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Solvent modulated assembly of two Zn metal–organic frameworks: syntheses, luminescence, and gas adsorption properties
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Liangliang Zhang, Yu Wang, Rongming Kang, Zixi Liu, Xiaobin Sun, Daofeng Meng, Qingguo |
| Copyright Year | 2015 |
| Abstract | A 2D wave-like layered framework based on benzotriazole-5-carboxylic acid (H2btca), 2,2′-bipy and zinc ions – [Zn(btca)(2,2′-bipy)]n (1) – has been resoundingly designed and synthesized by a solvothermal method. By changing the solvent from DMF to DMA, a 3D porous framework – [Zn2(btca)2(bpy)(H2O)]n·n(DMA) (2) – was obtained. Complexes 1 and 2 have been determined by single-crystal X-ray diffraction analysis and further characterized by powder X-ray diffraction (PXRD), elemental analysis, IR spectroscopy, and thermogravimetric (TG) analysis. Complex 1 shows an AA packing 2D layered structure and complex 2 displays a 3D open honeycomb framework with a (3,4)-connected 2-nodal fsc topology. Moreover, gas adsorption of 2a (the activated form of 2) and the luminescence properties of 1, 2 and 2a have also been investigated intensively. |
| Starting Page | 6591 |
| Ending Page | 6597 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5CE00833F |
| Volume Number | 17 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ce/c5ce00833f/c5ce00833f1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5CE00833F |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
