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Synthesis of 1-benzoylpyrene using silica-supported phosphotungstic heteropoly acid as an efficient and reusable catalyst
| Content Provider | Semantic Scholar |
|---|---|
| Author | He, Minqiang Xie, Jimin Li, Hengjun Yuan, Xinhua Cheng, X. Chen, Min |
| Copyright Year | 2012 |
| Abstract | −A novel one-pot catalytic synthesis of 1-benzoylpyrene through acylation of pyrene with benzoic anhydride catalyzed by several heteropoly acids (HPAs) was investigated. Pure 1-benzoylpyrene was obtained and its structure was identified by GC/MS, FT-IR and 1H NMR spectra. Silica-supported phosphotungstic heteropoly acid (PW/SiO2) was found to be the most active catalyst in the acylation. The yield and the selectivity of 1-benzoylpyrene were up to 62.5% and 100%, respectively. The effects of experimental parameters on the catalytic acylation reaction, and the possibility of reusability of PW/SiO2 catalyst were studied. PW/SiO2 catalyst is easily separable from the reaction mixture and reusable without loss of its activity. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://www.cheric.org/PDF/KJChE/KC29/KC29-10-1388.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |