NDLI: Nanoporous carbon derived from a functionalized metal–organic framework as a highly efficient oxygen reduction electrocatalyst

Content Provider	Royal Society of Chemistry (RSC)
Author	Zhai, Quan-Guo Xie, Shilei Kong, Aiguo Feng, Pingyun Wang, Yuan Lin, Qipu Chen, Xitong
Copyright Year	2017
Abstract	High levels of iron–nitrogen doped porous carbon materials are obtained from MOF-253 using a step-by-step post-synthetic modification strategy. MOF-253 possessing open 2,2′-bipyridine nitrogen sites not only serves as a precursor but also provides chelate bonding sites for Fe2+. Followed by further impregnation of 1,10-phenanthroline, high surface area porous carbon materials are obtained. For comparison, when iron-1,10-phenanthroline species as a whole are incorporated into MOF-253, carbon materials with less active sites and low surface area are obtained. The porous carbon materials derived from MOF-253 by using a step-by-step post-synthetic modification strategy demonstrate excellent ORR activity, high selectivity (direct 4e− reduction of oxygen to water) and stability under both alkaline and acidic conditions. The onset potential of the porous carbon material under alkaline conditions (980 mV) is the same as that of Pt/C (20 wt%) (980 mV) and the half-wave potential (E1/2) is 840 mV, which is 20 mV more than that of Pt/C (20 wt%). Under acidic conditions, the onset potential and the half-wave potential are only 20 mV and 30 mV less than those of Pt/C (20 wt%). The developed step-by-step post-synthetic modification route of MOFs has expanded the ways to prepare functionalized porous carbon for energy related applications.
Starting Page	862
Ending Page	868
Page Count	7
File Format	HTM / HTML PDF
ISSN	20403364
Volume Number	9
Issue Number	2
Journal	Nanoscale
DOI	10.1039/c6nr07268b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Oxygen Bipyridine The Onset Phenanthroline Nitrogen Carbon
Content Type	Text
Resource Type	Article
Subject	Nanoscience and Nanotechnology

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Nitrogen-doped porous activated carbon derived from cocoon silk as a highly efficient metal-free electrocatalyst for the oxygen reduction reaction

A Highly Nanoporous Nitrogen-Doped Carbon Microfiber Derived from Bioresource as a New Kind of ORR Electrocatalyst

A highly efficient electrocatalyst for oxygen reduction reaction: phosphorus and nitrogen co-doped hierarchically ordered porous carbon derived from an iron-functionalized polymer.

A cobalt–nitrogen complex on N-doped three-dimensional graphene framework as a highly efficient electrocatalyst for oxygen reduction reaction

Bimetallic Metal-Organic Framework Derived Metal-Carbon Hybrid for Efficient Reversible Oxygen Electrocatalysis

N-doping nanoporous carbon microspheres derived from MOFs for highly efficient removal of formaldehyde

Nitro Lignin-Derived Nitrogen-Doped Carbon as an Efficient and Sustainable Electrocatalyst for Oxygen Reduction

Phosphate functionalized activated carbon as an efficient metal-free electrocatalyst for the oxygen reduction reaction

Biomass lysine-derived nitrogen-doped carbon hollow cubes via a NaCl crystal template: an efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions

Nanoporous carbon derived from a functionalized metal–organic framework as a highly efficient oxygen reduction electrocatalyst

Similar Documents

Nitrogen-doped porous activated carbon derived from cocoon silk as a highly efficient metal-free electrocatalyst for the oxygen reduction reaction

A Highly Nanoporous Nitrogen-Doped Carbon Microfiber Derived from Bioresource as a New Kind of ORR Electrocatalyst

A highly efficient electrocatalyst for oxygen reduction reaction: phosphorus and nitrogen co-doped hierarchically ordered porous carbon derived from an iron-functionalized polymer.

A cobalt–nitrogen complex on N-doped three-dimensional graphene framework as a highly efficient electrocatalyst for oxygen reduction reaction

Bimetallic Metal-Organic Framework Derived Metal-Carbon Hybrid for Efficient Reversible Oxygen Electrocatalysis

N-doping nanoporous carbon microspheres derived from MOFs for highly efficient removal of formaldehyde

Nitro Lignin-Derived Nitrogen-Doped Carbon as an Efficient and Sustainable Electrocatalyst for Oxygen Reduction

Phosphate functionalized activated carbon as an efficient metal-free electrocatalyst for the oxygen reduction reaction

Biomass lysine-derived nitrogen-doped carbon hollow cubes via a NaCl crystal template: an efficient bifunctional electrocatalyst for oxygen reduction and evolution reactions

Nanoporous carbon derived from a functionalized metal–organic framework as a highly efficient oxygen reduction electrocatalyst