NDLI: Ionic semi-interpenetrating networks as a new approach for highly conductive and stretchable polymer materials

Content Provider	Royal Society of Chemistry (RSC)
Author	Gumileva, Lyudmila V. Aubert, Pierre-Henri Armand, Michel Morcrette, Mathieu Shaplov, Alexander S. Vidal, Frédéric Lozinskaya, Elena I. Ponkratov, Denis O. Vlasov, Petr S. Vygodskii, Yakov S. Surcin, Christine
Copyright Year	2015
Abstract	The synthesis and characterization of ionically conductive polymer films with high stretchability and good elasticity based on ionic semi-interpenetrating polymer networks (semi-IPNs) are discussed. Such innovative semi-IPN materials were prepared by radical copolymerization of an ionic monomer, namely, (N-[2-(2-(2-(methacryloyloxy)ethoxy)ethoxy)ethyl]-N-methylpyrrolidinium bis(fluorosulfonyl)imide) with poly(ethylene glycol)(di)methacrylates in the presence of the dissolved nitrile butadiene rubber, ionic liquid and lithium salt, using a simple one-step process. The suggested approach allows for simultaneous imparting of high ionic conductivity (1.3 × 10−4 S cm−1 at 25 °C) and excellent mechanical properties (tensile strength up to 80 kPa, elongation up to 60%) to a single polymer material. Ionic semi-IPNs, possessing unusual “Emmentaler cheese” like structure, exhibit a wide electrochemical stability window (4.9 V) and acceptable time-stable interfacial properties in contact with metallic lithium. Preliminary battery tests have shown that Li/LiFePO4 solid-state cells are capable to deliver a 77 mA h g−1 average specific capacity at 40 °C during 75 charge/discharge cycles.
Starting Page	2188
Ending Page	2198
Page Count	11
File Format	HTM / HTML PDF
ISSN	20507488
Volume Number	3
Issue Number	5
Journal	Journal of Materials Chemistry A
DOI	10.1039/c4ta05833j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Conductive polymer Polymer Monomer Imide Ethylene glycol Nitrile 3-Butadiene Ionic liquid Lithium Ultimate tensile strength Pascal (unit) Ionic order Emmental cheese Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Renewable Energy, Sustainability and the Environment Materials Science

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