NDLI: Phosphomolybdic Acid Supported on Silica Gel: An Efficient, Mild and Reusable Catalyst for the Chemoselective Hydrolysis of Acetonides

Content Provider	Scilit
Author	Raghavendra, S. Satyanarayana, M. Balanarsaiah, E.
Editor	Yadav, J. S.
Copyright Year	2005
Description	Carbohydrate acetonides were chemoselectively cleaved to the corresponding diols by using environmentally benign phosphomolybdic acid $(H_{3}PMo_{12}O_{40}$) supported on silica gel $(PMA-SiO_{2}$) at ambient temperature in a short span of 5-7 minutes in acetonitrile. Acid-labile protective groups such as THP, TBS, TBDPS, MOM, OMe and PMB were found to be stable under the reaction conditions.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-2005-872701.pdf
Ending Page	2464
Page Count	4
Starting Page	2461
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-2005-872701
Journal	Synlett
Issue Number	16
Volume Number	2005
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2005-09-21
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Phosphomolybdic Acid Chemoselective Hydrolysis Silica Gel
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Phosphomolybdic Acid Supported on Silica Gel: An Efficient, Mild and Reusable Catalyst for the Chemoselective Hydrolysis of Acetonides