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Phosphomolybdic Acid Supported on Silica Gel as an Efficient and Reusable Catalyst for Cyanosilylation of Aldehydes.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Kadam, Santosh T. Kim, Sung Soo |
| Copyright Year | 2008 |
| Abstract | Phosphomolybdic acid supported on silica gel (PMA-SiO2) is an efficient catalyst for the activation of TMSCN for the facile cyanosilylation of various aldehydes. Cyano transfer from TMSCN to aldehyde proceeds smoothly at rt in presence of 0.8 mol % of PMA-SiO2 leading to a range of cyanosilylether in excellent yield (mostly over 93%) within short reaction time (30 min). The catalyst can be recovered and reused several times without loss of activity. |
| Starting Page | 1320 |
| Ending Page | 1322 |
| Page Count | 3 |
| File Format | PDF HTM / HTML |
| DOI | 10.1002/chin.200845043 |
| Volume Number | 39 |
| Alternate Webpage(s) | http://ocean.kisti.re.kr/downfile/volume/chemical/JCGMCS/2008/v29n7/JCGMCS_2008_v29n7_1320.pdf |
| Alternate Webpage(s) | https://doi.org/10.1002/chin.200845043 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |