Mn(II) metal–organic frameworks based on Mn3 clusters: from 2D layer to 3D framework by the “pillaring” approach

Content Provider	Semantic Scholar
Author	Chen, Yong-Qiang Liu, Sui-Jun Li, Yun-Wu Li, Guo-Rong He, Kun-Huan Chang, Ze Bu, Xian-He
Copyright Year	2013
Abstract	Two complexes {[Mn3(btcit)2(H2O)2(DMF)2]·2DMF}∞ (1) and {[Mn3(btcit)2(bib)2]·2DMF}∞ (2) (H3btcit = 4,4′,4′′-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid, bib = 1,4-bis(imidazol-1-yl)benzene) were obtained under the same reaction condition. Complex 1 is a two dimensional (4,4) network constructed from linear Mn3 units and btcit ligands. Complex 2, which presents an interesting two-fold interpenetrating three dimensional framework with fsf topology, was obtained by modifying complex 1 with a “pillaring” approach. Moreover, the magnetic properties of 1 and 2 have been investigated and both of them show antiferromagnetic behaviour.
File Format	PDF HTM / HTML
DOI	10.1039/C2CE26734A
Alternate Webpage(s)	http://www.rsc.org/suppdata/ce/c2/c2ce26734a/c2ce26734a.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C2CE26734A
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article