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Metal-free oxidative C–C bond formation of active methylenic sp3 C–H bonds with benzylic sp3 C–H and allylic sp3 C–H bonds mediated by DDQ
| Content Provider | Semantic Scholar |
|---|---|
| Author | Ramesh, D. Ramulu, Udugu Rajaram, Singanaboina Prabhakar, Peddikotla Venkateswarlu, Yenamandra |
| Copyright Year | 2010 |
| Abstract | Abstract An efficient and simple method for the oxidative coupling of benzylic and allylic sp 3 C–H bonds with active methylenic sp 3 C–H bonds under metal-free conditions was developed by employing 2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) as an oxidant. The reaction was shown to proceed smoothly for various 1,3-dicarbonyl compounds with a range of benzylic and allylic substrates in good to excellent yields. |
| Starting Page | 4898 |
| Ending Page | 4903 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1016/j.tetlet.2010.07.080 |
| Volume Number | 51 |
| Alternate Webpage(s) | http://www.cs.gordon.edu/~ijl/_lead_papers/Metal-free%20oxidative%20C_C%20bond%20formation%20of%20active%20methylenic%20sp3%20C_H%20bonds%20with%20benzylic%20sp3%20C_H%20and%20allylic%20sp3%20C_H%20bonds%20mediated%20by%20DDQ.pdf |
| Alternate Webpage(s) | https://doi.org/10.1016/j.tetlet.2010.07.080 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
