NDLI: Ni<sub>3</sub>S<sub>2</sub> nanosheet-anchored carbon submicron tube arrays as high-performance binder-free anodes for Na-ion batteries

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Inorganic Chemistry Frontiers Vol -3

Inorganic Chemistry Frontiers Vol -2

Inorganic Chemistry Frontiers Vol -1

Ni₃S₂ nanosheet-anchored carbon submicron tube arrays as high-performance binder-free anodes for Na-ion batteries

Content Provider	Royal Society of Chemistry (RSC)
Author	Xia, Xueke Xie, Jian Zhang, Shichao Cao, Gaoshao Zhao, Xinbing Pan, Bin
Copyright Year	2017
Abstract	Owing to the increasing concerns regarding limited lithium reserves, sodium-ion batteries (SIBs) have attained worldwide attention in recent years. However, there is still a challenge to find suitable anodes for SIBs with high capacity and a long cycle life. In this work, we propose a unique feather-like array-type anode composed of thin Ni3S2 nanosheets anchored on cracked carbon submicron tubes (CSTs) on a porous Ni foam substrate. The porous structure of the Ni foam facilitates electrode wetting by the electrolyte. The voids in between the Ni3S2/CST arrays provide free space for buffering volume changes upon sodiation/desodiation. The CSTs not only act as the support for Ni3S2 growth but also uniformly disperse the Ni3S2 nanosheets, leading to high capacity and good capacity retention. The Ni-supported Ni3S2/CSTs can deliver a high initial reversible capacity of 887 mA h g−1 at 50 mA g−1. The reversible capacity can be kept at 212 mA h g−1 after 260 cycles. This work will shed light on the design of high-performance SIB anodes.
Starting Page	131
Ending Page	138
Page Count	8
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	4
Issue Number	1
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c6qi00286b
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	SIB Lithium Anode Carbon CSTS Electrode Electrolyte Central Time Zone
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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