NDLI: Surface-initiated controlled radical polymerizations from silica nanoparticles, gold nanocrystals, and bionanoparticles

Content Provider	Royal Society of Chemistry (RSC)
Author	Glebe, Ulrich Böker, Alexander Wu, Lei
Copyright Year	2015
Abstract	In recent years, core/shell nanohybrids containing a nanoparticle core and a distinct surrounding shell of polymer brushes have received extensive attention in nanoelectronics, nanophotonics, catalysis, nanopatterning, drug delivery, biosensing, and many others. From the large variety of existing polymerization methods on the one hand and strategies for grafting onto nanoparticle surfaces on the other hand, the combination of grafting-from with controlled radical polymerization (CRP) techniques has turned out to be the best suited for synthesizing these well-defined core/shell nanohybrids and is known as surface-initiated CRP. Most common among these are surface-initiated atom transfer radical polymerization (ATRP), surface-initiated reversible addition–fragmentation chain transfer (RAFT) polymerization, and surface-initiated nitroxide-mediated polymerization (NMP). This review highlights the state of the art of growing polymers from nanoparticles using surface-initiated CRP techniques. We focus on mechanistic aspects, synthetic procedures, and the formation of complex architectures as well as novel properties. From the vast number of examples of nanoparticle/polymer hybrids formed by surface-initiated CRP techniques, we present nanohybrid formation from the particularly important and most studied silica nanoparticles, gold nanocrystals, and proteins which can be regarded as bionanoparticles.
Starting Page	5143
Ending Page	5184
Page Count	42
File Format	HTM / HTML PDF
ISSN	17599954
Volume Number	6
Issue Number	29
Journal	Polymer Chemistry
DOI	10.1039/c5py00525f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	CRP Atom-transfer radical-polymerization Nanoparticle Living free-radical polymerization Polymerization Polymer Drug delivery Grafting Silicon dioxide Nanoelectronics NMP Nanophotonics Chain transfer
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Biochemistry Bioengineering Biomedical Engineering Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Surface-initiated SET living radical polymerisation for the synthesis of silica–polymer core–shell nanoparticles

Preparation and characterization of dual-responsive spiropyran-based random copolymer brushes via surface-initiated atom transfer radical polymerization

Controlled grafting of polystyrene on silica nanoparticles using NMP: a new route without free initiator to tune the grafted chain length

Controlled/living radical polymerization in nanoreactors: compartmentalization effects

Surface modification of pH-responsive poly(2-(tert-butylamino)ethyl methacrylate) brushes grafted on mesoporous silica nanoparticles

One-step synthesis of Janus hybrid nanoparticles using reverse atom transfer radical polymerization in emulsion

Controlled grafting of cellulose fibres – an outlook beyond paper and cardboard

Clickable initiators, monomers and polymers in controlled radical polymerizations – a prospective combination in polymer science

An improved grafting technique for producing imprinted thin film composite beads

Surface-initiated controlled radical polymerizations from silica nanoparticles, gold nanocrystals, and bionanoparticles

Similar Documents

Surface-initiated SET living radical polymerisation for the synthesis of silica–polymer core–shell nanoparticles

Preparation and characterization of dual-responsive spiropyran-based random copolymer brushes via surface-initiated atom transfer radical polymerization

Controlled grafting of polystyrene on silica nanoparticles using NMP: a new route without free initiator to tune the grafted chain length

Controlled/living radical polymerization in nanoreactors: compartmentalization effects

Surface modification of pH-responsive poly(2-(tert-butylamino)ethyl methacrylate) brushes grafted on mesoporous silica nanoparticles

One-step synthesis of Janus hybrid nanoparticles using reverse atom transfer radical polymerization in emulsion

Controlled grafting of cellulose fibres – an outlook beyond paper and cardboard

Clickable initiators, monomers and polymers in controlled radical polymerizations – a prospective combination in polymer science

An improved grafting technique for producing imprinted thin film composite beads

Surface-initiated controlled radical polymerizations from silica nanoparticles, gold nanocrystals, and bionanoparticles