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| Content Provider | Royal Society of Chemistry (RSC) |
|---|---|
| Author | Trotter, James Gibbons, Cyril S. |
| Copyright Year | 1971 |
| Abstract | Crystals of exo-tricyclo[3,2,1,02,4]oct-6-ene-silver nitrate are orthorhombic, a= 25·54, b= 6·28, c= 5·60 Å, Z= 4, space group P212121. The structure was determined with Mo-Kα diffractometer data from Patterson and electron-density maps and was refined by least-squares methods to a final R of 0·105 for 322 observed reflexions. The structure contains thick layers perpendicular to a and separated by ½a; within the layers each silver ion is coordinated roughly tetrahedrally to the double bond of the hydrocarbon (in the exo-position, Ag ⋯ C 2·4 Å), and to three nitrate groups (Ag ⋯ O 2·45–3·03 Å). The layers are held together by van der Waals forces.The structure of silver nitrate was refined with Mo-Kα diffractometer data to R 0·067 for 404 observed reflexions. Previously observed inequalities in N–O distances have been removed, all three bond lengths in the nitrate ion being 1·26(1)Å. |
| Starting Page | 2058 |
| Ending Page | 2062 |
| Page Count | 5 |
| File Format | |
| ISSN | 00224944 |
| Volume Number | 0 |
| Journal | Journal of the Chemical Society A: Inorganic, Physical, Theoretical |
| DOI | 10.1039/J19710002058 |
| Language | English |
| Publisher | Royal Society of Chemistry |
| Access Restriction | Open |
| Subject Keyword | Patterson Nitrate Orthorhombic crystal system Space group Diffractometer Polyatomic ion Covalent bond Alkane Van der Waals force Silver nitrate Chemical bond |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physical and Theoretical Chemistry Inorganic Chemistry |
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