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Synthesis and characterization of a cadmium(II)– organic supramolecular coordination compound based on the multifunctional 2-amino-5-sulfo- benzoic acid ligand
| Content Provider | Semantic Scholar |
|---|---|
| Author | Yuan, Ganyin Zhang, Lei Wang, Mengjie Zhang, Kou-Lin |
| Copyright Year | 2016 |
| Abstract | Much attention has been paid by chemists to the construction of supramolecular coordination compounds based on the multifunctional ligand 5-sulfosalicylic acid (H3SSA) due to the structural and biological interest of these compounds. However, no coordination compounds have been reported for the multifunctional amino-substituted sulfobenzoate ligand 2-amino-5-sulfobenzoic acid (H2asba). We expected that H2asba could be a suitable building block for the assembly of supramolecular networks due to its interesting structural characteristics. The reaction of cadmium(II) nitrate with H2asba in the presence of the auxiliary flexible dipyridylamide ligand N,N0-bis[(pyridin-4-yl)methyl]oxamide (4bpme) under ambient conditions formed a new mixed-ligand coordination compound, namely bis(3-amino-4-carboxybenzenesulfonatoO)diaquabis{N,N0-bis[(pyridin-4-yl)methyl]oxamideN}cadmium(II)–N,N0-bis[(pyridin-4-yl)methyl]oxamide–water (1/1/4), [Cd(C7H6NO5S)2(C14H14N4O2)2(H2O)2] C14H14N4O2 4H2O, (1), which was characterized by singlecrystal and powder X-ray diffraction analysis (PXRD), FT–IR spectroscopy, thermogravimetric analysis (TG), and UV–Vis and photoluminescence spectroscopic analyses in the solid state. The central Cd atom in (1) occupies a special position on a centre of inversion and exhibits a slightly distorted octahedral geometry, being coordinated by two N atoms from two monodentate 4bpme ligands, four O atoms from two monodentate 4-amino-3-carboxybenzenesulfonate (Hasba ) ligands and two coordinated water molecules. Interestingly, complex (1) further extends into a threefold polycatenated 0D!2D (0D is zerodimensional and 2D is two-dimensional) interpenetrated supramolecular twodimensional (4,4) layer through intermolecular hydrogen bonding. The interlayer hydrogen bonding further links adjacent threefold polycatenated twodimensional layers into a three-dimensional network. The optical properties of complex (1) indicate that it may be used as a potential indirect band gap semiconductor material. Complex (1) exhibits an irreversible dehydration– rehydration behaviour. The fluorescence properties have also been investigated in the solid state at room temperature. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://journals.iucr.org/c/issues/2016/12/00/yf3111/yf3111.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
