NDLI: Main group metal lone-pair⋯π(arene) interactions: a new bonding mode for supramolecular associations

Content Provider	Semantic Scholar
Author	Caracelli, Ignez Zukerman-Schpector, Júlio Haiduc, Ionel Tiekink, Edward R. T.
Copyright Year	2016
Abstract	Crystal structures of the heavier main group elements in low oxidation states have been evaluated for the presence of supramolecular element(lp)⋯π(arene) interactions that are structure-directing. It is revealed that when present, these interactions lead to zero-dimensional, binuclear aggregates but higher-nuclearity species are sometimes observed, with one-dimensional supramolecular chains of varying topology being prominent. By contrast, two-dimensional aggregation based on element(lp)⋯π(arene) interactions are rare. In summary, interactions of main group metal lone-pairs with aromatic rings are revealed as synthons capable of assembling molecules into supramolecular aggregates.
Starting Page	6960
Ending Page	6978
Page Count	19
File Format	PDF HTM / HTML
DOI	10.1039/C6CE01460G
Volume Number	18
Alternate Webpage(s)	http://eprints.sunway.edu.my/612/1/CEC%2018%202016%206960%20Deposited.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C6CE01460G
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Central Library (ISO-9001:2015 Certified)
Indian Institute of Technology Kharagpur
Kharagpur, West Bengal, India | PIN - 721302

See location in the Map
03222 282435
Mail: support@ndl.gov.in

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in