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Temperature identification on two 3D Mn( ii ) metal–organic frameworks: syntheses, adsorption and magnetism
| Content Provider | Semantic Scholar |
|---|---|
| Author | Liu, Jian-Qiang Wu, Jian Xing Wang, Jun Daiguebonne, Carole Calvez, Guillaume Guillou, Olivier Sakiyama, Hiroshi Weng, Ng Seik Zeller, Matthias |
| Copyright Year | 2014 |
| Abstract | Two new 3-D NaCl-type frameworks of [AmineH+][Mn(HCOO)3] (AmineH+ = N(CH3)4+ for 1 and AmineH+ = NH4+ for 2) have been synthesized at different temperatures. The N(CH3)4+ cation was generated in situ by the decomposition of a large number of DMF molecules. The potential porosity of the coordination framework of 1 has been estimated using a computational method based on Connolly's algorithm, indicating that compound 1 presents a kinetic radius greater than 1.61 A. Because unremovable guest cations are clogged in the channels, 1 presents no significant adsorption for CO2 gas upon desolvation by long-duration thermal activation. In addition, the magnetic behavior of the two compounds was explored. |
| Starting Page | 20605 |
| Ending Page | 20611 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C4RA02609H |
| Volume Number | 4 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c4/c4ra02609h/c4ra02609h1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C4RA02609H |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
