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Simultaneous enhancement in open circuit voltage and short circuit current of hybrid organic–inorganic photovoltaics by inorganic interfacial modification

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Inside back cover

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Journal of Materials Chemistry C Vol -3

Journal of Materials Chemistry C Vol -2

Journal of Materials Chemistry C Vol -1

Simultaneous enhancement in open circuit voltage and short circuit current of hybrid organic–inorganic photovoltaics by inorganic interfacial modification

Content Provider	Royal Society of Chemistry (RSC)
Author	Hopkinson, Paul E. Bakulin, Artem A. Vaynzof, Yana Hofstetter, Yvonne J.
Copyright Year	2016
Abstract	One of the key advantages of metal oxide/polymer organic–inorganic hybrid photovoltaic devices is the possibility to control the photo-induced charge separation efficiency by interfacial modification. While a large variety of organic modifiers have been investigated, inorganic modification layers remain largely unexplored. Here, we investigate the model poly(3-hexathiophene)/ZnO system and show that by introducing a caesium carbonate interlayer, a simultaneous increase in all photovoltaic performance parameters can be achieved. While improved energy level alignment results in a significant increase in the open circuit voltage, the suppression of interfacial bound charge pairs formation causes a reduction in interfacial recombination losses and an increase in short circuit current. The overall power conversion efficiency is enhanced twelve fold, demonstrating the significant potential of inorganic modifiers for improving the performance of hybrid photovoltaic devices.
Starting Page	1111
Ending Page	1116
Page Count	6
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	4
Issue Number	5
Journal	Journal of Materials Chemistry C
DOI	10.1039/c5tc03206g
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Polymer Solar cell Caesium carbonate Polarization density Carrier generation and recombination Short circuit
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

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