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| Content Provider | World Health Organization (WHO)-Global Index Medicus |
|---|---|
| Author | Alpaslan, Yelda Bingöl Temel, Ersin Albayrak, Çigdem Alpaslan, Gökhan Dilek, Nefise Güder, Aytaç Gökçe, Halil Alasalvar, Can |
| Description | Author Affiliation: Temel E ( Giresun University, Technical Science Vocational High School, Department of Electric and Energy, 28100 Giresun, Turkey. Electronic address: ersin.temel@giresun.edu.tr.); Alasalvar C ( Giresun University, Technical Science Vocational High School, Department of Electric and Energy, 28100 Giresun, Turkey.); Gökçe H ( Giresun University, Vocational High School of Health Services, Department of Medical Services and Techniques, 28100 Giresun, Turkey.); Güder A ( Giresun University, Vocational High School of Health Services, Department of Medical Services and Techniques, 28100 Giresun, Turkey.); Albayrak Ç ( Sinop University, Faculty of Arts and Sciences, Department of Chemistry, 57000 Sinop, Turkey.); Alpaslan YB ( Giresun University, Faculty of Medicine, Department of Biophysics, 28100 Giresun, Turkey.); Alpaslan G ( Giresun University, Vocational High School of Health Services, Department of Medical Services and Techniques, 28100 Giresun, Turkey.); Dilek N ( Aksaray University, Faculty of Arts and Sciences, Department of Physics, 68100 Aksaray, Turkey.) |
| Abstract | We have reported synthesis and characterization of (E)-2-nitro-4-[(phenylimino)methyl]phenol by using X-ray crystallographic method, FT-IR and UV-vis spectroscopies and density functional theory (DFT). Optimized geometry and vibrational frequencies of the title compound in the ground state have been computed by using B3LYP with the 6-311G+(d,p) basis set. HOMO-LUMO energy gap, Non-linear optical properties and NBO analysis of the compound are performed at B3LYP/6-311G+(d,p) level. Additionally, as remarkable properties, antioxidant activity of the title compound (CMPD) has been determined by using different antioxidant test methods i.e. ferric reducing antioxidant power (FRAP), hydrogen peroxide scavenging (HPSA), free radical scavenging (FRSA) and ferrous ion chelating activities (FICA). When compared with standards (BHA, BHT, and -tocopherol), we have concluded that CPMD has effective FRAP, HPSA, FRSA and FICA. |
| ISSN | 13861425 |
| Volume Number | 136 Pt B |
| e-ISSN | 18733557 |
| Journal | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy |
| Language | English |
| Publisher | Elsevier |
| Publisher Date | 2015-02-05 |
| Publisher Place | Great Britain (UK) |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Antioxidants Chemistry Pharmacology Phenols Crystallography, X-ray Ferrous Compounds Free Radicals Hydrogen Peroxide Methylation Models, Molecular Nitro Compounds Spectroscopy, Fourier Transform Infrared Journal Article Research Support, Non-u.s. Gov't Discipline Spectroscopy |
| Content Type | Text |
| Resource Type | Article |
| Subject | Spectroscopy Atomic and Molecular Physics, and Optics Analytical Chemistry Instrumentation |
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