI) available. CCDC 1858695. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc04601h

Content Provider	Semantic Scholar
Author	Wu, Zijun Wang, Jing
Copyright Year	2018
Abstract	In this study, the first example of the carbene-catalyzed tandem dearomatization/rearomatization reaction of azonaphthalenes with a-chloroaldehydes is described. This protocol enables the efficient assembly of chiral dihydrocinnolinone derivatives in good yields with excellent enantioselectivities (up to 99% ee). Moreover, this strategy enables not only the highly enantioselective NHC-catalyzed nucleophilic aromatic substitution, but also a formal Csp–Csp bond formation.
Starting Page	2501
Ending Page	2506
Page Count	6
File Format	PDF HTM / HTML
DOI	10.1039/c8sc04601h
PubMed reference number	30881680
Volume Number	10
Alternate Webpage(s)	https://pubs.rsc.org/en/content/articlepdf/2019/sc/c8sc04601h
Alternate Webpage(s)	https://doi.org/10.1039/c8sc04601h
Journal	Chemical Science
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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