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Metal-free TEMPO-catalyzed oxidative C-C bond formation from Csp3-H bonds using molecular oxygen as the oxidant.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zhang, Bo Cui, Yuxin Jiao, Ning |
| Copyright Year | 2012 |
| Abstract | An efficient TEMPO-catalyzed oxidative C-C bond formation with two Csp(3)-H bonds using molecular oxygen as the oxidant has been developed. The novel transformation provides a new strategy for the TEMPO-O(2) catalysis to construct C-C bonds. The advantages of this method include: (1) relatively mild and neutral conditions; (2) simplicity and safety of operation; (3) a stoichiometric amount of dangerous oxidants, any transition metals, additives, even solvent, is not required. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c2cc30684k |
| PubMed reference number | 22453837 |
| Journal | Medline |
| Volume Number | 48 |
| Issue Number | 37 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/c2/c2cc30684k/c2cc30684k.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c2cc30684k |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |