NDLI: Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe<sup>3+</sup> and Al<sup>3+</sup> ion detection and VOC vapor sensing

Please wait, while we are loading the content...

New push–pull polyene chromophores containing a Michler's base donor and a tricyanofuran acceptor: multicomponent condensation, allopolar isomerism and large optical nonlinearity

Fluorination of supramolecular liquid crystals – tuning tool and analytical probe

Fabrication of silver nanowire transparent conductive films with an ultra-low haze and ultra-high uniformity and their application in transparent electronics

Synthesis of low band gap polymers based on pyrrolo[3,2-d:4,5-d′]bisthiazole (PBTz) and thienylenevinylene (TV) for organic thin-film transistors (OTFTs)

Superior resistive switching memory and biological synapse properties based on a simple TiN/SiO₂/p-Si tunneling junction structure

Tunable room-temperature soft ferromagnetism in magnetoceramics of organometallic dendrimers

Building block magneto-luminescent nanomaterials of iron-oxide/ZnS@LaF₃:Ce³⁺,Gd³⁺,Tb³⁺ with green emission

2D lateral heterostructures of monolayer and bilayer phosphorene

Ferroelectric crystal Ca₉Yb(VO₄)₇ in the series of Ca₉R(VO₄)₇ non-linear optical materials (R = REE, Bi, Y)

Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe³⁺ and Al³⁺ ion detection and VOC vapor sensing

Comparative assessment of the strain-sensing behaviors of polylactic acid nanocomposites: reduced graphene oxide or carbon nanotubes

High T_g small-molecule phenanthroline derivatives as a potential universal hole-blocking layer for high power-efficiency and stable organic light-emitting diodes

A facile route to a high-quality graphene/MoS₂ vertical field-effect transistor with gate-modulated photocurrent response

Water-free synthesis of ZnO quantum dots for application as an electron injection layer in light-emitting electrochemical cells

Optimized organometal halide perovskite solar cell fabrication through control of nanoparticle crystal patterning

High efficiency planar Sn–Pb binary perovskite solar cells: controlled growth of large grains via a one-step solution fabrication process

Ultralow bandgap molecular semiconductors for ambient-stable and solution-processable ambipolar organic field-effect transistors and inverters

Easy access to new anthracenyl π-conjugates: generation of distinct AIE-active materials

C-Axis oriented crystalline IGZO thin-film transistors by magnetron sputtering

Efficient white polymer light-emitting diodes from single polymer exciplex electroluminescence

A water-based silver nanowire ink for large-scale flexible transparent conductive films and touch screens

Charge transfer tuning in TiO₂ hybrid nanostructures with acceptor–acceptor systems

Flexible metal nanowire-parylene C transparent electrodes for next generation optoelectronic devices

A wearable microwave absorption cloth

Engineering surface ligands of nanocrystals to design high performance strain sensor arrays through solution processes

Size-dependent downconversion near-infrared emission of NaYF₄:Yb³⁺,Er³⁺ nanoparticles

Investigation of piezoelectric property and nanodomain structures for PIN–PZ–PMN–PT single crystals as a function of crystallographic orientation and temperature

Facile synthesis of water soluble fluorescent metal (Pt, Au, Ag and Cu) quantum clusters for the selective detection of Fe³⁺ ions as both fluorescent and colorimetric probes

Inside back cover

Back cover

Journal of Materials Chemistry C Vol - 5 Issue - 8

Journal of Materials Chemistry C Vol - 5 Issue - 7

Journal of Materials Chemistry C Vol - 5 Issue - 6

Journal of Materials Chemistry C Vol - 5 Issue - 5

Journal of Materials Chemistry C Vol - 5 Issue - 4

Journal of Materials Chemistry C Vol - 5 Issue - 3

Journal of Materials Chemistry C Vol - 5 Issue - 2

Journal of Materials Chemistry C Vol -4

Journal of Materials Chemistry C Vol -3

Journal of Materials Chemistry C Vol -2

Journal of Materials Chemistry C Vol -1

Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe³⁺ and Al³⁺ ion detection and VOC vapor sensing

Content Provider	Royal Society of Chemistry (RSC)
Author	Chen, Di-Ming Zhang, Nan-Nan Du, Miao Liu, Chun-Sen
Copyright Year	2017
Abstract	A flexible bidentate polyaromatic acid ligand 4,4′-oxybis(benzoic acid) (H2oba) was used for the construction of a novel luminescent Tb(III)-based metal–organic framework (MOF), namely {(Me2NH2)[Tb(OBA)2]·(Hatz)·(H2O)1.5}n, with 3-amino-1,2,4-triazole (Hatz) as the template reagent. In the structure of the Tb-MOF, there co-exist single-stranded and double-stranded helical chains along the c axis, and the overall network shows a three-fold interpenetrated qtz net. This MOF is capable of selectively sensing Fe3+ and Al3+ ions in water via quenching the luminescence and tuning the emission ratio between the ligand-based and metal-based luminescence, respectively. More importantly, this MOF can realize fast detection for p-xylene (PX) vapor with a response time of less than 10 s and 40% fluorescence enhancement, while nitrobenzene (NB) vapor could lead to a quenching effect in 10 min with a 75% quenching efficiency. Remarkably, this is the first example of a multi-responsive luminescent Tb-MOF sensor for Fe3+ and Al3+ ions and VOC vapor detection. In connection to these, the probable sensing mechanisms were also discussed in this paper.
Starting Page	2311
Ending Page	2317
Page Count	7
File Format	HTM / HTML PDF
ISSN	20507526
Volume Number	5
Issue Number	9
Journal	Journal of Materials Chemistry C
DOI	10.1039/c6tc05349a
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	MOF NB Hatz Denticity Acid Ligand Properties of water 3-Amino-1 4-triazole Reagent Luminescence P-Xylene Fluorescence Nitrobenzene Volatile organic compound
Content Type	Text
Resource Type	Article
Subject	Chemistry Materials Chemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

A dynamic, luminescent and entangled MOF as a qualitative sensor for volatile organic solvents and a quantitative monitor for acetonitrile vapour

New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of $Sm^{3+}$ with $Gd^{3+}$ and $Tb^{3+}$ Ions on the Luminescent Properties

Volatile Organic Compound (VOC) Removal by Vapor Permeation at Low VOC Concentrations: Laboratory Scale Results and Modeling for Scale Up

A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature

A Highly Selective Perylenediimide-Based Chemosensor: “Naked-Eye” Colorimetric and Fluorescent Turn-On Recognition for Al3+

Luminescent and Magnetic Tb-MOF Flakes Deposited on Silicon

Novel and easy access to highly luminescent Eu and Tb doped ultra-small CaF₂, SrF₂ and BaF₂ nanoparticles – structure and luminescence

Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis

Synthesis, structures and properties of three new compounds based on multidentate ligand containing triazole and pyrimidine

Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe³⁺ and Al³⁺ ion detection and VOC vapor sensing

Similar Documents

A dynamic, luminescent and entangled MOF as a qualitative sensor for volatile organic solvents and a quantitative monitor for acetonitrile vapour

New Carboxylate Anionic Sm-MOF: Synthesis, Structure and Effect of the Isomorphic Substitution of $Sm^{3+}$ with $Gd^{3+}$ and $Tb^{3+}$ Ions on the Luminescent Properties

Volatile Organic Compound (VOC) Removal by Vapor Permeation at Low VOC Concentrations: Laboratory Scale Results and Modeling for Scale Up

A dual functional MOF as a luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature

A Highly Selective Perylenediimide-Based Chemosensor: “Naked-Eye” Colorimetric and Fluorescent Turn-On Recognition for Al3+

Luminescent and Magnetic Tb-MOF Flakes Deposited on Silicon

Novel and easy access to highly luminescent Eu and Tb doped ultra-small CaF2, SrF2 and BaF2 nanoparticles – structure and luminescence

Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis

Synthesis, structures and properties of three new compounds based on multidentate ligand containing triazole and pyrimidine

Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe3+ and Al3+ ion detection and VOC vapor sensing

Novel and easy access to highly luminescent Eu and Tb doped ultra-small CaF₂, SrF₂ and BaF₂ nanoparticles – structure and luminescence

Template-directed synthesis of a luminescent Tb-MOF material for highly selective Fe³⁺ and Al³⁺ ion detection and VOC vapor sensing