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Synthesis and structure characterization of two cadmium coordination polymers based on μ 2 -bridging bidentate hydrazine ligand
| Content Provider | Semantic Scholar |
|---|---|
| Author | Shanthakumar, D. Santhosh Pradeep, Rebelli Subramani, Baskaran Sivasankar, Bommasamudram |
| Copyright Year | 2018 |
| Abstract | Synthesis, single crystal structures, spectral and thermal characteristics of two cadmium coordination polymers, viz., [Cd(NO3)2(N2H4)2] (1) [Cd(C3H2O4)(N2H4)] (where C3H2O4 is malonate) (2) are reported. The μ2-bridging bidentate binding mode of the crystallographically unique hydrazine ligands in (1) leads to a one-dimensional polymeric structure extending along c axis. The central Cd(II) in (2) exhibits hepta-coordination and is bonded to a unique malonate anion which exhibits a μ3-bridging pentadentate coordination, extending the structure along the a axis. The bridging bidentate binding of the crystallographically independent hydrazine ligand extends along b axis resulting in a 2-D structure. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://nopr.niscair.res.in/bitstream/123456789/44741/2/IJCA%2057A(7)%20905-909_Suppl%20Data.pdf |
| Alternate Webpage(s) | http://nopr.niscair.res.in/bitstream/123456789/44741/1/IJCA%2057A(7)%20905-909.pdf |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
