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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Kapila, V. P. Malhotra, K. C. Puri, J. K. Paul, Ram Chand |
| Copyright Year | 1971 |
| Abstract | Tetrachlorides of selenium and tellurium form the pyramidal cation MCl3+ when dissolved in disulphuric acid. Tellurium tetrabromide disproportionates and phosphorus pentachloride forms PCl4+ ions, whereas phosphorus pentabromide forms phosphoryl bromide and iodine trichloride forms ICl2+. However, mono- and di-chlorides of sulphur and selenium disproportionate to give elements and tetrachloride. Trihalides of phosphorus are oxidised to phosphoryl halides which become protonated but trihalides of arsenic and antimony are solvolysed to form hydrogen sulphate. |
| Starting Page | 2132 |
| Ending Page | 2137 |
| Page Count | 6 |
| File Format | |
| ISSN | 00224944 |
| Volume Number | 0 |
| Journal | Journal of the Chemical Society A: Inorganic, Physical, Theoretical |
| DOI | 10.1039/J19710002132 |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Selenium Tellurium Ion Acid Tellurium tetrabromide Disproportionation Antimony pentachloride Phosphorus pentabromide Bromine Iodine trichloride Sulfur Phosphorus Arsenic Antimony Hydrogen |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Inorganic Chemistry |
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