NDLI: Synthesis of Fe/M (M = Mn, Co, Ni) bimetallic metal organic frameworks and their catalytic activity for phenol degradation under mild conditions

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Inorganic Chemistry Frontiers Vol -3

Inorganic Chemistry Frontiers Vol -2

Inorganic Chemistry Frontiers Vol -1

Synthesis of Fe/M (M = Mn, Co, Ni) bimetallic metal organic frameworks and their catalytic activity for phenol degradation under mild conditions

Content Provider	Royal Society of Chemistry (RSC)
Author	Zuo, Yi Li, Keyan Sun, Qiao Guo, Xinwen Chai, Fanfan Song, Chunshan Han, Yitong Liu, Min Zhang, Guoliang
Copyright Year	2017
Abstract	Partial isomorphic substitution of iron in an Fe(BDC)(DMF,F) metal organic framework by manganese, cobalt, and nickel has been described for the first time. Specifically, different amounts of Mn, Co and Ni have been incorporated into the Fe-based framework during a solvothermal crystallization procedure. Several characterization techniques, including XRD, FT-IR, SEM, EDS, TG, XPS and ICP-AES, strongly support the effective incorporation of Mn, Ni and Co into material frameworks. The catalytic performance of these materials was examined in liquid-phase degradation of phenol at 35 °C and near neutral pH of 6.2. The results show that the degradation efficiency can be evidently improved by the incorporation of Mn, while it can be inhibited by the incorporation of Ni. The incorporation of Co shows no remarkable influence on the degradation process. Moreover, the ratios of n(Fe)/n(Mn) in the bimetallic MOFs have a strong impact on the degradation process. The stability and reusability of these catalysts under mild conditions were also demonstrated in this study. This work illustrates the potential of bimetallic MOF structures in developing active heterogeneous catalysts for the degradation process of toxic compounds.
Starting Page	144
Ending Page	153
Page Count	10
File Format	HTM / HTML PDF
ISSN	20521553
Volume Number	4
Issue Number	1
Journal	Inorganic Chemistry Frontiers
DOI	10.1039/c6qi00441e
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	SEM MOF Isomorphism Metal\u2013organic framework Manganese Cobalt Nickel X-ray crystallography Fourier-transform infrared spectroscopy Inductively coupled plasma atomic emission spectroscopy Phenol PH
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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