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On the role of DMSO-O(lone pair)⋯π(arene), DMSO-S(lone pair)⋯π(arene) and SO⋯π(arene) interactions in the crystal structures of dimethyl sulphoxide (DMSO) solvates
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zukerman-Schpector, Júlio Tiekink, Edward R. T. |
| Copyright Year | 2014 |
| Abstract | Dimethyl sulphoxide (DMSO) molecules in their all-organic solvates were shown to interact with arene rings of organic molecules via DMSO-O(lone pair)⋯π(arene) or DMSO-S(lone pair)⋯π(arene) interactions in approximately 5–6% of their crystal structures, often in conjunction with conventional hydrogen bonding involving the O(DMSO) atom, resulting in zero-, one- and two-dimensional supramolecular architectures. Zero-, one- and two-dimensional supramolecular architectures were also found to be sustained by parallel SO⋯π(arene) interactions operating in combination with hydrogen bonding. |
| Starting Page | 6398 |
| Ending Page | 6407 |
| Page Count | 10 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4CE00305E |
| Volume Number | 16 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ce/c4/c4ce00305e/c4ce00305e1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C4CE00305E |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
