NDLI: Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature “Picasso”

Please wait, while we are loading the content...

Determination of meloxicam in plasma samples using a highly selective and sensitive voltammetric sensor based on carbon paste electrodes modified by molecularly imprinted polymer nanoparticle–multiwall carbon nanotubes

A paperfluidic device for dental applications using a novel patterning technique

Preparation of magnetic core–shell nanoflower Fe₃O₄@MnO₂ as reusable oxidase mimetics for colorimetric detection of phenol

SERS detection of expired tetracycline hydrochloride with an optical fiber nano-probe

A facile sensitive l-tyrosine electrochemical sensor based on a coupled CuO/Cu₂O nanoparticles and multi-walled carbon nanotubes nanocomposite film

Preparative separation of isoflavones in plant extract of Pueraria lobata by high performance counter-current chromatography

A novel photoelectrochemical sensor for the detection of α-fetoprotein based on a mesoporous TiO₂–CdS QD composite film

Synthesis and characterization of diphenyl–phenyl polysiloxane as a high-temperature gas chromatography stationary phase

An electrochemical sensing method for the determination of levodopa using a poly(4-methyl-ortho-phenylenediamine)/MWNT modified GC electrode

Gold-nanoparticle, functionalized-porous-polymer monolith enclosed in capillary for on-column SERS detection

The development of a multiplex real-time PCR to quantify Fusarium DNA of trichothecene and fumonisin producing strains in maize

Evaluation of organochlorine pesticides in soil using ultrasound-assisted liquid phase microextraction

Determination of unconjugated non-steroidal anti-inflammatory drugs in biological fluids using air-assisted liquid–liquid microextraction combined with back extraction followed by high performance liquid chromatography

Hollow fiber supported liquid membrane coupled with high performance liquid chromatography for highly sensitive determination of bisphenols in environmental water samples

An l-dopa electrochemical sensor based on a graphene doped molecularly imprinted chitosan film

Cathodic electrochemiluminescence of a CdSe/ZnS QDs-modified glassy carbon electrode and its application in sensing of Pb²⁺

Humidity effects on resolution and sensitivity of UV-FAIMS in VOCs detection

A metal-enhanced fluorescence study of primary amines: determination of aminoglycosides with europium and gold nanoparticles

Chemical identification of cannabinoids in street marijuana samples using electrospray ionization FT-ICR mass spectrometry

Simultaneous determination of twenty-six components of Flos Lonicerae japonicae–Fructus Forsythiae herb couple using UPLC-ESI-MS/MS: application to its preparations

In situ electrochemical synthesis of Ni-capped electrochemiluminescence nanoprobe for ultrasensitive detection of cancer cells

The development of a sensitive and rapid liquid-phase microextraction method followed by liquid chromatography mass spectrometry for the determination of zearalenone residues in beer samples

Colorimetric detection of melamine based on the size effect of AuNPs

Investigation of the adsorption behaviour of different types of dyes on MIL-100(Fe) and their removal from natural water

Simultaneous determination of dopamine, ascorbic acid and uric acid using a multi-walled carbon nanotube and reduced graphene oxide hybrid functionalized by PAMAM and Au nanoparticles

Gold nanoparticles as a colorimetric probe for the determination of N-acetyl-l-cysteine in biological samples and pharmaceutical formulations

Local linear embedded regression in the quantitative analysis of glucose in near infrared spectra

Highly sensitive electrochemical sensor based on pyrrolidinium ionic liquid modified ordered mesoporous carbon paste electrode for determination of carbendazim

Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature “Picasso”

A novel micro pressurized liquid extraction method for very rapid solid sample preparation

Multi-commutation flow system with on-line solid phase extraction exploiting the ion-imprinted polymer and FAAS detection for chromium speciation analysis in sewage samples

Differentiation of vehicle top coating paints using pyrolysis-gas chromatography/mass spectrometry and multivariate chemometrics with statistical comparisons

Rapid assay for testing superoxide anion radical scavenging activities to natural pigments by ultra-high performance liquid chromatography-diode-array detection method

A simple and sensitive assay for the determination of nitrite using folic acid as the fluorescent probe

A multi-residue analysis of sulphonamides in edible animal tissues using QuEChERS extraction and HPLC-MS/MS

Glutathione-protected silver nanoclusters for sensing trace-level Hg²⁺ in a wide pH range

Preparation of a restricted access material–macroporous hybrid monolithic column – for on-line solid-phase extraction of the sulfonamides residues from honey

Towards the development of a sensitive electrochemical sensor for the determination of chloramphenicol residues in milk

Role of electrostatic contributions in the separation of peptides with silica hydride stationary phases

Extraction and determination of sulfadiazine and sulfathiazole in milk using magnetic solid phase extraction-HPLC-UV

A validated method to measure benzo[a]pyrene concentrations in tobacco by high-performance liquid chromatography-fluorescence detection

A novel approach to determine the tyrosine concentration in human plasma by DART-MS/MS

Magnetic solid-phase extraction based on Fe₃O₄@polyaniline particles followed by ultrafast liquid chromatography for determination of Sudan dyes in environmental water samples

Non-destructive evaluation of total volatile basic nitrogen (TVB-N) and K-values in fish using colorimetric sensor array

Integration of a bio-chip technique with technetium-99m labeling provides zeptomolar sensitivity in liver cancer biomarker detection

Is your ‘homogeneity test’ really useful?

Determination of formaldehyde residue in cosmetics by short-column high performance liquid chromatography with mass spectrometric confirmation

Back cover

Analytical Methods Vol - 7 Issue - 3

Analytical Methods Vol -6

Analytical Methods Vol -5

Analytical Methods Vol -4

Analytical Methods Vol -3

Analytical Methods Vol -2

Analytical Methods Vol -1

Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature “Picasso”

Content Provider	Royal Society of Chemistry (RSC)
Author	López-Ramírez, Maria Rosa Manzano, Eloisa Rodríguez-Simón, Luis R. Navas, Natalia Otero, Juan C.
Copyright Year	2015
Abstract	A painting bearing the signature “Picasso” was investigated and its components – pigments and binders – were characterised using micro-Raman spectroscopy (mRS) combined with other analytical techniques such as Scanning Electron Microscopy with Energy Dispersive X-ray analysis (SEM/EDX), Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Gas Chromatography-Mass Spectrometry (GC-MS). We identified the pigments in order to assess chronological inconsistency (anachronistic pigments) with the work of the Spanish artist Pablo Picasso (1881–1973) by means of in situ and cross-section analyses by mRS. Using mRS we identified the pigments ‘phthalocyanine blue’, ‘phthalocyanine green’, ‘pyrazolone orange’, ‘anatase’ and ‘rutile’ (titanium dioxide). These results were corroborated by SEM/EDX elemental analysis, which detected Ba, S and Zn among others, so prompting discussion about the use of ready-mixed house paints (Ripolin®). The ground layer was also investigated by mRS, which confirmed the use of rutile (titanium dioxide), calcite and phyllosilicates (Al, Fe). mRS on the white area identified the binding media as beeswax, the most important wax used in art. ATR-FTIR and GC-MS analysis support the presence of a wax and an oil–resin mixture as the binder, described in previous research as being used by Picasso. All the artist materials identified were widely used in art at the beginning of the twentieth century according to the available bibliography and are therefore consistent with the Picasso era. To the best of our knowledge this is the first attempt to investigate a painting related to Picasso using the combination of analytical techniques proposed here.
Starting Page	1499
Ending Page	1508
Page Count	10
File Format	HTM / HTML PDF
ISSN	17599660
Volume Number	7
Issue Number	4
Journal	Analytical Methods
DOI	10.1039/c4ay02365j
Language	English
Publisher	Royal Society of Chemistry
Access Restriction	Open
Subject Keyword	Spectroscopy Gas chromatography\u2013mass spectrometry Anatase Beeswax Scanning Electron Microscopy Fourier-transform infrared spectroscopy Spanish language Pyrazolone Paint Scanning electron microscope Phthalocyanine Blue BN Calcite X-ray crystallography Phthalocyanine Ripolin Pablo Picasso Picasso Silicate minerals Titanium dioxide Ba
Content Type	Text
Resource Type	Article
Subject	Analytical Chemistry Engineering Chemical Engineering

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Amateur means in cubism? the use of ripolin ® by pablo picasso.

Electro-optical properties of copper phthalocyanines (CuPc) vacuum deposited thin films

AMATEUR MEANS IN CUBISM? THE USE OF RIPOLIN® BY PABLO PICASSO

AMATEUR MEANS IN CUBISM? THE USE OF RIPOLIN® BY PABLO PICASSO

A facile and efficient preparation of anatase titania nanoparticles in micelle nanoreactors: morphology, structure, and their high photocatalytic activity under UV light illumination

Scientific Study of the Origin of the Painting from the Early 20th Century Leads to Pablo Picasso

Madame Picasso

Effects of titanium foil thickness on TiO₂ nanostructures synthesized by anodization

The Painting of Pablo Picasso: A Psychoanalytic Study

Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature “Picasso”

Similar Documents

Amateur means in cubism? the use of ripolin ® by pablo picasso.

Electro-optical properties of copper phthalocyanines (CuPc) vacuum deposited thin films

AMATEUR MEANS IN CUBISM? THE USE OF RIPOLIN® BY PABLO PICASSO

AMATEUR MEANS IN CUBISM? THE USE OF RIPOLIN® BY PABLO PICASSO

A facile and efficient preparation of anatase titania nanoparticles in micelle nanoreactors: morphology, structure, and their high photocatalytic activity under UV light illumination

Scientific Study of the Origin of the Painting from the Early 20th Century Leads to Pablo Picasso

Madame Picasso

Effects of titanium foil thickness on TiO2 nanostructures synthesized by anodization

The Painting of Pablo Picasso: A Psychoanalytic Study

Study of modern artistic materials using combined spectroscopic and chromatographic techniques. Case study: painting with the signature “Picasso”

Effects of titanium foil thickness on TiO₂ nanostructures synthesized by anodization