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Surprising behaviour of M–CO(lone pair)⋯π(arene) interactions in the solid state of fluorinated oxaphosphirane complexes
| Content Provider | Semantic Scholar |
|---|---|
| Author | Murcia-García, Cristina Bauzá, Antonio Schnakenburg, Gregor Frontera, Antonio Streubel, Rainer |
| Copyright Year | 2015 |
| Abstract | We report the synthesis and X-ray characterization of several oxaphosphirane tungsten(0) complexes especially designed to analyse the intramolecular W–CO(lone pair)⋯π(arene) interaction. The unexpected behaviour of this interaction in the solid state of oxaphosphirane complexes with different degrees of fluorination is rationalized by means of DFT calculations using orbital analysis and Bader's theory of “atoms-in-molecules”. |
| Starting Page | 1769 |
| Ending Page | 1772 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5CE00104H |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ce/c5ce00104h/c5ce00104h1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5CE00104H |
| Volume Number | 17 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |