NDLI: Kinetic studies on the interconversion of quadridentate and quinquedentate chromium(III)-EDTA (aquo) complexes and attempts to identify the sexidentate complex

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Journal of the Chemical Society A: Inorganic, Physical, Theoretical Vol -0

Growth of crystals from the gas phase. Part II. Diffusional limitations and interfacial stability in crystal growth by dissociative sublimation, with an inert third gas present

Single-crystal vibrational spectrum of tetrakis(thioacetamido)copper(I) chloride

Single-crystal Raman and far-infrared spectra of tetrakis(thiourea)nickel(II) dichloride

The carbon atom in methane

π-Allylic complexes of ruthenium

Isonitrile complexes of platinum(II) and their reactions with alcohols and amines to give carbene complexes

Ground states of σ-bonded molecules. Part XII. MINDO/1 studies of inversion barriers, rotational barriers, tautomerism, and hydrogen bonding

Synthesis and ion-exchange characteristics of stannic molybdates: separation of Fe³⁺ from Al³⁺, Ni²⁺, and Mn²⁺ and of Ce³⁺ from Pr³⁺ and Nd³⁺

Orthophosphates. Part II. The transformations brushite → fluoroapatite and monetite → fluoroapatite in aqueous potassium fluoride solution

Complexes of transition metals with Schiff bases and the factors influencing their redox properties. Part II. Nickel and cobalt complexes of some terdentate chelating ligands containing the donor atom set N₂S

Kinetics of reactions of Schiff-base complexes of iron(II). Part IV. Reaction of tris-[α-(2-pyridyl)benzylideneaniline]iron(II) complexes with cyanide in aqueous alcohols

Thermal elimination of hydrogen chloride from adducts of aromatic amines with boron trichloride with reference to borazole formation

Barriers to internal rotation in some fluorinated ethanes from ultrasonic and spectroscopic measurements

The mass spectra and fragmentation patterns of silicon, germanium, and tin tetra-allyls, and tetramethyltin

Lanthanide ions as sensitive probes. Part III. Triplet-energy transfer from 2-acetonaphthone and 2-acetylfluorene to europic ions in frozen solution

A Raman spectroscopic study of dimanganese and dirhenium decacarbonyls

The crystal and molecular structure of a cyclic phosphite–borane adduct

Halogeno-, oxohalogeno-, and ethoxyhalogeno-complexes of quinquevalent protactinium, uranium, niobium, and tantalum

Crystal and molecular structure of di-µ-methylthio-(bis-π-cyclopentadienyltitanium)tetracarbonylmolybdenum

Crystal structure of triethylplatinum(IV) chloride, tetra-µ₃-chlorotetrakis[triethylplatinum(IV)]

Vibrational spectra of hexahalogenometallates. Part II. The infra-red spectra of some cubic and orthorhombic perovskite fluorides

Diffusion studies. Part II. Tracer diffusion coefficients of copper(II) in HCl and HClO₄ at 25 °C

Structures of diethylenetriaminecopper(II) cations. Part IV. Crystal structure of µ-formato-diethylenetriaminecopper(II) formate

Further studies of the metal–carbonyl bending vibrations of (π-ring)M(CO)₂X derivatives of the first-row transition metals

Complexes of metal ions with phosphorus- or arsenic-containing ligands. Part VI. Complexes of o-carboxyphenyl tertiary arsines with cobalt(II) and nickel(II)

Interaction of triphenylphosphineplatinum(0) complexes with organic azides and some carbonylation reactions

Kinetics of thallium(III)[and mercury(II)]-catalysed aquations of the chloropenta-amminecobalt(III) and cis- and trans-dichlorobis(ethylenediamine)cobalt(III) complexes

ω-Type calculations on π-electron systems with inclusion of overlap charges. Part II. Electron affinities of some alternant hydrocarbons

Electron spin resonance studies. Part XXVII. The geometry of oxygen-substituted alkyl radicals

Structure of tetrasulphur dinitride

Synthesis and ion-exchange properties of thorium tungstate: separation of La³⁺ from Ba²⁺, Sr²⁺, Ca²⁺, and Y³⁺ and of VO²⁺ from Fe³⁺ and Mn²⁺

Reaction of 2,2,6,6-tetramethylheptane-3,5-dione with hexachlorodipalladate ion

Some hydroxycyclo-octenyl complexes of palladium(II)

Crystal and molecular structure of the five-co-ordinate complex diisothiocyanato-[NN-bis-(2-diethylaminoethyl)-2-diphenylarsinoethyl-amine-NNN]-nickel(II)

Stable nickel hydride complexes of tricyclohexylphosphine and triisopropylphosphine

2,3,5-Trimethylenehexanediyl (allene trimer) hexacarbonyldi-iron complexes with no iron–iron bond

Phenylethynylberyllium complexes

Autoxidation of hydroxylamine in alkaline solutions

Crystal and molecular structure of hexaphenoxycyclotriphosphazene, [NP(OPh)₂]₃

Nuclear quadrupole resonance studies of boron–chlorine compounds. Part I. Boron trichloride and the phenylboron chlorides

Nuclear quadrupole resonance studies of boron–chlorine compounds. Part II. Chlorine-35 quadrupole resonance frequencies

Proton resonance studies of the Schlenk equilibria for methyl- and ethyl-zinc iodide in tetrahydrofuran

Studies on Grignard reagents. Part III. Proton resonance spectra of alkyl and aryl Grignard reagents

Molecular orbital calculations on distorted hydrogen bonds in the water dimer

Heteronuclear transition-metal complexes. Part I. Di-µ-organothio-(bis-π-cyclopentadienyltitanium)tetracarbonyl complexes of group VI, (π-C₅H₅)₂Ti(SR)₂M(CO)₄

The chemistry of vitamin B₁₂. Part XII. The co-ordination of nitrogenous bases

Unstable intermediates. Part LXXXII. Electron spin resonance spectra of the species Br₂^–, I₂^–, BrOH^–, and IOH^– in γ-irradiated frozen aqueous solutions of alkali-metal halides

Metal–carbonyl and metal–nitrosyl complexes. Part X. Photochemical generation of organometallic nitrenes and the crystal structure of a carbonylation product, isocyanatocarbonyl-π-cyclopentadienylbis(triphenylphosphine)molybdenum

Co-ordination compounds of indium. Part IX. Indium(III)–dithiolate complexes

Selective cleavage of metal–carbon and metal–olefin bonds in the novel dicyclopentadiene complex [Pt(C₁₀H₁₂OMe)(PPh₃)(Ph)]

Orbital modification by the coulomb field of ligand atoms of later second-row elements in perfect pairing valence states

Tritertiary arsine complexes of tervalent rhodium and iridium

Action of bistrifluoromethylphosphino-compounds on pentacarbonylmanganese hydride

Palladium(II) chelate complexes derived from 3-hydroxyiminopentane-2,4-dione and some related complexes

Mass spectrometric studies of the phosphorus sulphides

Crystal and molecular structure of tetraphosphorus pentaselenide

Shock tube pyrolyses. Part II. Thermal decompositions of isopropyl, n-butyl, isobutyl and t-butyl fluorides

Photolysis of methylcobalamin

Preparation and infrared spectra of some Group IV metal–tricarbonylnitrosyliron derivatives

Magnetic and spectral properties of nickel(II) complexes with bridging nitrite groups

Structural studies of metal diselenocarbamates. Crystal and molecular structures of nickel(II), copper(II), and zinc(II) diethyldiselenocarbamates

Nuclear magnetic resonance studies on fluorine-containing compounds. Part III. The tetrafluoro-oxovandate(V) ion

Kinetics of complex formation of molybdate and tungstate with 8-hydroxyquinolines

Kinetic studies on the reaction of Cr²⁺ with the µ-amido-µ-sulphato- and µ-amido-µ-selenato-bis[tetra-amminecobalt(III)] complexes

Molecular adsorption cross section and orientation of tetraphenylporphin and its copper derivative at mercury and air interfaces

Synthesis and some reactions of π-cyclo-octatrienyl-π-cyclo-octatetraenecobalt

The decomposition of peroxides. Part II. The effects of deformation and contamination of copper(I) oxide–copper surfaces on the decomposition of hydrogen peroxide vapour

Organonitrogen groups in metal carbonyl complexes. Part II. Di-t-butylmethyleneamino-derivatives of π-cyclopentadienyl-molybdenum and -tungsten carbonyl complexes.

Redetermination of the crystal structure of [NH₄]₂[SbCl₅]

Molecular orbital calculations on transition metal complexes. Part II. Hexa-aquometal(II) and hexa-aquometal(III) ions

Unstable intermediates. Part LXXXIV. E.s.r. study of the radical XeF in γ-irradiated XeF₂

Thermal diffusion in the n-heptane–benzene system at 25°C

Thermodynamics of protonation of amines. Values of log K, ΔH, and ΔS for the protonation of NN′- and NN-dimethylethylenediamine and NNN′N′-tetramethylethylenediamine

Thermodynamic properties of organic oxygen compounds. Part XXVI. Diethyl ether

Imidazole complexes with cobalt(II) salts

Palladium(II) complexes of azocyclohexene derivatives

The gas-phase reactions of singlet oxygen atoms with methane

Pseudo-halide complexes of transition metals. Part I. Synthesis and properties of cobalt(II), nickel(II), copper(II), and zinc(II) derivatives

Nickel(II) complexes of aromatic aldehyde oximes

Hydrogen fluoride solvent system. Part III. Solutions of the acids SbF₅, AsF₅, and PF₅. Evidence for the As₂F₁₁^– ion

Mass spectra of trimethylamine adducts of the boron trihalides and some mixed trihalides

Oxidation of n-olefins containing six to eight carbon atoms by molecular oxygen

Hydrolysis products of dibutyltin dichlorides

Reaction of alkyldicarbonylcyclopentadienyliron complexes with phosphorus ligands

Oxalato-aniline complexes of ruthenium(III)

Transition metal–carbon bonds. Part XXII. The hydrogen chloride catalysed isomerization of σ-2-methylallyl- to σ-2-methylprop-1-enyl-iridium(III) complexes

Transition metal–carbon bonds. Part XXIII. Cationic iridium(I)–ethylene and 1,3-diolefin complexes

Kinetics of the oxidation of formic acid by aquocerium(IV) ions in aqueous perchlorate media

Bonding studies of compounds of boron and the group IV elements. Part IV. Redistribution equilibria among the boron trihalides by ¹¹B nuclear resonance

Molecular orbital calculations on polypeptides and proteins. Part II. Stability and conformational structure of cis-dipeptides

Studies on the magnetic crossover in five-co-ordinate complexes of iron(II), cobalt(II), and nickel(II). Part I

Enthalpies of mixing of carbon tetrachloride with some methyl-substituted benzenes. Part III. Analysis of results by use of Flory's theory of liquid mixtures

Some vibrational spectroscopic studies on oxygen fluorides

Far-infrared spectra and single-crystal reflectance spectra of some complex chlorides containing distorted MCl₄^2– tetrahedra

Zerovalent platinum chemistry. Part IV. Bistriphenylphosphineplatinum(0) complexes with some activated mono-olefins and monoalkynes

Zerovalent platinum chemistry. Part V. Bistriphenylphosphineplatinum(0) quinone complexes

Reactivity of co-ordinated ligands. Part VI. Electrophilic substitution and addition reactions of co-ordinated cyclo-octatetraene

Kinetics and mechanism of the oxidation of methanol by aquomanganese(III) ions in aqueous perchlorate media

Dislocations in ammonium perchlorate

Dipyrromethene complexes of transition metals. Part II. Stereochemistry of complexes of cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), mercury(II), and palladium(II) and crystal structure analysis of the palladium complex

Reactions of low-valent metal complexes with fluorocarbons. Part XVI. Hexakis(trifluoromethyl)benzene–nickel complexes

Reactions of low-valent metal complexes with fluorocarbons. Part XVII. Tertiary arsine–nickel complexes

Chemistry of the metal carbonyls. Part LX. Halogeno(organo-group IVB) carbonyls of ruthenium and osmium

Semiempirical molecular orbital calculations on closed- and open-shell hydrocarbons

Studies on tertiary phosphine–hydride and –hydridoborohydride compounds of nickel and palladium

Alkynylberyllium complexes

Molecular structure of bis(trifluoromethyl)nitroxyl: an electron diffraction study

Pseudo-halide complexes of transition metals. Part II. Spectra, structure, and nature of bonding

Hückel molecular orbital study of the non-additivity of proton chemical shifts in ortho-substituted phenols

Ni(phen)₃²⁺–Co(phen)₃²⁺ system: evaluation of the dipolar proton magnetic resonance shift contribution in paramagnetic cobalt(II) complexes

Five-co-ordination with ‘hybrid’ ligands. Part VI. Cobalt(II) and nickel(II) complexes with a quadridentate tripod ligand having a NOPP donor set

Group IVB dicyanoethylene-1,2-dithiolato-complexes

Chemistry of soil minerals. Part IX. Ion exchange and ion fixation in synthetic fluorhectorites

Kinetics of the reduction of the µ-amido-µ-sulphato- and µ-amido-µ-selenato-bis[tetra-amminecobalt(III)] and sulphatopenta-amminecobalt(III) complexes with vanadium(II)

Anisotropic semiconduction in single crystals of dichlorodiamminepalladium(II)–tetrachlorodiamminepalladium(IV) and related halogen-bridged mixed-valence complexes

Effect of added gases on the photolysis of biacetyl

Zerovalent platinum chemistry. Part VI. The reactions of bis- and tris-triphenylphosphineplatinum(0) with hydrogen sulphide, hydrogen selenide, sulphur, and related molecules

Magnetic susceptibility and electron spin resonance studies on amine–copper(II) arylcarboxylates

Complexes of Bi- and ter-valent nickel with olefinic ditertiary arsines

Complexes of Bi- and ter-valent cobalt with olefinic ditertiary arsines

Molecular complexes. Part X. The crystal and molecular structure of the 1 : 1 complex of 8-hydroxyquinoline and 1,3,5-trinitrobenzene

Structure and stability of carboxylate complexes. Part II. Crystal and molecular structure of diaquobis(ethoxyacetato)copper(II)

Structure and stability of carboxylate complexes. Part III. Crystal and molecular structure of diaquobis(methoxyacetato)nickel(II) and crystal data for tetra-aquobis(phenoxyacetato)nickel(II)

Hexanitrolanthanates(III)

Organobismuth(V) compounds. Part II. Acetonyltriphenylbismuthonium perchlorate and tetrafluoroborate

Absolute configuration of the tris-(1,10-phenanthroline)nickel(II) and tris(oxalato)cobaltate(III) complex ions by X-ray structure analysis

Crystal and molecular structure of 2,2,6,6-tetrafluoro-4,4,8,8-tetramethylcyclotetraphosphazene

Crystal and molecular structure of 2,2,4,4,6,6-hexafluoro-8,8-dimethylcyclotetraphosphazene

Crystal structure of iproniazid phosphate

Further studies on the reactivity of π-cyclo-octenyl-π-cyclo-octa-1,5-dienecobalt. Formation of π-cycloheptadienyl-π-cyclo-octa-1,5-dienecobalt

π-Cycloheptadienyl-π-cyclo-octa-1,5-dienecobalt; fluxional bonding

Silyl and germyl compounds of platinum and palladium. Part I. Platinum derivatives of monosilane and monogermane

Kinetic effects of anionic ligands in some reactions of palladium(II) complexes

Mass spectra of the isothiocyanato-derivatives of trimeric and tetrameric cyclophosphazenes

Mixed halogeno-derivatives of methylgermane

Complexes of nickel(II) with o-nitrosophenols (mono-oximes of ortho-benzoquinones)

Origin of infrared emission from the reactions of atomic oxygen with carbonyl sulphide and carbon disulphide

Ionic radii from a continuum model for alkali-metal halide lattices

Redox reactions of some chromium and molybdenum dicarbonyldi-(tertiary phosphine) derivatives

The chemistry of vitamin B₁₂. Part XIV. Reaction of vitamin B_12s with nitrobenzene and its reduction products

Single-crystal electron paramagnetic resonance investigation of copper-doped calcium tetracetatocadmate(II) hexahydrate: an estimation of the orbital reduction parameters of copper(II)

Dipole moments and conformations of chlorosulphinates and chlorosulphonates

Mechanism of osmium(VIII)-catalysed oxidation of selenium(IV) by aqueous alkaline ferricyanide ion

Transition metal dithiolene complexes. Part XVIII. Adducts of cobalt and iron bis-1,2-dithiolenes containing ethyldiphenylphosphine and bis(1,2-diphenylphosphino)ethane

Positive-ion mass spectra of some polychloro-organomercurials

Some reactions of bis(tricarbonyl-π-cyclopentadienylchromium)-mercury and related compounds

Stable methylnickel complexes containing tertiary phosphine ligands

Photoelectron spectra of halides. Part I. Tetrafluorides and tetrachlorides of group IV_B

Acid-catalysed oxygen-18 exchange, racemisation, and aquation studies with the trisoxalatocobaltate(III) anion in aqueous solution

Solvent extraction from halide solutions. Part V. Temperature-dependence and dissociation of ion pairs

Infrared spectra of trimetal dodecacarbonyl species in frozen gas matrices at 20 K

Magnetic and spectroscopic studies of some lutidine complexes of cobalt(II) and nickel(II)

Thermodynamic properties of organic oxygen compounds. Part XXVII. (±)-Butan-2-ol and (+)-butan-2-ol

An ab initio study of the bonding in phosphine borane, trifluorophosphine broane and trifluorophosphine oxide

Optical rotatory power of co-ordination compounds. Part XV. Regional rules and electronic mechanisms for the optical activity of d→d transitions

Mössbauer spectra of complexes of tin(II) halides with nitrogen donor ligands

Crystal and molecular structure of the tetra-n-butylammonium salt of the cluster anion iodopentadecacarbonylhexarhodate

Manganese and rhenium dihydrobis(pyrazolylato)borate-complexes

Trimethylsilyl derivatives for the study of silicate structures. Part II. Orthosilicate, pyrosilicate, and ring structures

The chemistry of polynuclear compounds. Part XXIII. Some monomeric carboxylate derivatives of ruthenium carbonyl

Single-crystal electronic and electron spin resonance spectra of dichloroaquo-(2,9-dimethyl-1,10-phenanthroline)copper(II)

The infrared spectra of metal carbonyl compounds. Part IV. [¹³C]-and [¹⁸O]-substitution in metal carbonyls

Unstable intermediates. Part LXXXV. Electron spin resonance study of γ-irradiated sodium chlorate: librating chlorine dioxide

Unstable intermediates. Part LXXXVI. Electron spin resonance studies of the effect of γ-rays on potassium difluorophosphate: the radical PO₂F^–

Preparation and characterisation of the dinuclear dinitrogen complex, trichloro-µ-dinitrogen-bis(tetrahydrofuran){chlorotetrakis[dimethyl-(phenyl)phosphine]rhenium(I)}chromium(III)[(PMe₂Ph)₄ClReN₂CrCl₃(thf)₂]

Rhenium µ-nitrido complexes

Transition-metal dithiolene complexes. Part XIX. Mixed 1,1-/1,2-dithiolene complexes of cobalt and iron

Transition-metal dithiolene complexes. Part XX. Dicyano-1,2-dithiolene complexes of rhenium

Single-crystal Raman and far-infrared study of tetraethylammonium pentachloroindate(III)

Infrared spectra and structures of di-µ-carbonyl-(π-cyclopentadienylnickelio)carbonyl-π-cyclopentadienyliron(Ni–Fe), (π-C₅H₅)₂FeNi(CO)₃ and di-µ-carbonyl-bis-(π-cyclopentadienylnickel)(Ni–Ni), [(π-C₅H₅)Ni(CO)]₂

Molecular orbital theory of organometallic compounds. Part XII. Nature of metal–metal bonding in some binuclear metal carbonyls

Redox reaction mechanisms in non-complementary processes. Part I. Redox reactions between the tetrabromobismethylaminoplatinum(IV)–dibromobismethylaminoplatinum(II) and iron(III)–iron(II) systems in the presence of bromide ions

Reactivity of complexes containing group IIB metal–manganese bonds

Electrochemical formation of rhodium(II) complexes

Tricarbonylnitrosyliron derivatives of germanium, tin, and lead

Alkali-metal complexes. Part IV. Investigation of diethyl β-ketopropylphosphonate, diethyl phenacylphosphonate, and phenacyldiphenylphosphine oxide as ligands, and synthesis of magnesium, uranyl, and lithium complexes of phenacyldiphenylphosphine oxide

Alkali-metal complexes. Part V. Crystal structure of a potassium compound with isonitrosoacetophenone, K⁺[PhC(O)CH:NOHON:CHC(O)Ph]^–

Alkali-metal complexes. Part VI. Crystal and molecular structure of a complex formed from isonitrosoacetophenone and potassium o-nitrophenolate

Electronic absorption, polarised excitation, and circular dichroism spectra of [5]-helicene (dibenzo[c,g]phenanthrene)

π-Electron absorption and circular dichroism spectra of [6]- and [7]-helicene

Unstable intermediates. Part LXXXVII. The dipositive radical cations of gallium, thallium, and mercury derived from aqueous solutions of gallium(III), thallium(III), and mercury(II) salts at 77 K by γ-irradiation

Reactions of sulphur dioxide, nitric oxide, and dinitrogen tetroxide with some dioxygen complexes of the platinum metals: formation of sulphato-, nitro-, and nitrato-derivatives

Factors influencing the preparation of the cyclic phosphonitrilic chlorides

Covalent compounds of quadrivalent transition metals. Part II. Chromium(IV) tertiary alkoxides and triethylsilyloxide

The infrared spectra (40–3000 cm^–1) of potassium hexacyanoferrate and potassium hexacyanocobaltate

The enthalpy of formation of π-allylpalladium(I) chloride dimer and the palladium–allyl bond energy

Preparation and properties of aminodifluorophosphine

Electron diffraction determination of the molecular structures of dimethylaminodifluorophosphine and aminodifluorophosphine in the gas phase

Nitrogen nuclear magnetic resonance spectroscopy. Part IV. The azo-compounds and hyponitrite ion

Carbene complexes of iron, molybdenum, and ruthenium: a new route to metal–carbene derivatives

Mössbauer effect study of tristetraphenylphosphonium tris(dicyanoethylene-1,2-dithiolato)iron: a 1,2-dithiolene complex of iron(III)

Adducts of hexacyanoferric(II) acid, trans-dicyanotetrakis(methyl isocyanide)iron(II), and trans-dicyanotetrakis(ethyl isocyanide)iron(II) with boron trihalides. Infrared and Mössbauer spectroscopic studies

Electron paramagnetic resonance spectra of iron(III) complexes of sulphur-containing ligands

Structure of the polyhedral metal–borane complex methyltriphenylphosphonium bis(dodecahydro-nido-decaborato)zincate [Ph₃MeP]₂[Zn(B₁₀H₁₂)₂]

Investigation of the properties and thermochemistry of some complexes of aluminium hydride with tertiary amines and diamines

Molecular structure of the co-ordinated allene ligand

Reaction of silyl bromide with some group VI hydrido-anions

Metal complexes of the virus inhibitor 2-α-hydroxybenzylbenzimidazole

Preparation and substitution reactions of bis(glycinato)palladium(II) complexes

Unstable intermediates. Part LXXXVIII. Alkali-metal interaction with trapped hydrogen atoms in barium sulphate

Crystal structure of arsenic trichloride–trimethylamine, AsCl₃,NMe₃

Raman, infrared, and electronic spectra of titanium tetraiodide

Thermodynamics of the actinide elements. Part III. Heats of formation of the dicaesium actinide hexachloro-complexes

New fluoride complexes derived from the interaction of liquid hydrogen fluoride with zerovalent and divalent complexes of platinum and palladium

Interactions of hydridocarbonyltriphenylphosphine complexes of rhodium and iridium with conjugated dienes and allene

Iron(III) complexes of triphenylphosphine and triphenylarsine oxides; their electron paramagnetic resonance and vibrational spectra

Carbon compounds of the transition metals. Part XXI. The crystal and molecular structure of bis[tricarbonyl-(3-chloro-2-methylnitrosobenzene)iron]

Observations on the growth of nuclei during the thermal decomposition of nickel oxalate

Isosteric heats of adsorption for nitrogen adsorbed on microporous silica

Amido-derivatives of metals and metalloids. Part XIII. Dialkylamides of low-valent titanium: their preparation and properties

Far-infrared reflectance spectra of some hexachlorotellurates and other hexachlorometallates

Thallium derivatives of imidazole, triazole, and related heterocycles

Mechanisms of pyrolysis and bond dissociation energies in trimethylsilane

Reactions of trivinylborane with diboron tetrahalides: properties of some dihalogenoboryl(vinylboryl)ethanes

Hydrolysis of the borohydride ion catalysed by metal–boron alloys

Hydride complexes of osmium halides with carbon monoxide, dinitrogen, and tertiary phosphines as co-ligands

Some complexes of Rhodium and Iridium halides with organic sulphides (thioethers)

On the self-quenching of the first excited singlet states of aromatic molecules in the gas phase

Crystal structure of protactinium tetrabromide

σ-Bonded organotransition metal ions Part XIII. Kinetics and mechanism of the displacement of a manganese carbonyl group from saturated carbon by Mercury(II) and thallium(III) species

Orthophosphates. Part III. The hydrolysis of secondary calcium orthophosphates

Orthophosphates. Part IV. Stability relationships of orthophosphates within the systems CaO–P₂O₅–H₂O and CaF₂–CaO–P₂O₅–H₂O under aqueous conditions

Metal carbonyl chemistry. Part XV. Reactions of the dicarbonylbis-(triphenylphosphine)rhodate anion, [Rh(CO)₂(PPh₃)₂]^–, with some perfluoroaromatic compounds

Metal carbonyl chemistry. Part XVI. Reactions of Prop-2-ynyl compounds with phosphine-substituted carbonylmanganese anions and methyl- and phenyl-pentacarbonylmanganese

Growth of crystals from the gas phase. Part III. Diffusional limitations and interface stability in crystal growth by chemical vapour transport

Carbonyl substitution reactions of chlorotricarbonyl-(π-tetrahydroindenyl)molybdenum: the ‘long-range effect’ of an aromatic ring

Fluoride crystal structures. Part XV. Arsenic trifluoride–antimony pentafluoride

Single-crystal vibrational spectrum of potassium chromate

Magnetic double-resonance study of some derivatives of tungsten hexafluoride and tungsten oxotetrafluoride

The liquid hydrogen chloride solvent system. Part XIV. Reactions of π-cyclopentadienyldicarbonyliron dimer, of π-cyclopentadienylirondicarbonyl chloride, bromide, and iodide, and of π-cyclopentadienyltricarbonyliron chloride in the solvent

CNDO/2 and INDO all-valence-electron calculations on the geometry and properties of some interhalogens

Influence of electrolytic dissociation upon rates of reactions. Part VI. Acceleration of reaction between chromium(II) and hydroxylamine by the sulphate ion

The ⁵T₂–¹A₁ crossover in some iron(II)–amidine complexes: magnetic properties and Mössbauer spectra

Heat of formation of tri-isopropoxyaluminium

The hydrogenation of buta-1,3-diene on evaporated copper–nickel alloy films

Complexes of the two geometrical isomers of pyridine-2-carbaldehyde 2′-pyridylhydrazone with group vi metal carbonyls and substituted carbonyls

Transition-metal nitrosyl compounds. Part V. Nuclear magnetic resonance temperature-dependence studies on mono- and di-nitrosyl-(dithiocarbamato)-complexes of molybdenum and tungsten

Infrared and diffuse reflectance spectra of copper(II) complexes of pyridine-2-carbaldehyde oxime

Metal–carbonyl and metal–nitrosyl complexes. Part XI. Crystal and molecular structures of π-cyclopentadienyl-trans-dicarbonyliodo(triphenylphosphine)molybdenum and π-cyclopentadienyl-cis-carbonyl-chloro-[1,2-bis(diphenylphosphino)ethane]molybdenum

Metal–carbonyl and metal–nitrosyl complexes. Part XII. The crystal and molecular structure of (3-acetyl-1h-azepine)tricarbonyliron(0)

Crystal and molecular structure and magnetic anisotropy of µ-oxo-bis-[NN′-ethylenebis(salicylideneiminato)iron(III)]–dichloromethane

Electron spin resonance of a series of biscyclopentadienyltitanium(III) hydrides. Deductions from solid-state spectra

Ligand-field splittings in noncubic complexes. Part VI. Comparison of the crystal field and angular overlap treatments for eight-co-ordinate D_2d systems

Steric effects and five-co-ordination in first-row transition-metal compounds. Compounds with a linear tetra-amine ligand

The interpretation of carbon nuclear magnetic resonance shifts

Covalency factors of first-row transition-metal fluoride complex ions from electron spin resonance measurements

Transition-metal Schiff Base complexes. Part III. Nickel complexes derived from pyrrole-2-carbaldehyde and aliphatic and aromatic diamines

Substitution at saturated carbon. Part IX. Free energies of transfer from methanol to aqueous methanol of tetra-alkyltins and the transition states in the bimolecular substitution of tetra-alklytins by mercuric chloride

The chemistry of π-cyclopentadienyl nitrosyl molybdenum complexes. Compounds containing bridging iodine and sulphur ligands

Optically active co-ordination compounds. Part XXI. The oxygenation of cobalt(II)–tripeptide complexes

Crystal and molecular structure of tetra(pentafluorophenyl)cyclotetraphosphane

Infrared spectra of solid di-imide, N₂H₂, and deuteriodi-imide, N₂D₂

The co-ordination of the thiocyanate group

A kinetic study of the reaction between peroxydisulphate ion and iodine

Crystal and molecular structure of the low-spin complex isothiocyanato[NN-bis-(2-diphenylphosphinoethyl)-2-methoxyethylamine-NOPP]-nickel(II) hexafluorophosphate

Preparation and molecular structure of a new isomer of P₄S₃I₂: 3,5-di-iodo-2,6,7-trithia-1,3,4,5-tetraphosphabicyclo[2,2,1]heptane

Nuclear magnetic resonance studies on metal complexes. Part VII. The ³¹P n.m.r. spectra of some complexes of the type trans-RhCl-(CO)L₂[L = tertiary phosphine or P(OMe₃)]

Crystal structure of (Me₃Sn)₂N₂C

The Mössbauer effect in tin(II) compounds. Part IX. The sign of the quadrupole coupling constants in a number of tin(II) materials

Weak complexes of sulphur and selenium. Part I. Complex species of SO₂, SOCl₂, and SO₂Cl₂ with chloride, bromide, and iodide ions

Structures of hydrides formed by addition of an organic molecule to a transition-metal complex. Part I. Crystal and molecular structure of hydridobis-[1,2-bis(dimethylphosphino)ethane]naphthylruthenium(II) and its osmium analogue

Dialkylaminotellurium(VI) fluorides

Oxidation of addition compounds between organic sulphides and mercury(II) chloride

Peroxo-complexes: triperoxovanadates(V) complexes

A gas-phase Raman study of trimethylaluminium and trimethylboron monomers

Preparation of some anionic acetylene complexes of the Group VI metal carbonyls

Crystal and molecular structure of dichlorobis-(4-ethylpyridine)-copper(II)

Alkyl sulphide and selenide complexes of the platinum group metals

The dependence of metal–ligand bond lengths on the nature of ligand groups: centroids of overlap density in metal–ligand bonds

Hybridisation, centroids of overlap density, and the lengths of certain carbon–hydrogen bonds

Auger electron emission spectra: a simple treatment of energies and intensities

Reaction mechanisms in molten salts. Part II. Ligand replacement and redox reactions of cobalt(III) complexes dissolved in hydrogen sulphate melt and in 100% sulphuric acid

Trimethyl-silyl, -germyl and -stannyl complexes of platinum

Preparation and properties of complexes of osmium(II) with carbonyl, nitrosyl, organic cyanide and organic isocyanide ligands

Standard E.m.f.s of the cells H₂|HX|AgX–Ag (X = Cl, Br, or I) in 20 and 40%(w/w) dimethyl sulphoxide–water mixtures at 25°C

Kinetics and mechanism of the oxidation of phosphorous acid by thallium(III) in perchloric acid solutions

The preparation and reactions of nitrato-complexes of iridium(III) containing tertiary phosphines or tertiary arsines as ligands

Mössbauer spectra and structures of organotin compounds. The relationship between quadrupole splitting and intermolecular association

Electronic relaxation and molecular vibrations; transition-metal complexes and the valence shell force field

Some oxidative elimination reactions of zerovalent osmium complexes

The complex cyanides of vanadium

Crystal structure of disodium orthophosphite pentahydrate

Ligand-field splittings in noncubic complexes. Part VII. Calcium copper(II) acetate hexahydrate

Palladium(II) and platinum(II) complexes of thiocarbamic esters

Crystal structure of dichloro(O-methyl N-allylthiocarbamato)palladium(II)

Semiempirical SCF–MO treatment of excited states of aromatic compounds

Cyclogallazanes. Part II. Effect of R group on ring size of (RNHGaH₂)_n compounds

Standard potentials of the silver–silver chloride electrode in t-butyl alcohol–water mixtures and the thermodynamics of solutions of hydrochloric acid at different temperatures

Crystal and molecular structure of primary nickel dithizonate

Germyl and silyl complexes of iridium. The reactions of bis(trimethylgermyl)- and bis(trimethylsilyl)-mercury with trans-chloro(carbonyl)bis-(triethylphosphine)iridium(I)

Transition-metal complexes containing phosphorus ligands. Part IV. Convenient syntheses of some phosphine (and arsine) halogenonitrosyl derivatives of rhodium and iridium

Thermal properties of transition-metal compounds. Part V. Heat capacity measurements on [NMe₄]₂MCl₄(M = iron, cobalt, or copper), [NEt₄]₂CuCl₄, and Cs₂CoCl₄

Thermodynamic properties of organic oxygen compounds. Part XXVIII. Vapour pressure of (+)-butan-2-ol

Thermodynamic properties of fluorine compounds. Part X. Critical properties and vapour pressures of pentafluorobenzene, chloropentafluorobenzene, 2,3,4,5,6-pentafluorotoluene, and pentafluorophenol

Reactions of µ-hydroxo dicobalt complexes. Part VI. Equilibrium and kinetic studies on the reaction of chloride ions with the µ-amido-µ-hydroxo-bis[tetra-amminecobalt(III)] complex

Solid-state vibrational spectroscopy. Part I. The vibrational spectra of some halide complexes

Solid-state vibrational spectroscopy. Part II. The vibrational spectra of some chromates and dichromates

Bi₃Nb₁₇O₄₇: a potentially ferroelectric crystal structure of the tungsten bronze type

Crystal and molecular structure of bistriphenylphosphinecadmium(II) chloride

Phosphorus–fluorine chemistry. Part XXV. Synthesis and properties of fluoro-1,2,4-phosphadiazetidin-3-ones

Phosphorus-fluorine chemistry. Part XXVI. Phosphoranes involving the 1,3,2-dioxa-4,5-benzophosphole ring system

An investigation of an LCAO–MO–SCF method for co-ordination compounds based on Mulliken-type approximations

Neopentyl beryllium compounds, and complexes of methyl(-neopentyl)beryllium

Preparation of base-free beryllium alkyls from trialkylboranes. Dineopentylberyllium, bis(trimethylsilylmethyl)beryllium, and an ethylberyllium hydride

Mössbauer spectra of some organotin compounds of type R₃SnX

Amido-derivatives of metals and metalloids. Part XIV. Reactions of titanium(III) dimethylamides with protic or unsaturated reagents, or with metal hydrides

Reaction of metal-ion complexes with hydrocarbons. Part III. Palladium acetate in the oxidation and autoxidation reactions of cyclohexene, cyclohexa-1,3-diene, and cyclohexa-1,4-diene in acetic acid solution

The electronic structure of difluoromethane: ab initio studies in several basis sets and semiempirical calculations

Crystal structure of tetrabutylammonium tetraiodotriargentate, Bu₄N[Ag₃l₄]

Ultraviolet absorption spectra of iodide ions in aqueous gels

Reactions of adducts of dichloro(phenyl)borane with aromatic amines in boiling benzene

Vanadium(II) chemistry. Part III. Spectroscopic and magnetic properties of the double chlorides

Bis-π-cyclopentadienyl–molybdenum and –tungsten complexes containing sulphur, phosphorus, nitrogen or hydrogen ligands

The rate of cross combination of difluoroamino-radicals with ethyl and isopropyl radicals

Static and shock tube pyrolyses of alkyl fluorides. Part III. The thermal decomposition of 1-chloro-2-fluoroethane, 1,1-difluoroethane, and 1,1,1-trifluoroethane

Reactions of complex compounds of cobalt. Part VII. Studies of the mechanism of degradation of co-ordinated salicylic acid

Kinetics of the formation of monocomplexes of iron(III) with salicylic acid, sulphosalicylic acid, 8-hydroxyquinoline, and salicylaldehyde

Crystal and molecular structure of bis-(2,2-bipyridylamine)copper(II) perchlorate

The crystal and molecular structure of 1,4-diphenyl-3-phenylamino-1,2,4-triazolium tetrakis(isothiocyanato)cobaltate(II), [C₂₀H₁₇N₄]₂[Co-(NCS)₄]: a salt of the conjugate acid of nitron

Complexes of ruthenium halides with organic sulphides (thioethers)

The reaction of hydrogen with a jet of liquid sodium

Electrical resistivity of solutions of barium in liquid sodium

Vibrational spectra and force constants of the tetrachloroaluminate, tetrabromoaluminate, and mixed bromochloroaluminate ions

Uranyl complexes with biological ligands pyridoxine and its uranyl complexes. Part I

The kinetics of the oxidation of 2,3-dimethylbutane-2,3-diol (pinacol) by aquomanganese(III) ions in aqueous perchlorate media

Complexes with sulphur and selenium donor ligands. Part II. Crystal spectra of some tris(bidentate ligand)–metal(III) complexes

The kinetics of the reduction of the µ-amido-µ-superoxo-complexes (bipy)₂Co·µ(NH₂, O₂)·Co(bipy)₂⁴⁺ and (phen)₂Co·µ(NH₂, O₂)·Co(phen)₂⁴⁺ with Fe²⁺ and related studies

Factors affecting electron-transfer reactions between O₂^– and O₂^2– bridging ligands in binuclear complexes of cobalt(III)

Electric discharge reactions of methylsilanes

Reactions of µ-hydroxo-dicobalt complexes. Part VII. The decomposition of the µ-amido-µ-hydroxo-bis[tetra-amminecobalt(III)] complex in aqueous perchlorate solutions and related studies

Covalent compounds of quadrivalent transition metals. Part III. Chromium(IV) dialkylamides

Single-crystal electronic and electron spin resonance spectra of the square pyramidal µ-formato-mono(diethylenetriamine)copper(II) formate

Single-crystal electronic and electron spin resonance spectra of thiocyanatotriethylenetetraminecopper(II) thiocyanate

The single-crystal electronic and electron spin resonance spectra of trans-bis(monochloroacetato)bis-(2-methylpyridine)copper(II)

An improved determination of the crystal structure of hexachlorocyclotriphosphazene (phosphonitrilic chloride)

Reaction of tin(IV) and tin(II) halides with transition-metal ion Schiff-base complexes

Chemistry of methinyltricobalt enneacarbonyls. Part V. Tertiary phosphine and arsine derivatives

Thiomorpholin-3-one and thiazolidine-2-thione complexes with Group IIB metals

Substitution at saturated carbon. Part X. Substitution of tetraethyltin by mercuric chloride, iodide, and acetate in t-butyl alcohol–methanol mixtures. Kinetics, salt effects, and activation parameters

Substitution at saturated carbon. Part XI. Substitution of tetraethyltin by mercury(II) salts in acetonitrile

Crystal structure of decacarbonyl-µ-[1,2-bis(dimethylarsino)tetrafluorocyclobutene-As,As]-triangulo-triruthenium [(Me₂AsCC(AsMe₂)CF₂·CF₂)Ru₃(CO)₁₀]

Crystal and molecular structure of chloro[dodeca(dimethylamino)-cyclohexaphosphazene-NNNN]-copper(II) dichlorocuprate(I), [N₆P₆(NMe₂)₁₂Cu^IICl]⁺ Cu^ICl₂^–

Five-co-ordination with ‘hybrid’ ligands. Part VII. Cobalt(II) and nickel(II) complexes with asymmetric tripod ligands having N₂OP, N₂SP, and NOAs₂ donor sets

Metal complexes of unsaturated tertiary phosphines and arsines. Part IX. Platinum complexes of tris-olefin-phosphine, -arsine, and -stibine chelate groups

Kinetic studies on the interconversion of quadridentate and quinquedentate chromium(III)-EDTA (aquo) complexes and attempts to identify the sexidentate complex

Crystal structure of [1,2-bis(dimethylarsino)hexafluoropropane]tetracarbonylmolybdenum, Me₂AsCF(CF₃)CF₂AsMe₂·Mo(CO)₄

Crystal structure of dichloromalonamide

Some hydrido(aryl)bis-(π-cyclopentadienyl)tungsten and related compounds

Covalent compounds of quadrivalent transition metals. Part IV. Niobium(IV) dialkylamides

Solutions of soaps in organic solvents

The interaction of L-(+)-histidine methyl ester with metal ions. Part I. Formation constants

The interaction of L-(+)-histidine methyl ester with metal ions. Part II. The metal-ion catalysed base hydrolysis of L-(+)-histidine methyl ester

Features of the co-ordination chemistry of B-metals. Part I. Antimony(III) fluoride complexes

Crystal and molecular structure of [1,2-bis(diphenylphosphino)hexafluorocyclopentene]dinitrosyliron

Preparation and characterisation of some nitrogen-bridged phosphorus fluorides

Photoelectron spectra of halides. Part II. High-resolution spectra of the boron trihalides

Crystal and molecular structure of chloropentacarbonylmanganese

The spectra of complexes of conjugated ligands. Part V. Zero differential overlap calculations on α-di-imine and its iron(II) complexes

Preparation and some properties of lead thiolates

Mass spectrometry of organomercurials. Part II. Fragmentation of geminal bis(chloromercurio)-derivatives

Crystal structure and infrared spectrum of trans-diaquobis(pyridine-2-carboxamide)copper(II) chloride, [Cu(H₂O)₂(C₅H₄N·CO·NH₂)₂]Cl₂

Complexes of bis(hexafluoroacetylacetonato)copper(II) with some nitrogen-containing chelates and ethylene glycol

Crystal structure of (1-phenylbutane-1,3-dionato)(ethylene glycol)-sodium

H–F Coupling constants and hindered internal rotation in NN-dimethyltrifluoroacetamide

Dinitrogen trioxide. Part VIII. Vapour–liquid equilibria in the system dinitrogen trioxide–dinitrogen tetroxide

Dinitrogen trioxide. Part IX. Stability of dinitrogen trioxide in solution

The chemistry of π-cyclopentadienyl nitrosyl molybdenum complexes. Tertiary-phosphine and -arsine, and isonitrile complexes

Kinetics of nucleophilic attack on co-ordinated organic moieties. Part I. Addition of β-diketones on cyclic dienyl complexes

Crystal structure of µ-[1,2-bis(dimethylarsino)tetrafluorocyclobutene-AsAs]-di-µ-carbonyl-bis-(dicarbonylcobalt)(Co–Co)

Substitution at saturated carbon. Part XII. Calculation of the electrostatic contribution to free energies of transfer from methanol to aqueous methanol and to water of solutes and transition states. A new method for the examination of transition states

The Mössbauer effect in tin(II) compounds. Part X. Insertion reactions of tin(II) compounds with carbonyl-π-cyclopentadienyliron derivatives

Metallo-organic compounds containing metal–nitrogen bonds. Part VII. Synthesis and properties of bis-(NN′-diethylbutane-1,3-di-iminato) derivatives of cobalt(II)² and zinc

Kinetic studies on the reactions of indium(I) with iron(III), iodine and oxygen in aqueous solutions

Mechanism of the nitrous acid-catalysed aquation of aquochromium(III) complexes

Spectroscopic evidence for co-ordination of thiocyanate and perchlorate groups in copper(II) complexes

Arylamine co-ordination complexes. Part IV. Complexes of nickel(II) thiocyanate with substituted anilines

Crystal and molecular structure of [bis(diphenylphosphino)methane]-tetracarbonylmolybdenum

Unstable intermediates. Part LXXXIX. E.s.r. detection of paramagnetic centres formed in solids by explosive shock

Electric dipole moment and relaxation time of some ester molecules in benzene. Part II

Some symmetry aspects of homogeneous catalysis

Thermal unimolecular decomposition of bicyclo[2,2,2]oct-2-ene

Carbon–carbon bond cleavage via oxidative addition: reaction of tetrakis(triphenylphosphine)platinum(0) with 1,1,1-tricyanoethane

Steric constraints in facultative ligands. The stereochemistry of cobalt(III), nickel(II), copper(II), and palladium(II) compounds of two homologous tetra-amines with terminal pyridyl residues

Thermal transpiration data for xenon and nitrous oxide at high temperature

Stereochemistry of cobalt complexes with heteronuclear metal–metal bonds: the crystal and molecular structure of tetracarbonyl(triphenylphosphineaurio)cobalt, and of tetracarbonyl{[bis-(o-dimethylarsinophenyl)methylarsine]argentio}cobalt

Electron paramagnetic resonance and vibrational spectra of some iron(III) complexes with oxygen-containing ligands

Spectroscopic studies of some aquo-complexes of iron(III) and indium(III)

Ferric complexes of nitrogen-containing heterocyclic ligands; their electron paramagnetic resonance and vibrational spectra

The equilibrium between sodium hydrogen acetylide and disodium acetylide

The reactions of acetylene and propyne at the surface of liquid sodium

The reactions of ethylene and acetylene at the surface of solutions of barium in liquid sodium

Reactions of quinolin-8-ol with covalent halides. Part V. Iron(III) halides

Platinum and iron complexes of pentamethylcyclopentadiene and related ligands

(Pentamethylcyclopentadiene)palladium complexes

Aniline and o-allylaniline complexes of titanium tetrachloride and titanium tetrabromide

Hetero-atomic molecules: semi-empirical (π+σ) molecular orbital calculations and prediction of physical properties

Chlorine nuclear quadrupole resonance of phosphorus–chlorine compounds

The electronic and electron spin resonance spectra of complexes of the copper(II) ion with di-(2-pyridyl)amine

Generalized valence force field force constants and mean-square amplitudes of vibration of some trigonal bipyramidal XY₅ molecules calculated by the logarithmic steps method

Mössbauer effect and electron paramagnetic resonance investigation of some complexes of iron with ‘persulphide’ ligands

Dislocations in orthorhombic ammonium perchlorate

Electron impact studies on some group III metal alkyls

Crystal and molecular structure of dinitratobis(methyl-α-picolylamine)-copper(II)

The laser-Raman spectrum of pyridine adsorbed on oxide surfaces

Some cyclic tetra-amines and their metal-ion complexes. Part VII. Nickel(II) complexes of some tetra-aza-cyclotridecane derivatives

A spectroscopic investigation of complexes of tin(II) fluoride with strong Lewis acids

Reduction of buta-1,3-diene by the hexacyanodinickelate(I) anion

Thermodynamic properties of gold telluride

Crystal structure of potassium µ-nitrido-bis[aquotetrachlororuthenate(IV)]

The crystal and molecular structure of ammonium µ-nitrido-bis[aquotetrachlororuthenate(IV)]

The chemistry of polynuclear compounds. Part XXIV. Some cationic carbonyl derivatives of ruthenium

A comparison of unidentate and bidentate amines as entering groups in some reactions of dichloro(bipyridyl)platinum(II)

Five-co-ordinate complexes in transition metals. Crystal and molecular structures of two forms of dicyanotris-(5-methyl-5H-dibenzophosphole)nickel(II) and of dicyanotris-(5-ethyl-5H-dibenzophosphole)nickel-(II)

Organometallic studies. Part XXXIII. Hydrogenation of olefins and ligand exchange reactions catalysed by iron carbonyl complexes

The thermal decomposition of potassium permanganate and related substances. Part I. Chemical aspects

Nuclear magnetic resonance studies on metal complexes. Part VIII. Phosphorus–phosphorus coupling constants and other n.m.r. data for some di-t-butylphosphine–transition-metal complexes

Medium effects on activation parameters of alkaline hydrolysis of acetylmandelate ion

Heteropolytungstate complexes of the lanthanide elements. Part I. Preparation and reactions

Catalysis by rhodium(I) in nucleophilic substitutions at rhodium(III)

Crystal and molecular structure of di-µ-oxo-bis[oxo(L-cysteinato ethyl ester-N,S)-molybdenum(V)]

Crystal and molecular structure of di-µ-sulphido-bis[oxo-(L-cysteinato methyl ester-N,S)molybdenum(V)]

Antimony-121 Mössbauer spectroscopy of some chloro-complexes of antimony

Mean X–O bond lengths of the XO₄^n– tetrahedral oxyanions

The chemistry of vitamin B₁₂. Part XV. Catalysis of alkyl halide reduction by vitamin B_12a: studies using controlled potential reduction

The determination of the sign of the quadrupole interaction in some organotin(IV) compounds

A Mössbauer study of some nitrogen-containing adducts of organotin(IV) chlorides

A Mössbauer-effect study of the bonding in compounds containing tin–transition-metal bonds

Ruthenium-99 Mössbauer spectra of some nitrosylruthenium(II) compounds

Uncatalysed cis–trans isomerization of chloro-(o-tolyl)bis(triethylphosphine)platinum(II) in protic solvents

Kinetic study of the base hydrolysis reaction of fluoropenta-amminechromium(III) cation

Use and interpretation of non-rigorous force constants derived from C–O stretching frequencies of metal carbonyls. Part I. Symmetric carbonyls

Five-co-ordination in cobalt(II) complexes. Crystal structure of di-isothiocyanato-[NN-bis-(2-diethylaminoethyl)-2-methylthioethylamine-NNN]cobalt(II)

Orthophosphates. Part V. Phase equilibria in the system calcium oxide–phosphorus pentoxide–calcium fluoride–water along the fluoroapatite–hydroxyapatite join under aqueous conditions

Co-ordination numbers of cyanide complexes of zinc, cadmium, and mercury in aqueous solution

Kinetics of the equilibrium: cis-⇌trans-diaquobis(oxalato)chromate(III)

Studies in Mössbauer spectroscopy. Part IV. Signs of the quadrupole coupling constants for some organotin(IV) compounds

Calculated and observed vibrational spectra of a linear chain, bent chain, and sheet polymer (α-bismuth pentafluoride, selenium dioxide, and tin tetrafluoride respectively)

Crystal structure of di-iodo[ethylenebis(oxyethylene)]bis(diphenylphosphine)nickel(II)

Crystal and molecular structure of trans-bis[(chloroacetato)-(α-picoline)]copper(II)

Reaction of methyltitanium trichloride with some unidentate and bidentate ligands

Complexes of 1,2-dimethylimidazole with divalent cobalt, nickel, copper, and zinc

Crystal and molecular structure of dichlorotris-(1,2-dimethylimidazole)copper(II); a trigonal-bipyramidal complex showing elongation of the equatorial Cu–N bond

Organometallic compounds of bivalent europium, ytterbium, and samarium

Organotin complexes: the acceptor properties of triphenyltin isothiocyanate and diphenyltin di-isothiocyanate and the infrared spectra of complexes containing oxygen donor ligands

Heteropolytungstate complexes of the lanthanide elements. Part II. Electronic spectra: a metal–ligand charge-transfer transition of cerium(III)

The Mössbauer effect and chemistry. Part V. Spectra of some triorganotin compounds

Studies on bis(triphenyl phosphite)-π-cyclopentadienyliron derivatives and related complexes

Some unsaturated heterocyclic complexes containing two nitrogen atoms and molybdenum or tungsten

Transition metal complexes as ligands: preparation of mixed-transition-metal complexes of molybdenum or tungsten and nickel, palladium, platinum, or rhodium

Crystal and molecular structure of cis-(hydroxydiphenylgermyl)phenyl-bis(triethylphosphine)platinum(II)

Photoionization of potassium hexacyanoferrate(II)

Macrocyclic derivatives of cobalt including some new organometallic complexes

Five-co-ordinate silicon. Kinetics of the acid-catalysed hydrolysis of nitrilotriphenoxysilanes

Stabilisation of nucleophilic carbenes co-ordinated to transition metals

Carbon compounds of the transition metals. Part XXII. Crystal and molecular structure of (tetraphenylbutatriene)tetracarbonyliron

Carbon compounds of the transition metals. Part XXIII. Crystal and molecular structure of tricarbonyl(bicyclo[4,4,1]undeca-1,3,5-triene)chromium

Structure and stability of carboxylate complexes. Part IV. The crystal and molecular structure of sodium phenoxyacetate hemihydrate

Optical activity of oriented molecules

The synthesis of perhalogeno-organic borates from perhalogenoketones

The crystal structures of the acid salts of some dibasic acids. Part IV. Potassium hydrogen succinate: X-ray and neutron-diffraction studies

The crystal structures of the acid salts of some dibasic acids. Part V. Caesium hydrogen succinate monohydrate

Cyclopentadienyls of palladium and platinum

Thallium(I) derivatives of β-diketones, phenols and carboxylic acids

Exchange reaction between cyclopentane and deuterium on evaporated nickel–copper alloy films

Force-constant computations. Part II. Some model calculations to test the Fletcher–Powell method and to analyse the III-conditioned force-constant refinement

Cobalt(II) and nickel(II) complexes with the propylene-bridged tripod ligand tris-(3-dimethylaminopropyl)amine (donor set N₄)

Spectral intensities of the trivalent lanthanides. Part I. Solution spectra of heteropoly-complexes of Pr³⁺ and Ho³⁺

Vibrational and ¹H nuclear magnetic resonance spectroscopic studies of some complexes of platinum(II) and palladium(II) containing methylthio bridges

A new polynuclear oxocarbonyl containing six osmium atoms

Solutions of electrolytes in liquid ammonia. Part II. The mean molal ion activity coefficients in ammonium nitrate solutions at –40 °C

Chemistry of methinyltricobalt enneacarbonyls. Part VI. Arene derivatives

Mössbauer parameters of adducts of tin(IV) halides with amines, nitriles, phosphines, and arsines

Phosphorus-31 nuclear magnetic resonance spectra of platinum complexes containing nonequivalent phosphorus atoms and the cis-influence

Complexes formed by titanium tetrachloride with 1,4,5-trimethyltetrazaboroline and some aromatic hydrocarbons

Crystal structure of exo-tricyclo[3,2,1,0^2,4]oct-6-ene–silver nitrate, and a refinement of the silver nitrate structure

Unstable intermediates. Part XCIV. Hyperfine coupling and zero-field splitting for nitrogen atoms in γ-irradiated azides

Unstable intermediates. Part XCV. Electron spin resonance spectra assigned to the radicals POCl₃^–, POCl₂, PO₂Cl₂, PCl₂, and PCl₄ in γ-irradiated POCl₃, PCl₃, and PCl₅

Electron spin resonance studies of the pentacyanocobaltate(II) ion in various host lattices

Hammett acidity function in concentrated aqueous solutions of hydrochloric acid–lithium chloride

Crystal structures of the non-isomorphous potassium and rubidium acid salts of 5-bromo-3-hydroxy-6-methyluracil

Molecular orbital theory of organometallic compounds. Part XIII. Electronic structures and reactivities of halogenopentacarbonyl compounds of manganese and rhenium

Kinetics of substitution reactions of halogenopentacarbonyl compounds of rhenium and manganese

Silyl and germyl compounds of platinum and palladium. Part II. Some trisgermyl-complexes of six-co-ordinated platinum

Phosphine–borane derivatives. Part IV. The proton nuclear magnetic resonance and vibrational spectra of some alkylphosphine–boranes

The chemistry and structure of Chugaev's salt and related compounds containing a cyclic carbene ligand

Arylamine co-ordination complexes. Part V. Electronic spectra of complexes of nickel(II) perchlorate and halide, with substituted anilines

Crystal structure of potassium tetramolybdate, K₂Mo₄O₁₃, and its relationship to the structures of other univalent metal polymolybdates

Viscosity B-coefficients at 15 and 25 °C for glycine, β-alanine, 4-amino-n-butyric acid, and 6-amino-n-hexanoic acid in aqueous solution

Ion association of caesium chloride solutions and its effect upon the interionic frictional coefficients of an irreversible thermodynamic analysis

The vibrational spectra of dimethyltin difluoride and some related compounds

N-substituted urea complexes of thorium and uranium tetrahalides

Behaviour of inorganic and organic acid anhydrides in disulphuric acid

The nature of the solutions of some inorganic halides in disulphuric acid

Group IVB complexes of rhodium

Complexes with ligands containing group VB and VIB atoms. Part III. Complexes of cobalt(II) with thiomorpholine

Redetermination of the structure of nitrosylpenta-amminecobalt(III) dichloride

Structural and mechanistic studies of co-ordination compounds. Part II. Preparation, aquation, and base hydrolysis of trans-chloronitro- and trans-bromonitro-tetra-amminecobalt(III) cations

Electrical conduction studies on single crystals of transition-metal complexes containing linear chains of directly interacting metal atoms

The Mössbauer effect and chemistry. Part VI. Mössbauer spectra, paramagnetic susceptibilities, and electron paramagnetic resonance measurements for three iron(III) compounds of type FeCl(β-diketonate)₂

Unstable intermediates. Part XCVI. The effect of hydrogen-bonding on the e.s.r. parameters for NH₂, NH₃⁺, and H₂CN

Crystal structure of dichlorotetra-µ-adenine-dicopper(II) chloride hexahydrate

Crystal structure of tri-µ-carbonyl-pentacarbonylbis-(π-cyclopentadienylrhodio)di-iron(Rh–Rh)(Fe–Fe)(4Rh–Fe), (π-C₅H₅)₂Rh₂Fe₂(CO)₈

Crystal structures of methyltriphenylarsonium and methyltriphenylphosphonium bis-(ααα′α′-tetracyanoquinodimethanide){di-[3,6-bis(dicyanomethylene)cyclohexa-1,4-dienes]}

Crystal structure of 2,6-dichloro-4-nitroaniline

Studies on the magnetic cross-over in five-co-ordinate complexes of iron(II), cobalt(II), and nickel(II). Part II

Solvent effects on the kinetics of the reactions of nickel(II) and cobalt(II) ions with 2,2′-bipyridyl and 2,2′,2″-terpyridyl

Kinetics of solvent exchange and ligand substitution reactions of metal ions in relation to structural properties of the solvent

Kinetics of the reaction of nickel(II) ions with 2,2′-bipyridyl in water–methanol mixtures

Kinetics of the reaction of nickel(II) ion with 2,2′-bipyridyl in methanol–acetonitrile mixtures

Ionisation ratios for the protonation of a series of isothiocyanato-complexes of cobalt(III) and rhodium(III) and the protonation of azidocomplexes in aqueous solutions of different acids

Mössbauer studies of order and disorder in rutile and trirutile compounds derived from FeF₂

Crystal and molecular structures of difluorobis-(π-cyclopentadienyl)zirconium(IV) and di-iodobis-(π-cyclopentadienyl)zirconium(IV)

Magnetic susceptibilities of some rhenium(III) and osmium(IV) halide complexes; preparation of some new d⁴ complexes

Dynamic stereochemistry of allylic palladium(II) carboxylate complexes

Calculation of the vibrational frequencies of polyatomic molecules, including those of crystals

Silicon–phosphorus hydrides. Part IV. The disilylphosphinoaluminate anion

Photochemistry of tocoquinone-1

Electron spin resonance study of dimer formation by copper(II) chelates of hydroxybenzoic acids

Comparison of the transport properties of normal and expanded forms of a cation-exchange membrane by use of an irreversible thermodynamic approach. Part I. Membranes in the sodium form in 0·1M-sodium chloride

Binuclear organometallic compounds. Part III. Metal–metal bond dissociation energies, Raman, and infrared spectra for the series (π-C₅H₅)(CO)₃M¹M²Me₃: (M¹= Cr, Mo, or W; M²= Ge or Sn)

Optically active co-ordination compounds. Part XXII. Stereoselectivity in isomers of the (L-glutamate)bisethylenediaminecobalt(III) ion

Optically active co-ordination compounds. Part XXIII. Inversion at an octahedral centre

Optically active co-ordination compounds. Part XXIV. Tartrato-complexes of cobalt(III) and other transition metals

Co-ordinating tendencies of the hexafluorophosphate ion

Electron spin resonance study of chlorine radicals stabilised on an oxide surface

Trigonal-prismatic co-ordination. Crystal and molecular structure of tris-[cis-1,2-di(trifluoromethyl)ethylene-1,2-diselenato]molybdenum

Unstable intermediates. Part XC. The radicals AlR₃^–, SiR₃, and PR₃⁺: their electron spin resonance spectra and pyramidal character

Defect energies in CsCl and its solid solutions with KCl, RbCl, and CsBr

Kinetics and pressure-dependence of the t-butoxyl radical decomposition

Conformations and heats of formation of organic molecules by use of a minimal slater type basis

Far-infrared, Raman, and Mössbauer spectra of trihalogenostannate(II) complexes, [SnX₃]^–, [SnX₂Y]^–, and [SnXYZ]^–, with different cations

Molecular magnetic ellipsoid in cobalt ammonium Tutton salt

Reactions between the gallium ‘dihalides’ and ethanol

Fluoride crystal structures. Part XVI. Dibromine hexadecafluorotriantimonate(V), [Br₂]⁺[Sb₃F₁₆]^–

Structures of some hexacarbonyl-(π-dienyl)iron–cobalt complexes, [(π-ring)Fe(CO)₂Co(CO)₄], and the ruthenium compound [(π-C₅H₅)Ru(CO)₂Co(CO)₄]

Kinetics and mechanism of the reaction of hydrogen and of the homogeneous catalytic hydrogenation of ethylene with hydridocarbonyltris(triphenylphosphine)iridium(I)

Crystal and molecular structure of di-µ-iodo-bis-[(o-dimethylaminophenyl)dimethylarsine-As,N]-dicopper(I)

Cationic transition-metal complexes. Part I. Synthesis and reactions of bis(diene)-rhodium and -iridium tetrafluoroborates

Activation energy of dissolution at emergent dislocations

Reactivity of co-ordinated ligands. Part VII. Reactions of diene complexes of palladium(II) and platinum(II) with carboxylic acids

Molar volumes of ions which form long-lived solvation complexes with water

Substituted phenols as ligands. Part II. Copper(II) complexes

Some oxo-complexes of molybdenum(IV) and (V) with 1,2-bisdiphenylphosphinoethane

Crystal structure of ethyl 3,5-dinitrobenzoate

Reaction of halogenophosphinecarbonylrhenium(I) complexes with anhydrous hydrazine: preparation of isocyanato derivatives of rhenium(I)

Reaction of bromotricarbonylbis(dimethylphenylphosphine)manganese(I) with anhydrous hydrazine to yield isocyanato(dicarbonyl)hydrazinebis(dimethylphenylphosphine)manganese(I)

Some new π-cyclopentadienylruthenium complexes

Zeolitic water content and adsorptive capacity for ammonia of microporous sepiolite

Unstable intermediates. Part XCVII. Electron spin resonance spectra and structures of radicals in γ-irradiated aluminium alkyls, trialkyl phosphines, and alkylphosphonium salts

Unstable intermediates. Part XCVIII. Electron spin resonance spectra for various antimonate radicals in γ-irradiated potassium antimonate and sodium hexafluoroantimonate

Unstable intermediates. Part XCIX. Solvated electrons in solid metal–ammonia solutions

Unstable intermediates. Part C. Urea and formamide: the radicals ĊONH₂ and H₂NCONH

Infrared spectrum and photochemistry of di-iron enneacarbonyl in matrices at 20 K: evidence for the formation of Fe₂(CO)₈

Solutions in acetone. Part I. Conductances in anhydrous acetone of some perchlorates, perchloric acid, and lithium chloride at 25 °C by a four-electrode alternating current potentiometric method

Solutions in acetone. Part II. Transference numbers of potassium thiocyanate and ionic conductances in acetone at 25 °C

Further examples of unbalanced packing of chiral molecules and the crystal and molecular structure of tris(triphenylphosphine)nitrosyl-iridium

Bonding studies of compounds of boron and the Group IV elements. Part V. Boron-11 nuclear magnetic resonance data for the boron trihalides and mixed trihalides

Studies in cyclophosphazenes. Part II. The kinetics of the reactions of chlorocyclotriphosphazenes with dimethylamine in tetrahydrofuran

Magnetic anisotropy and polarized electronic spectrum of dichlorotetrakis(thiourea)nickel(II)

Reactions of oximes and diethylhydroxylamine with titanium alkoxides

The chemistry of copper(I) complexes. Part II. Halogeno-complexes containing triphenyl-arsine or -stibine

Crystal and molecular structure of bis-(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)bis-(NN-dimethylethylenediamine)copper(II)

Nuclear magnetic resonance and Raman studies of the aluminium complexes formed in aqueous solutions of aluminium salts containing phosphoric acid and fluoride ions

Transition-metal complexes of the 2,3-dipyridylquinoxalines. Part III. Cobalt(II), nickel(II), and copper(II) halide derivatives of 6-methyl-2,3-di-(2-pyridyl)quinoxaline and 6,7-dimethyl-2,3-di-(2-pyridyl)quinoxaline

Dissociation constants of anhydrous ammonium sulphite and ammonium pyrosulphite prepared by gas-phase reactions

Preparation and thermochemistry of complexes of Δ²-tetrazaborolines with titanium tetrachloride, boron trichloride, antimony pentachloride, and stannic chloride

Tetrafluoroethylene complexes of platinum(0)

The reactions of hydrogen atoms with solids at low temperature. Part I. Apparatus, hydrocarbon, and hydrogen cyanide reactions

The reactions of hydrogen atoms with solids at low temperature. Part II. Nitrogen tetroxide reactions

Nuclear magnetic resonance studies on fluorine-containing compounds. Part IV. Solutions of niobium(V) in hydrogen fluoride

Nuclear magnetic resonance studies on fluorine-containing compounds. Part V. Reactions of tantalum pentafluoride with organic donor molecules

Reactions of quinolin-8-ol with covalent halides. Part VI. Bis-π-cyclopentadienyldihalides of titanium, zirconium, and hafnium

Structural investigations of metal nitrate complexes. Part I. Crystal and molecular structure of bis[dinitratobis(pyridine)copper(II)]–pyridine [Cu(NO₃)₂(py)₂]₂,py

A search for the ⁴A₂→⁴T₂ transition in the tetrachlorocobaltate(II) ion

Crystal and molecular structure of octamethoxycyclotetraphosphazene

Cobalt(III) complexes with a tetradentate chelating system and a monodentate tertiary phosphine

Crystal structure of dimethyltin bisfluorosulphate

Carbon monoxide insertion reactions in [methoxy(cyclopentadiene dimer)]platinum(II) derivatives

Glacial acetic acid as a non-aqueous solvent for metal fluorides

Preparation and properties of the pentachlorovanadate(IV) ion and related species

ω-Nitroacetophenone as a chelating agent. Part IV. Axial and equatorial ligation in several adducts of bis(ω-nitroacetophenonato)copper(II) with heterocyclic and other N-bases

ω-Nitroacetophenone as a chelating agent. Part V. The Lewis acid-base interaction of bis(ω-nitroacetophenonato)copper(II) in solution with several heterocyclic and other N-bases

Proton magnetic resonance studies of metal-complex formation in some sulphur-containing α-amino acids

Preparation of (nonacarbonyltricobaltmethoxy)(tetracarbonylcobalt)-silicon(IV) derivatives

An electron spin resonance study of the formation of hetero-metal ion hydroxycarboxylate chelates in nonaqueous solution

Crystal and molecular structure of trichloro(π-trans-but-2-en-1,4-diammonium)platinum(II) chloride

Crystal structure of dichloro(diphenyl)tin

Complexes of thallium with unsaturated bidentate sulphur ligands

Fragmentation and rearrangement processes in the mass spectra of perhalogeno-aromatic compounds. Part V. Pentafluorophenyl derivatives of tin and related compounds

Thermal unimolecular reactions of bicyclo[3,2,0]hept-2-ene

Substitution at saturated carbon. Part XIII. Steric effects in the substitution of tetra-alkyltin compounds by mercury(II) chloride in t-butyl alcohol and in acetonitrile

An electron spin resonance study of the copper(II) complex of L-dopa and related systems formed in nonaqueous solution

Proton mobility in aqueous solutions of some alkali halides

¹H nuclear magnetic resonance study of the exchange reaction between the complex trimethylphosphine–trimethylborane and its components. Part I. Trimethylphosphine in excess

Crystal and molecular structure of the blue form of the 1 : 2 addition complex of copper(II) dichloroacetate with α-picoline

The properties of some diboron tetrafluoride–tertiary amine adducts

Aniline complexes of ruthenium(II) and ruthenium(III) halides

Effect of electrical discharge on silane and ammonia

Some reactions of di-µ-hydroxo-bis{dioxalatocobaltate(III)} in aqueous solution

Chemistry of soil minerals. Part X. Shape-selective sorbents derived from fluorhectorites

Effect of solutes on the sodium sulphate decahydrate transition temperature

Single-crystal magnetic properties of lanthanide complexes. Part III. Tri-iodohexakis(antipyrine)terbium(III)

Single-crystal magnetic properties of lanthanide complexes. Part IV. Tri-iodohexakis(antipyrine)neodymium(III)

Crystal and molecular structure of cyclopentadienyl(trimethyl)platinum(IV), (π-C₅H₅)PtMe₃

Molecular complexes. Part XI. Crystal and molecular structure of the 1 : 1 complexes of 1,3,5-trinitrobenzene and bis-(N-t-butylsalicylideneiminato)-cobalt(II), -nickel(II), and -copper(II)

Organotin halide equilibria. Part III. Comparison of the stability constants of 2,2′-bipyridyl adducts of diorganotin di-isothiocyanates and dichlorides in benzene and toluene solutions

Some benzoylazo-complexes of rhenium halides with tertiary phosphines, and related compounds

Polarography of the hydrogen ion in aqueous solutions of some tetraalkyl ammonium bromides

The [1,5] hydrogen transfer and cis–trans-isomerizations of cis-2,3-dimethylpenta-1,3-diene: the cis–trans-isomerization of penta-1,3-diene. Kinetics and equilibrium measurements

Reactions of hydrogen atoms of high translational energy with ethane

Pentacarbonylrhenium complexes of zinc, cadmium, and mercury

Fluoride crystal structures. Part XVII. Dipotassium pentafluoro-manganate(III) hydrate

Hydrogen ion–1,10-phenanthroline system. Calorimetric determination of the equilibrium constants and heats of formation of the species H(phen)_n⁺, where n= 1 or 2

Crystal structure of ferrocenylmethyl(dimethyl)ammonium tetrachlorozincate monohydrate

Binuclear organometallic compounds. Part IV. Crystal and molecular structure of chlorobis(π-cyclopentadienyl)(triphenylsilyl)zirconium(IV)

Transition metal–carbon bonds. Part XXIV. Alkenyl- and allenylplatinum(II) and alkenyl-palladium(II) complexes

Metal complexes involving the heavier donor atoms. Part IV. Stability and heats of formation of cupric complexes of semicarbazide, thiosemicarbazide, and selenosemicarbazide

Addition of alcohols and water to Schiff bases co-ordinated to copper(II). Part II. The ligands NN′-bis-(2′-pyridylmethylene)propane-1,2-diamine and NN′-bis-(2′-pyridylmethylene)-2-methylpropane-1,2-diamine

Electrical resistivity of liquid potassium and of solutions of sodium in liquid potassium: the potassium–sodium phase diagram

The sodium–barium phase diagram

Crystal and molecular structure of di-iodotris(2-diphenylphosphinoethyl)aminecobalt(II)

Normal co-ordinates for the planar vibrations of thiourea, and frequency assignment for selenourea

Reactivity of co-ordinated ligands. Part VII. Some cationic cycloocta-1,5-diene complexes of rhodium(I) and pentane-2,4-dionato-complexes of palladium(II)

The chemistry of polynuclear compounds. Part XXIV. Some cationic carbonyl derivatives of ruthenium: preparation of nonacarbonyl-[µ₃-(sulphido)-µ₂-(dihydrido)]triruthenium-(3 Ru–Ru)

Solutions of potassium fluoride in glacial acetic acid

Dinitrogen trioxide. Part X. The density of dinitrogen trioxide and its mixture with dinitrogen tetroxide and some organic solvents

Proton Knight shifts and antiferromagnetic exchange in dimeric oxygenbridged Schiff-base–iron(III) complexes

Phosphorus–nitrogen compounds. Part XXXII. The reaction of hexachlorocyclotriphosphazatriene with diphenylmagnesium in 1,4-dioxan

Crystal and molecular structure of NN′-ethylenebis(salicylideneiminato)-ethylcobalt(III)

Far-infrared reflectance spectra of A₂CuCl₄,2H₂O (A = NH₄, K, or Rb) single crystals: copper–chlorine vibrations of the distorted octahedral aquochlorocuprate(II) anion

Comments on the interaction of copper(II) chelates with chloroform as observed in the electron paramagnetic resonance spectra

Molecular orbital calculations on transition-metal complexes. Part III. Hexafluorometallate-(III) and -(IV) ions

Vibrational spectra of dihalogeno-anions of copper(I) and silver(I) in solution in tri-n-butyl phosphate

Orthophosphates. Part VIII. The transformation of newberryite into bobierrite in aqueous alkaline solutions

Covalent compounds of quadrivalent transition metals. Part V. Molybdenum(IV) dialkylamides

Some metal complexes of morpholine-4-carbodithioate

Cationic complexes of iridium. Part III. Some thiocarbonyl complexes

Crystal structure of trisodium phosphonoformate hexahydrate, Na₃PO₃CO₂,6H₂O

The ferricyanide–sulphite reaction

Single-crystal electronic and electron spin resonance spectra of bis(ethoxyacetato)bisaquocopper(II)

Crystal structure of tris(tetraethylammonium) tris-(1,2-dicyanoethylene-1,2-dithiolate)indate(III)

Chromium(II) chemistry. Part VIII. Complexes of 1,3-diaminopropane and some carbon- and nitrogen-substituted ethylenediamines

An electron spin resonance study of vanadium(II). Part IV. Lattice sites of dipositive ions vanadium(II) and manganese(II) in lithium and sodium fluoride crystals, and effects of X-irradiation

The surface chemistry of manganese

Fluorite formation in biological and mineralogical systems. Part I. The transformation calcite → fluorite in aqueous fluoride solutions

Far-infrared single crystal reflectance spectra of some tetra-alkylammonium tetrachlorometallates; influence of crystal field effects and distortion on the vibrations of the ‘tetrahedral’ anions

An electron spin resonance study of dimeric titanium(III) complexes

Preparation and crystal structure of osmium pentaluoride

The vibrational spectra of hexagonal perovskites. Part I. Single-crystal infrared reflectance and Raman spectra of complex halides having the CsNiCl₃ structure

Molybdenum(IV) oxo-complexes. Part I. Crystal and molecular structure of the blue isomer of oxodichlorotris(dimethylphenylphosphine)-molybdenum(IV), cis-mer-[MoOCl₂(PMe₂Ph)₃]

A survey study of the vibrational spectra of some aquo-halogenocomplexes

Transition metal complexes as ligands: mixed metal complexes of molybdenum or tungsten and iron or cobalt

Effect of temperature on the chemical changes accompanying nuclear isomeric transition (^121mTe, ^127mTe, and ^129mTe decay) in crystalline telluric acid

Optically active co-ordination compounds. Part XXV. Some reactions of isothiocyanate ion co-ordinated to cobalt(III)

Optically active co-ordination compounds. Part XXVI. Determination of the optical purity of cobalt complexes by the method of isotope dilution

ortho-Metallation reactions. Part II. Some ruthenium complexes containing the phenylazophenyl group

Reactions of low-valent metal complexes with fluorocarbons. Part XVIII t-Butyl isocyanide–nickel complexes

Complexes of nickel(II) with some 1,5,8,12-tetra-azacyclotetradecane derivatives; two isomeric cyclic tetraimines and a cyclic tri-iminemonoamine

The electron spin resonance spectra of β-diamminecopper(II) halides diluted in ammonium halides; bonding parameters

Metal atom vibrations in transition metal clusters and complexes by inelastic neutron scattering spectroscopy

The formation of hydridopentacyanorhodate(III): a reappraisal of the formation of hydridoaquotetracyanorhodate(III)

The acid-catalysed hydrolysis of nitro- and nitrito-pentammine complexes of cobalt(III), rhodium(III),and iridium(III)

Antimony halides as solvents. Part VIII. Spectral studies of polycyclic hydrocarbons in liquid antimony trichloride solution

Disproportionation–combination ratios of difluoroamino-radicals with isopropyl and with t-butyl radicals

A new and simple method of preparing dichlorophosphinylphosphorimidic trichloride

Hydration number of aluminium(III) in dilute aqueous solution

Phosphorus–fluorine chemistry. Part XXVIII. Fluorophosphines with bulky substituents as ligands in transition metal carbonyl complexes

Chemistry of the metal carbonyls. Part LXI. Organogermanium (carbonyl)-ruthenium and -osmium complexes

Nitrido-, oxo-, and imido-complexes. Part II. Crystal structure of potassium dioxotetracyanorhenate(V), K₃[ReO₂(CN)₄], by neutron diffraction

Ligands containing elements of group VIB. Part V. Thermodynamics of silver complex formation of some saturated and unsaturated (alkyl-thio)acetic and (alkylseleno)acetic acids

Organonitrogen groups in metal carbonyl complexes. Part III. Comparison of alkylarylmethyleneamino-complexes of molybdenum and tungsten with the corresponding dialkyl- and diaryl-methyleneamino-complexes

The reaction of trifluoromethylphosphino-compounds with nitric oxide

The synthesis of potentially quadridentate ligands containing both phosphorus and arsenic donor atoms

Symmetry rules for the differential Raman scattering of circularly polarized light by optically active molecules

Cation exchange reactions of a sedimentary phillipsite

Cation exchange reactions of zeolite na-P

Cation exchange in the synthetic zeolite K-F

Crystal structure of [1,2-bis(dimethylarsino)trifluoroethane]tetracarbonylmolybdenum, (Me₂AsCHF·CF₂AsMe₂)Mo(CO)₄

An electron spin resonance study of dimer formation by the copper(II) chelates of polyhydroxycarboxylic acids

Arene molybdenum chemistry: tertiary-phosphine and -phosphite derivatives and related phosphine-hydrides

The standard potentials of silver–silver halide electrodes and ion solvation in dimethyl sulphoxide–water mixtures at 25 °C

An electron spin resonance study of the vanadyl ion separation in dimeric vanadyl 1-hydroxycyclohexanecarboxylate

Photochemistry of the group VI hexacarbonyls in low temperature matrices. Part I. The pentacarbonyls of chromium, molybdenum, and tungsten

Effect of aromatic donor upon sensitized cis–trans isomerization of but-2-ene

Borazines. Part V. The mass spectra of some 1,3,5-trialkylborazines

On the magnetic properties of some distorted octahedral high-spin iron(II) complexes

Studies on co-ordination complexes of silver(II). Part VI. Crystal and molecular structure of bis(pyridine-2,3-dicarboxylato)silver(II) dihydrate

Flash photolysis of SnCl₂ and SnCl₄. Dissociation energies of SnCl₂ and SnCl

Kinetics of the hydrogen abstraction from propane, n-butane, isobutane, and cyclopentane by difluoroamino-radicals

Structure of radicals produced by γ-radiolysis. Part I. 3-Methylpentyl, 2-methylpentyl, and isopentyl radicals

The kinetic system A + B → C + D; B + C ⇌ E + F

Preparative and proton and phosphorus-31 nuclear magnetic resonance studies on palladium(II) complexes with t-butylphosphines

Structure and conformational analysis of co-ordination complexes. Part II. X-Ray crystal structure of cis-[carbonatobis(trimethylenediamine)cobalt(III)] perchlorate and conformational analysis of trimethylenediamine complexes

The non-expansion of the octet

Some new complexes containing gold–iron bonds

Platinum-metal complexes containing four or five diphenylphosphine ligands

Crystal structure of di-µ-carbonyl-nonacarbonyl-(π-cyclopentadienyl-rhodio)tri-iron(3Rh–Fe)(3Fe–Fe), (π-C₅H₅)RhFe₃(CO)₁₁

Raman spectra and factor-group analyses of crystalline group IV tetrachlorides

Lewis basicity of cyanodicarbonyl(π-mesitylene)manganese(I)

United atom models for polyatomic ligands. Part I. Hydrogen derivatives

United atom models for polyatomic ligands. Part II. Methyl and fluoro derivatives

United atom models for polyatomic ligands. Part III. Hydrogen and methyl derivatives and the pseudohalides

Adsorption of water vapour on palladium

Kinetics of the bromate–iodide reaction: catalysis by Molybdate

Crystal-field energies in the copper(II) ion

A study of halogen substitution in 4,5-dicarba-nido-hexaborane(8) and its C-methyl derivatives

The thermal decomposition of oxalates. Part XII. The thermal decomposition of lithium oxalate

Magnetic circular dichroism spectra of some nickel(II) complexes. Part I. The temperature dependence of the spectrum of the nickel(II) hexaquo-ion

Magnetic circular dichroism spectra of some nickel(II) complexes. Part II. Magnetic circular dichroism of d–d transitions in octahedral nickel(II) complexes in solution

Thermal behaviour of iron-containing micas in oxidising, reducing, and neutral atmospheres

One- and two-equivalent paths in the reaction of vanadium(II) with mercury(II). A recalculation of kinetic parameters

Mechanism of the reaction of vanadium(III) with mercury(II) in aqueous perchloric acid solutions

Fluoride crystal structures. Part XVIII. Dipotassium catena-µ-fluoro-difluoro-µ-sulphato-manganate(III)

Configuration of secondary amides and thioamides: spectroscopic and theoretical studies

One-electron energy levels in Cu(H₂O)₄TiF₆,NH₄F

Structural and mechanistic studies of co-ordination compounds. Part III. Steric effects in octahedral aquation of cobalt(III) complexes containing different quadridentate macrocyclic secondary amines

Vibrational spectra of the isoelectronic species IF₅, TeF₅^–, and SbF₅^2–

Bonding studies of organometallic compounds of boron and the group IV elements. Part VII. Enthalpies of formation of hexamethyldisiloxane, hexamethyldisilane, and tetraethylsilane by rotating bomb calorimetry

Co-ordination compounds of indium. Part XI. The stepwise one-electron reduction of some neutral indium(III) complexes

Far infrared spectra of complexes of pyridine with some divalent metal nitrates

The Mössbauer effect in tin(II) compounds. Part XI. The spectra of cubic trihalogenostannates(II)

Aquation of penta-amminechlorocobalt(III), trans-bisethylenediaminedi-chlorocobalt(III), and related complexes in mixed aqueous solvents

Synthesis of new π-allylic palladium complexes by the reaction of divinyl carbinols with palladium(II) salts

Trimethylsilylmethyl complexes of transition metals with π-bonding ligands

The interaction of hydridocarbonyltris(triphenylphosphine) complexes of iridium(I) and rhodium(I) with alk-1-ynes

Crystal and molecular structure of tetraphenylsilane

Crystal structure of piperidinium hexathiotetra-arsenate

The spectra and structure of aluminium chloride complexes. Part III. The strengths of a series of ligands towards aluminium chloride

The spectra and structure of aluminium chloride complexes. Part IV. Structure of higher complexes of aluminium chloride

Some factors influencing the absolute intensity of the carbonyl stretching modes of a series of transition-metal pentacarbonylhalide derivatives

Solid-state studies. Part IV. The vibrational spectra of cis-di-ethylenetriaminetricarbonyl-chromium, -molybdenum, and -tungsten, of 1,2,3-, 1,2,4,5-, and 1,3,5-methylbenzenetricarbonylchromium, and cyclopentadienyltricarbonylmanganese

Raman spectra of gaseous, liquid, and solid bismuth trichloride. Resonance fluorescence spectra of gaseous BiCl and BiBr

Thermodynamic considerations in co-ordination. Part IX. Heat capacity investigations into complex formation between some lanthanide(III) ions and histidine

Infrared spectra of the germyl and silyl anions

The sign of the ⁵⁷Fe quadrupole splittings in iron(II) low-spin compounds: partial quadrupole splittings and bonding properties of ligands

Solid-state interaction of anions and the interaction of solvents with cations of the type [Ru(NH₃)₅(XY)]²⁺

Disproportionation of dihalogenocyclopentadienylcobalt complexes to cobaltocenium salts

Kinetics of the formation of iron(III) monochelates with substituted malonic acids

The vibrational spectra of the carboranes. Part I. The small closo-carboranes C₂B₃H₅, 1,6-C₂B₄H₆, and C₂B₅H₇

Crystal and molecular structures of nickel(II) and zinc(II) bis(trithioperoxybenzoates)

Structural studies of metal complexes with NN′-disubstituted thioureas. Part I. Crystal structure of dichlorobis-(NN′-diethylthiourea)zinc(II)

Unstable intermediates. Part CI. Electron spin resonance spectra of the cations HgH²⁺, HgOH²⁺, HgOEt²⁺ and Hg₂³⁺ or Hg₂⁺

Unstable intermediates. Part CII. Electron spin resonance studies of solutions of sulphur in oleum: the S₈⁺ cation

Unstable intermediates. Part CIII. Electron spin resonance studies of γ-irradiated malonamide and related compounds

Electron spin resonance detection of nitric oxide and pentacyanonitrosylferrate(III) in γ-irradiated anhydrous sodium nitroprusside

Infrared and electron spin resonance studies of the effect of γ-irradiation on [Cr(CN)₅NO]^3–, [Mn(CN)₅NO]^3–, and [Fe(CN)₅NO]^2– in alkali-metal halide host lattices

Binuclear organometallic compounds. Part V. Insertion into M–C and H–C bonds of co-ordinatively unsaturated transition-metal fragments: synthesis of group VIA metal cyclopentadienyltricarbonyl metallates (germanium and tin) and hydrides

Studies on some alkenyliron compounds

Reactions of the dirhodium cation Rh₂⁴⁺, with triphenylphosphine and alkali metal carboxylates, dithiocarbamates and other anions

The activation of saturated hydrocarbons by transition-metal complexes in solution. Part I. Hydrogen–deuterium exchange in alkanes catalysed by potassium tetrachloroplatinate(II) in acetic acid

Sodium glass electrode studies of sodium tartrate complexes

Determination of relaxation time and related parameters of DNA with the Roussel–Jouan dichrograph

Crystal structure of tetraphenylgermane

Choice of applied field direction for resolving electric field gradient ambiguity in Mössbauer spectra

Preparation and properties of a but-2-enyl butadiene complex of cobalt and of an analogous complex from isoprene

Crystal field and angular overlap treatment of the p² configuration in low-symmetry ligand fields

Co-ordination compounds of indium. Part XII. Compounds derived from the reaction of 1,2-bis(trifluoromethyl)dithieten with indium(I) halides

Zinc, cadmium, and mercury complexes of the dodecahydro-nido-decaborate(2–) ion

Synthesis and studies of dehydro-NN′N″-trialkylguanidinohexacarbonyldi-iron(0)

Crystal polarised spectra of pentachloromanganese(III) ion

Reactions of metal carbonyl derivatives. Part IX. The synthesis, infrared spectra, and Mössbauer spectra of some tertiary and ditertiary phosphine, arsine, and stibine derivatives of bis(µ-methylsulphido-, -ethylsulphido-, and -phenylsulphido-tricarbonyliron)

Studies on the temperature dependence in the ¹H n.m.r. spectra of some methylcyclopentadienyl metal compounds

Substituent effects on the molecular core binding energies of some halogenated methanes

The vibrational spectra of silane and germane derivatives. Part V. The infrared and Raman spectra of dihalogeno(methyl)germanes

Infrared and Mössbauer spectra of tetracarbonylcadmioiron and related complexes

Halogenosilanes. Part II. Electrical discharge production of halogenodisilanes

Halogenosilanes. Part III. Fluoro-, chloro-, and bromo-derivatives of trisilane

Ligand-field splitting in eight-co-ordinate complexes of dodecahedral structure

Crystal and molecular structure of dicarbonyl-π-cyclopentadienyliodo[tri(n-butyl)phosphine]molybdenum(II)

Reactions of n-butene over a nickel exchanged 13X-type zeolite

Pentamethylcyclopentadienyl-rhodium and -iridium complexes. Part VI. π-Arene, π-cyclohexadienyl, and π-pyrrolyl complexes

Structure and stability of carboxylate complexes. Part V. Crystal and molecular structures of bis(methoxyacetato)bis(pyridine)copper(II) tetrahydrate and bis(phenoxyacetato)aquobis(pyridine)copper(II)

Structure and stability of carboxylate complexes. Part VI. Crystal and molecular structure of bis(methoxyacetato)tetrakis(imidazole)copper(II)

Structure and stability of carboxylate complexes. Part VII. Crystal and molecular structures of copper(II)meso-tartrate trihydrate and copper(II)d-tartrate trihydrate

Structure and stability of carboxylate complexes. Part VIII. Crystal and molecular structures of copper(II) hydrogen maleate tetrahydrate and copper(II) maleate hydrate

Structure and stability of carboxylate complexes. Part IX. Crystal and molecular structure of copper(II) phthalate monohydrate

Single-crystal electronic and electron spin resonance spectra of tetra-(6-aminohexanoic acid)copper(II) diperchlorate

Crystal structure of di-µ-[1,2-bis(dimethylarsino)tetrafluorocyclobutene]-octacarbonyl-tetrahedro-tetracobalt

Metal–metal bonding in co-ordination complexes. Part XI. Crystal and molecular structure of di[(benzenesulphinato)-µ-hydroxo-phenylstannio]-tetracarbonyldi-π-cyclopentadienyl-di-iron

Reactions of [acetoxy(2-furyl)carbene]pentacarbonylchromium

Single-crystal magnetic properties of lanthanide complexes. Part V. Hexakis(antipyrine)erbium(III) tri-iodide

Formation of nitrogen oxide trifluoride in microwave and pulsed discharges at –196 °C

Metal complex formazans. Part I. The reaction of copper and cobalt salts with certain bi- and tri-dentate 1,3,5-triarylformazans

Metal complex formazans. Part II. The reaction of copper salts with certain tetradentate formazans

Solutions of electrolytes in liquid ammonia. Part IV. The mean molal ion activity coefficients and ion transference numbers of ammonium iodide

Complexes of vanadium(IV) with 1,2-dihydroxybenzene and its substituted derivatives

Reactivity of silver oxide in the absorption of carbon dioxide

Rhodium complexes containing the trihalogenotin group

Structural investigations of metal nitrate complexes. Part II. Crystal and molecular structure of dinitratobis(pyridine)zinc(II), (C₅H₅N)₂Zn(NO₃)₂

Hydrated complexes of manganese(II) and cobalt(II) halides with heterocyclic ligands

Complex halides of transition metals. Part XII. The preparation, characterization, and reactivity of the pentachlororhenate(IV) anion

Transition-metal complexes containing phosphorus ligands. Part V. Synthesis and reactivity of some iridium triaryl phosphite complexes: metal-assisted cleavage of ortho-carbon–hydrogen bonds in co-ordinated triaryl phosphite ligands

Reaction of antimony halides and transition-metal carbonyls with transition-metal ion Schiff-base complexes

Electron spin resonance spectra and structure of some group IV and group V derivatives of dicyclopentadienyltitanium(III)

Crystal structure of di-µ-carbonyl-heptacarbonyltris[(dimethyl)phenylphosphine]-triangulo-tri-iron, [Fe₃(CO)₉(PMe₂Ph)₃]

Variable co-ordination of iron(III) complexes in co-ordinating solvents

Solvent extraction studies. Part VIII. The partition of alkali-metal and ammonium thiocyanates between tri-n-butyl phosphate and liquid ammonia

Zerovalent platinum chemistry. Part VII. Oxidative addition of diazonium salts to triphenylphosphine derivatives of platinum(0)

Magnetic and electron spin resonance properties of aniline and p-toluidine adducts of some copper(II) carboxylates. Crystal and molecular structure of diacetatocopper(II)–bis-(p-toluidine) trihydrate

Crystal and molecular structure of H₂FeRu₃(CO)₁₃; a tetrahedral hydridocarbonyl of iron and ruthenium containing asymmetric carbon bridges

Extraction of nitric acid and hydrochloric acid by methyl diphenyl phosphate

Crystal structures of transition-metal aryls. Part IV. trans-Bis-(methyldiphenylphosphine)-(σ-pentachlorophenyl)-(σ-pentafluorophenyl)nickel(II)

Chemistry of the metal carbonyls. Part LXII. Methylsilicon(carbonyl)ruthenium and -osmium complexes obtained from pentamethyl- and 1,1,2,2-tetramethyl-disilane

Reactions of low-valent metal complexes with fluorocarbons. Part XIX. Bis(t-butyl isocyanide)palladium and tetrakis(trimethyl phosphite or dimethylphenylarsine)palladium

Reactions of low-valent metal complexes with fluorocarbons. Part XX. Tricarbonyl(π-allyl and π-2-methylallyl)cobalt

Co-ordinative saturation of magnesium β-diketonates

Autoxidation of hydroxylamine in alkaline solutions. Part II. Kinetics. The acid dissociation constant of hydroxylamine

Cyclic inorganic compounds. Part XI. Fluorination of tris- and tetrakis-dimethylaminochlorotriphosphonitriles

Stereochemical control in the choice of donor atoms in metal complexes of a ‘bifunctional’ bidentate ligand

Single-crystal vibrational spectra of some chlorine-bridged anionic chains

Single-crystal Raman and far-infrared spectra of K₂CuCl₄(H₂O)₂ and related compounds

Nanosecond flash photolysis of α-tocopherylquinone

Phosphorus–nitrogen compounds. Part XXXIII. cis- and trans-1,3-Diethyl-2,4-diphenyl-2,4-dithiocyclodiphosphazanes

Electron paramagnetic resonance investigation of di-t-butyl nitroxide in Dianin's compound

Crystal and molecular structure of the compound formed from tetracyanoethylene and tricarbonyl(cycloheptatriene)iron: a novel 2,3,4,9-tetrahapto-bonded system

Heat of dilution of polymer solutions. Part II. Atactic poly(methyl methacrylate) solutions

Heat of dilution of polymer solutions. Part III. The influence of excess volume of dilution

Transition metal–carbon bonds. Part XXV. Allylic palladium complexes containing cyanide or azide ligands

Transition metal–carbon bonds. Part XXVI. Allylic and olefin complexes of platinum(II)

Transition metal–carbon bonds. Part XXVII. Oxidative addition reactions of [PtMe₂(dias)], dias o-phenylenebis(dimethylarsine)

Transition metal–carbon bonds. Part XXVIII. Oxidative addition reactions of the complexes [PtMe₂(rac-diars)] and [PtMe₂(meso-diars)]. Preparation of [PdX₂(rac-diars)] and [PdX₂(meso-diars)], (X = Cl, Br, or I; diars = PhMeAsCH₂CH₂AsMePh)

Diffusion studies. Part III. Tracer diffusion coefficients of lanthanum(III) in concentrated solutions of HCl and HClO₄ at 25 °C

Fluorophosphineiron tetracarbonyl derivatives

The interaction of DL-2,3-diaminopropionic acid and its methyl ester with metal ions. Part I. Formation constants

The vibrational spectra of systems containing linear or non-linear M–O–M linkages

Crystal and molecular structure of mercuriobis(pentacarbonylmanganese), Hg[Mn(CO)₅]₂

The hydrogen fluoride solvent system. Part IV. Solutions of mercury(II) cyanide. Evidence for the Hg₂(CN)₃⁺ cation

An SCF–MO–CNDO study of ionization potentials and orbital energies by the CNDO/BW theory

Thermodynamics of hydrochloric acid in propylene carbonate–water mixtures from e.m.f. measurements between 5 and 45 °C

Rhodium, palladium, and platinum complexes formed from 2,2,4-trimethylpent-3-en-1-ol

Boron halides as reagents in inorganic syntheses. Part II. A further general method for the preparation of anhydrous bromides and iodides: halogen exchange reactions

Crystal and molecular structure of nonacarbonyl(cyclododecatrienetriyl)hydrido-triangulo-triruthenium, HRu₃(CO)₉(C₁₂H₁₅): a ruthenium cluster with a novel allyl bonding system to the cyclododecatrienetriyl ligand

Reactions of group III metal alkyls in the gas phase. Part V. The kinetics of the intramolecular elimination of isobutene from tri-isobutylgallium

Reactions of group III metal alkyls in the gas phase. Part VII. The thermal unimolecular decomposition of tri-isobutylboron

Crystal and molecular structure of di-µ-chloro-bis[trichloro(thionyl chloride)zirconium(IV)]

Vapour pressures of anhydrous sulphates. Part I. Knudsen effusion results between 560 and 1000 °C for alkali-metal sulphates

Chlorosilylamines

Analysis of the valence electronic structures of some tin(IV) compounds

Molecular orbital calculations on polypeptides and proteins. Part IV. Studies by EHT and CNDO on the influence of hydrogen bond and chain length on certain structures

Crystal structure of hexa-amminecobalt(III) pentachlorocadmate(II)

Crystal structures of dichlorotetrakis(acetaldoxime)nickel(II) and tetrakis(acetamide)bisaquonickel(II) dichloride

Crystal and molecular structures of the trimethylamine complexes of titanium tribromide and chromium trichloride

The uncatalysed and metal-ion catalysed decarboxylation of 3-oxoglutaric acid: a model for an enzyme system

Crystal and molecular structure of tri-µ-(dimethylgermanio)-tris(tricarbonylruthenium), [Ru(CO)₃(GeMe₂)]₃

The preparation and characterization of the µ-amido-µ-oxalato-bis[tetra-amminecobalt(III)] complex, and the kinetics of reduction with Cr²⁺ and V²⁺

Oxidation of compounds containing the π-cyclopentadienylnitrosylmanganese group

High-spin organometallic derivatives of iron(III) and iron(II) stabilised by a quadridentate Schiff's base ligand

Chemical and electrical behaviour of graphite–metal halide compounds

Calculation of the electronic structure of boranes by the self-consistent molecular orbital method. Part I. B₁₀H₁₄ and some neutral chloroboranes

Some complexes of rhodium(I), rhodium(II), and rhodium(III) containing tertiary t-butylphosphines as ligands

Binuclear mixed-metal complexes formed by nickel(II) and other 3d bivalent ions with tripod ligands

Metal complexes of sulphur ligands. Part II. Reaction of bis(diphenylphosphinodithioato)-platinum(II) and -palladium(II) with ligands containing group V_B atoms

Organic reactions involving transition metals. Part IV. Carboxylatodiene complexes of rhodium(I) and iridium(I)

Organic reactions involving transition metals. Part V. Nucleophilic attack on co-ordinated dienes by carboxylate ions and a rearrangement reaction of a co-ordinated norbornenyl group

Organic reactions involving transition metals. Part VI. Complexes of unsaturated tertiary phosphines with palladium(II) and platinum(II), and their reactions with nucleophiles

Reactions involving transition metals. Part VII. Oxidation–addition reactions of cyclo-octa-1,5-dieneiridium(I) complexes

Steric factors affecting the additions of acids to complexes of type trans-[IrCl(CO)(PBu^tR₂)₂] and trans-[IrCl(CO)(PBu^t₂R)₂](R = Me, Et, or Prⁿ)

The chemistry of peroxonitrites. Part III. The reaction of peroxonitrite with nucleophiles in alkali, and other nitrite producing reactions

Crystal structure of brushite, calcium hydrogen orthophosphate dihydrate: a neutron-diffraction investigation

Magnetic properties of cobalt(II) complexes. Part I. Trigonally distorted octahedral geometries

Magnetic properties of cobalt(II) complexes. Part II. Tetragonally distorted octahedral geometries

Magnetic properties of cobalt(II) complexes. Part III. Crystal magnetic anisotropy of α-dichlorobis(pyridine)cobalt(II)

Photochemical isomerizations and related reactions of some tertiary phosphine- and tertiary arsine-iridium(III) complexes

Organosilicon chemistry. Part VIII. 2-(Pentafluorophenyl)ethylsilyl compounds and related polymers

Palladium and platinum complexes containing the trichlorotin group

Semiempirical calculation of effective atomic numbers based on the optical approximation

Photoenolization of ortho-substituted benzophenones by flash photolysis

Complexing behaviour of thiocarbamic esters: crystal and molecular structure of bis-(O-methyl phenylthiocarbamato)(triphenylphosphine)-palladium(II)

Transition-metal dithiolene complexes. Part XXI. Iron, cobalt, and nickel complexes containing chelating diarsine, diphosphine, and related ligands

Electron acceptor–electron donor interactions. Part XVIII. Charge-transfer interactions of some of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Group IV

Electron acceptor–electron donor interactions. Part XIX. Charge-transfer interactions of some of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Group VA

Electron acceptor–electron donor interactions. Part XX. Charge-transfer interactions of some of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Group VB

Electron acceptor–electron donor interactions. Part XXI. Charge-transfer interactions of some of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Group VIA

Electron acceptor–electron donor interactions. Part XXII. Charge-transfer interactions of some of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Some remaining elements

Electron acceptor–electron donor interactions. Part XXIII. Charge-transfer interactions of the highest-valency halides, oxyhalides, and oxides with aromatic hydrocarbons and fluorocarbons. Ball–plane interactions. Conclusions

Transition metal–carbon bonds. Part XXIX. Some internal metallation reactions of tertiary phosphine ligands with bulky substituents

Further e.s.r. studies of γ-irradiated hydrated sodium nitroprusside

Condensation of 1,3-hexasulphur di-imide with chlorosulphanes as a route to fused-ring sulphur nitrides

Cyclic imino derivatives of aluminium, gallium, and indium dialkyls

Index of authors, 1971

Index of subjects, 1971

Kinetic studies on the interconversion of quadridentate and quinquedentate chromium(III)-EDTA (aquo) complexes and attempts to identify the sexidentate complex

Content Provider	Royal Society of Chemistry (RSC)
Author	Sykes, A. G. Thorneley, R. N. F. Gans, P.
Copyright Year	1971
Abstract	The quinquedentate complex [CrIIIYH(H2O)](ethylenediaminetetra-acetate or EDTA ≡ Y4–), which is present as [CrIIIY(OH)]2– at pH >8, reacts in 0·1–1·0M NaOH to give the quadridentate complex [CrIIIY(OH)2]3–. The rate (k–4) is first order in complex and independent of [H+]. At 25°k–4= 4·8 × 10–3 s–1, ΔH‡–4= 17·4 ± 0·6 kcal mol–1 and ΔS‡–4=–6·4 ± 2·2 e.u. The reverse reaction has been studied over the pH range 0–12. At 25° rate constants for the reactions of five quadridentate species are [CrIIIYH2(H2O)2]+(k1= 1·4 s–1), [CrIIIYH(H2O)2](k2∼ 130 s–1)[CrIIIY(H2O)2]–(k3= 330 s–1), [CrIIIY(H2O)(OH)]2–(k4= 30 s–1) and [CrIIIY(OH)2]3–(k5= 0·004 s–1). The products are the quinquedentate species [CrIIIYH(H2O)], [CrIIIY(H2O)]–, and [CrIIIY(OH)]2– depending on the pH; protonation reactions are assumed to be rapid. Consecutive acid dissociation constants relating the five quadridentate species (25°, mol l–1) are ca. 3 × 10–3(K1), ca. 1 × 10–3(K2), 7 × 10–7(K3), and 1 × 10–8(K4). The five rate constants and four equilibrium constants were computed simultaneously by a method of non-linear least squares, by a procedure of function minimisation. At the extremities of the pH range values of k1, k2K1, and k4/K4 were obtained by graphical method and are in good agreement with the above. Activation parameters have been obtained for k1 and k3. The fast rates of substitution are attributed to neighbouring-group effects which are most favourable when –CO2– is replacing an H2O ligand. The reactions are believed to have a high degree of SN2 character. Attempts to identify the sexidentate complex [CrIIIY]– were unsuccessful.
Starting Page	1494
Ending Page	1501
Page Count	8
File Format	PDF
ISSN	00224944
Volume Number	0
Journal	Journal of the Chemical Society A: Inorganic, Physical, Theoretical
DOI	10.1039/J19710001494
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Properties of water Ethylenediaminetetraacetic acid PH Hydronium Potassium Acid Dissociative Ligand SN2 reaction
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry Inorganic Chemistry

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