NDLI: High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

Content Provider	Royal Society of Chemistry (RSC)
Author	Yuanyuan, Liu Junjie, Gu Ning, Nie Feng, Yu Jiao, Wang Jinli, Zhang Wei, Li
Copyright Year	2015
Abstract	A novel composite of LiFePO4 with phosphorus-doped carbon layers has been prepared via a simple hydrothermal method using glucose as the carbon source to generate a carbon coating and triphenylphosphine as the phosphorus source. The effects of phosphorus doping on the phase purity, morphology and electrochemical performance of the materials are studied by the characterizations using X-ray diffraction, Raman spectroscopy, scanning electron microscopy, high resolution transmission electron microscopy and electrochemical techniques. It is indicated that phosphorus doping into the carbon layers is beneficial for the graphitization of the carbon. Phosphorus in the carbon layers exists in the form of P–C bonds and its concentration depends on the second calcination temperature. Moreover, the phosphorus-doped carbon layers on the particle surface make the charge transfer resistance decrease remarkably from 156.5 Ω to 49.1 Ω, which can be ascribed to the free carriers donated by phosphorus. The as-prepared LiFePO4 with phosphorus-doped carbon layers calcined at 600 °C shows the best electrochemical performance with a discharge capacity of 124.0 mA h g−1 at a high rate of 20 C and an excellent retention rate of 91.4% after 50 cycles. The LiFePO4 with phosphorus-doped carbon layers exhibits excellent electrochemical performances, especially at high current rates; thus, it is a promising cathode material for high-performance lithium ion batteries.
Starting Page	2043
Ending Page	2049
Page Count	7
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	3
Issue Number	5
Journal	Journal of Materials Chemistry A
DOI	10.1039/c4ta05186f
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Raman Carbon Hydrothermal synthesis Glucose Triphenylphosphine Phosphorus Dopant Electrochemistry X-ray crystallography Raman spectroscopy Scanning electron microscope Transmission electron microscopy Calcination Cathode Ion
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Surfactants assisted synthesis of nano-LiFePO₄/C composite as cathode materials for lithium-ion batteries

Lithium-rich Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ oxide coated by Li₃PO₄ and carbon nanocomposite layers as high performance cathode materials for lithium ion batteries

Graphene–V₂O₅·nH₂O xerogel composite cathodes for lithium ion batteries

Enhanced electrochemical performance of novel K-doped Co₃O₄ as the anode material for secondary lithium-ion batteries

Core–shell CeO₂@C nanospheres as enhanced anode materials for lithium ion batteries

2,2′-Bis(3-hydroxy-1,4-naphthoquinone)/CMK-3 nanocomposite as cathode material for lithium-ion batteries

Improved electrochemical properties of LiMn₂O₄ with the Bi and La co-doping for lithium-ion batteries

High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

The solid-state chelation synthesis of LiNi_1/3Co_1/3Mn_1/3O₂ as a cathode material for lithium-ion batteries

High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

Similar Documents

Surfactants assisted synthesis of nano-LiFePO4/C composite as cathode materials for lithium-ion batteries

Lithium-rich Li1.2Ni0.13Co0.13Mn0.54O2 oxide coated by Li3PO4 and carbon nanocomposite layers as high performance cathode materials for lithium ion batteries

Graphene–V2O5·nH2O xerogel composite cathodes for lithium ion batteries

Enhanced electrochemical performance of novel K-doped Co3O4 as the anode material for secondary lithium-ion batteries

Core–shell CeO2@C nanospheres as enhanced anode materials for lithium ion batteries

2,2′-Bis(3-hydroxy-1,4-naphthoquinone)/CMK-3 nanocomposite as cathode material for lithium-ion batteries

Improved electrochemical properties of LiMn2O4 with the Bi and La co-doping for lithium-ion batteries

High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

The solid-state chelation synthesis of LiNi1/3Co1/3Mn1/3O2 as a cathode material for lithium-ion batteries

High-performance lithium iron phosphate with phosphorus-doped carbon layers for lithium ion batteries

Surfactants assisted synthesis of nano-LiFePO₄/C composite as cathode materials for lithium-ion batteries

Lithium-rich Li_1.2Ni_0.13Co_0.13Mn_0.54O₂ oxide coated by Li₃PO₄ and carbon nanocomposite layers as high performance cathode materials for lithium ion batteries

Graphene–V₂O₅·nH₂O xerogel composite cathodes for lithium ion batteries

Enhanced electrochemical performance of novel K-doped Co₃O₄ as the anode material for secondary lithium-ion batteries

Core–shell CeO₂@C nanospheres as enhanced anode materials for lithium ion batteries

Improved electrochemical properties of LiMn₂O₄ with the Bi and La co-doping for lithium-ion batteries

The solid-state chelation synthesis of LiNi_1/3Co_1/3Mn_1/3O₂ as a cathode material for lithium-ion batteries