NDLI: INVESTIGATION AND OPTICAL EVALUATION OF PRECURSORS FOR THE PHOTODEPOSITION OF NANOSIZED ZnS AMORPHOUS THIN FILMS

Content Provider	Scientific Electronic Library Online (SciELO)
Author	TEJOS R, MARISOL ROLÓN, BÁRBARA G DEL RÍO, RODRIGO CABELLO, GERARDO
Abstract	Thin amorphous nanostructured ZnS films have been photochemically obtained by means of direct UV radiation (X= 254 nm) of the complex Zn [ (CH3)2CHCH2OCS2 ]2 deposited on Si(100) and on ITO glass through the spin-coating technique. The UV photolysis of thin films of Zinc Xanthate complex results in the loss of all ligands from the coordination sphere. The binding energy values for as-deposited films in X-Ray Photoelectron Spectra were 1022.7 eV for Zn2p3 and 163-169 eV for S 2p. The as-deposited film showed a non-uniform rough surface with a root-mean-square (rms) roughness of 48.5 nm and a maximum height, Rmax, of 460.5 nm. The annealed ZnS films showed a uniform and a reasonably light but smooth surface with a rms roughness of 43.0 nm and Rmax of 274.2 nm. The optical band gap was determined and found to be 3.2 ± 0.01 eV and 3.25 ± 0.01 eV
Related Links	https://scielo.conicyt.cl/scielo.php?script=sci_abstract&pid=S0717-97072007000300015&lng=en&nrm=iso https://scielo.conicyt.cl/scielo.php?script=sci_arttext&pid=S0717-97072007000300015&lng=en&nrm=iso
Starting Page	1257
Ending Page	1260
Page Count	4
File Format	PDF
ISSN	07179707
DOI	10.4067/S0717-97072007000300015
Journal	Journal of the Chilean Chemical Society
Issue Number	3
Volume Number	52
Language	English
Publisher	Sociedad Chilena de Química
Publisher Date	2007-09-01
Publisher Institution	Universidad de Valparaíso Facultad de Ciencias Universidad de Guanajuato FIMEE Universidad Católica de Valparaíso Instituto de Química Universidad del Bio Bio Facultad de Ciencias Departamento de Ciencias Básicas
Publisher Place	Chile México
Access Restriction	Open
Subject Keyword	Amorphous Materials Photochemistry Synthesis Atomic Force Microscopy Optical Properties
Content Type	Text
Resource Type	Article
Subject	Chemistry

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