NDLI: Anisotropic highly-conductive films of poly(3-methylthiophene) from epitaxial electropolymerization on oriented poly(vinylidene fluoride)

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Anisotropic highly-conductive films of poly(3-methylthiophene) from epitaxial electropolymerization on oriented poly(vinylidene fluoride)

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Anisotropic highly-conductive films of poly(3-methylthiophene) from epitaxial electropolymerization on oriented poly(vinylidene fluoride)

Content Provider	Royal Society of Chemistry (RSC)
Author	Ren, Zhongjie Sun, Dianming Li, Yongxiu Yan, Shouke Li, Huihui Bryce, Martin R.
Copyright Year	2014
Abstract	Electrochemical polymerization of 3-methylthiophene on highly oriented poly(vinylidene fluoride) (PVDF) film was achieved by cyclic voltammetry to yield well-ordered poly(3-methylthiophene) (P3MT) thin films with anisotropic structural and conductivity properties. The conductivity of P3MT along the direction perpendicular to the chain direction of PVDF, after electrochemical dedoping, is 59 ± 3 S cm−1, while that along the PVDF chain direction is 1.2 ± 0.4 S cm−1. The high conductivity of the P3MT is attributed to the well-ordered structure with its flat-on single crystals as confirmed by electron diffraction and Reflection Absorption Infra-red Spectroscopy (RAIRS). The data are consistent with P3MT chains aligned with π–π stacking perpendicular to the chain direction of the PVDF substrate. Epitaxial electropolymerization is an unusual method of preparing highly ordered thin films of organic semiconductors.
Starting Page	3240
Ending Page	3245
Page Count	6
File Format	HTM / HTML PDF
ISSN	20416520
Volume Number	5
Issue Number	8
Journal	Chemical Science
DOI	10.1039/c4sc01068j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Subscribed
Subject Keyword	Cyclic voltammetry Nanoarchitectures for lithium-ion batteries Polyvinylidene fluoride Anisotropy Electron diffraction Polymerization Electrochemistry PVDF
Content Type	Text
Resource Type	Article
Subject	Chemistry

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