NDLI: Synthesis of some metallophthalocyanines with dimethyl 5-(phenoxy)-isophthalate substituents and evaluation of their antioxidant-antibacterial activities.

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Synthesis of some metallophthalocyanines with dimethyl 5-(phenoxy)-isophthalate substituents and evaluation of their antioxidant-antibacterial activities.

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Synthesis of some metallophthalocyanines with dimethyl 5-(phenoxy)-isophthalate substituents and evaluation of their antioxidant-antibacterial activities.

Content Provider	World Health Organization (WHO)-Global Index Medicus
Author	Özdemir, Sadin Salih Agirtas, M. Karatas, Ceyhun
Description	Author Affiliation: Salih Agirtas M ( Department of Chemistry, Faculty of Science, Yüzüncü Yil University, 65080 Van, Turkey. Electronic address: salihagirtas@hotmail.com.); Karatas C ( Department of Chemistry, Faculty of Science, Yüzüncü Yil University, 65080 Van, Turkey.); Özdemir S ( Department of Biology, Faculty of Arts and Science, Siirt University, 56100 Siirt, Turkey.)
Abstract	The synthesis, characterization, spectral, antioxidant and antibacterial properties of dimethyl 5-(phenoxy)-isophthalate substituted Zinc, Cobalt, Copper, and Nickel phthalocyanines are reported. The novel compounds have been characterized by using electronic absorption, nuclear magnetic resonance spectroscopy, infrared, elemental analysis and mass spectrometry. The antioxidant and antibacterial activities of newly synthesized phthalocyanines and its starting material are tested. The DPPH free radical scavenging ability of phthalocyanine Co(II) and Zn(II) complexes on DPPH are 44.8% and 40.1% at 100 mg/L concentration, respectively. The phthalocyanine Co(II) and Cu(II) complexes show very strong ferrous ion chelating activity of 91.2% and 89.3% at concentration of 100 mg/L, respectively. Compound 3 displays strong reducing power like -tocopherol. Antibacterial activities of phthalocyanine Co(II) and Amikacin (30 µg/disk) against Micrococcus luteus (ATCC 9341) are 16 mm in diameter.
ISSN	13861425
Volume Number	135
e-ISSN	18733557
Journal	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Language	English
Publisher	Elsevier
Publisher Date	2015-01-25
Publisher Place	Great Britain (UK)
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Anti-bacterial Agents Chemical Synthesis Pharmacology Antioxidants Indoles Metals Phthalic Acids Chemistry Biphenyl Compounds Chelating Agents Free Radical Scavengers Microbial Sensitivity Tests Oxidation-reduction Drug Effects Picrates Spectrometry, Mass, Matrix-assisted Laser Desorption-ionization Journal Article Discipline Spectroscopy
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Atomic and Molecular Physics, and Optics Analytical Chemistry Instrumentation

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