NDLI: Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

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Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

Content Provider	Royal Society of Chemistry (RSC)
Author	Mereau, R. Jerome, C. Detrembleur, C. Alves, M. Grignard, B. Gennen, S. Tassaing, T.
Copyright Year	2015
Abstract	A catalytic platform based on an onium salt used in combination with organic cocatalysts of various structures was developed for the efficient CO2/epoxide coupling under mild conditions. Through detailed kinetic studies by in situ FT-IR spectroscopy, a rational investigation of the efficiency of a series of commercially available hydrogen bond donors co-catalysts was realized and the influence of different parameters such as the pressure, the temperature, the catalyst loading, and the nature of the epoxide on the reaction kinetics was evaluated. Fluorinated alcohols were found to be more efficient than other hydrogen bond donor activators proposed previously in the literature under similar conditions.
Starting Page	4636
Ending Page	4643
Page Count	8
File Format	HTM / HTML PDF
ISSN	20444753
Volume Number	5
Issue Number	9
Journal	Catalysis Science & Technology
DOI	10.1039/c5cy00891c
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Quaternary ammonium cation Spectroscopy Epoxide Fourier-transform infrared spectroscopy Hydrogen bond
Content Type	Text
Resource Type	Article
Subject	Catalysis

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Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

Postsynthetic ionization of an imidazole-containing metal–organic framework for the cycloaddition of carbon dioxide and epoxides

Silica grafted ammonium salts based on DABCO as heterogeneous catalysts for cyclic carbonate synthesis from carbon dioxide and epoxides

Switchable catalytic processes involving the copolymerization of epoxides and carbon dioxide for the preparation of block polymers

Low-Cost Polymer-Supported Quaternary Ammonium Salts as High-Efficiency Catalysts for Cycloaddition of CO2 to Epoxides

Titanium dioxide modified with various amines used as sorbents of carbon dioxide

Insights into quaternary ammonium salts-catalyzed fixation carbon dioxide with epoxides

Fourier-transform infrared spectroscopic study of acetonitrile adsorbed on silica-supported nickel and nickel oxide

Experimental and theoretical studies on hydrogen bond-promoted fixation of carbon dioxide and epoxides in cyclic carbonates.

Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

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Organocatalytic promoted coupling of carbon dioxide with epoxides: a rational investigation of the cocatalytic activity of various hydrogen bond donors

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